Tag: 500-600

CuO-Catalyzed 1,3-Addition of Diaryliodonium Triflates to Diazo Esters for the Stereoselective Synthesis of Triflate-Substituted β-Aryloxyl Acrylates was written by Lin, Jia-Jia;Zhou, Jun;Wu, Panpan;Chen, Chao. And the article was included in European Journal of Organic Chemistry in 2019.Product Details of 139139-80-3 The following contents are mentioned in the article:

CuO-catalyzed 1,3-addition of diaryliodonium triflates to diazo esters was realized. This new strategy forms a series of triflate-substituted β-aryloxyl acrylate compounds with good tolerance of functional groups and excellent regioselectivity. Mild reaction conditions are enough, and strong acids or bases are not required. Easy manipulation and good step-economy are further advantages. The alkenyl triflate products can be further modified via cross-coupling reactions to generate derivatized products. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Product Details of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Product Details of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Multicomponent Synthesis of Biologically Relevant S-Aryl Dithiocarbamates Using Diaryliodonium Salts was written by Parida, Sushanta K.;Jaiswal, Sonal;Singh, Priyanka;Murarka, Sandip. And the article was included in Organic Letters in 2021.Formula: C19H22F3IO3S The following contents are mentioned in the article:

A transition-metal-free one-pot three-component annulation between diaryliodonium triflates, cyclic and acyclic aliphatic amines, and carbon disulfide providing a convenient and efficient access to biol. relevant S-aryl dithiocarbamates is developed. The reaction does not require metal, base, or any other additive and operates under mild and ambient conditions. This methodol. is robust, scalable, and exhibits a broad substrate scope. The in silico anal. revealed that the majority of the compounds have a drug-likeness and good ADMET characteristics. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Synthesis of [¹⁸F]fluoroarenes from the reaction of cyclotron-produced [¹⁸F]fluoride ion with diaryliodonium salts was written by Shah, Aneela;Pike, Victor W.;Widdowson, David A.. And the article was included in Journal of the Chemical Society in 1998.Recommanded Product: 139139-80-3 The following contents are mentioned in the article:

Diaryliodonium salts have been shown to react with fluoride ion at 80° in acetonitrile to generate aryl fluorides. The regioselectivity is controlled electronically and by the bulk of the ortho-substituents on the rings, with the latter the dominant factor such that electron-rich rings can be fluorinated. Ortho-substituted aryl fluorides can be selectively produced from unsym. diaryliodonium salts. The process has been used to synthesize [¹⁸F] labeled aromatics using cyclotron generated [¹⁸F]fluoride ion. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Recommanded Product: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Recommanded Product: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Sterically Congested 2,6-Disubstituted Anilines from Direct C-N Bond Formation at an Iodine(III) Center was written by Lucchetti, Nicola;Scalone, Michelangelo;Fantasia, Serena;Muniz, Kilian. And the article was included in Angewandte Chemie, International Edition in 2016.Synthetic Route of C19H22F3IO3S The following contents are mentioned in the article:

2,6-Disubstituted anilines are readily prepared from the direct reaction between amides and diaryliodonium salts. As demonstrated for 24 different examples, the reaction is of unusually broad scope with respect to the sterically congested arene and the nitrogen source, occurs without the requirement for any addnl. promoter, and proceeds through a direct reductive elimination at the iodine(III) center. The efficiency of the coupling procedure is further demonstrated within the short synthesis of a chemerin binding inhibitor. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Synthetic Route of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Synthetic Route of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Arylation of Click Triazoles with Diaryliodonium Salts was written by Virant, Miha;Kosmrlj, Janez. And the article was included in Journal of Organic Chemistry in 2019.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:

A robust, selective, and highly efficient method for the preparation of 1,3,4-triaryl 1,2,3-triazolium salts has been developed. It features arylation of a click triazole with a diaryliodonium salt in the presence of a copper catalyst under neat conditions. The presence of pyridine functionality is tolerated, enabling the first access to key precursors of pyridyl-mesoionic carbene ligands. The method has been integrated into a one-pot protocol with terminal alkyne, sodium azide, and diaryliodonium salt as starting compounds This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.HPLC of Formula: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF₂CH₃) was written by Li, Xinjin;Zhao, Jingwei;Wang, Yunze;Rong, Jian;Hu, Mingyou;Chen, Dingben;Xiao, Pan;Ni, Chuanfa;Wang, Limin;Hu, Jinbo. And the article was included in Chemistry – An Asian Journal in 2016.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:

A new method for the formation of 1,1-difluoroethyl copper species (“CuCF₂CH₃“) with 1,1-difluoroethylsilane (TMSCF₂CH₃) has been developed. The “CuCF₂CH₃” species can be applied to the efficient 1,1-difluoroethylation of diaryliodonium salts under mild conditions, affording (1,1-difluoroethyl)arenes in good to excellent yields. This convenient procedure tolerates a wide range of functional groups and thus serves as a practical synthetic tool for the introduction of CF₂CH₃ group(s) into complex mols. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Name: Bis(2,4,6-trimethylphenyl)iodonium triflate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

One-Pot Synthesis of Aryl Sulfones from Organometallic Reagents and Iodonium Salts was written by Margraf, Natalie;Manolikakes, Georg. And the article was included in Journal of Organic Chemistry in 2015.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

A transition-metal-free arylation of lithium, magnesium, and zinc sulfinates with diaryliodonium salts is described. The sulfinic acid salts were prepared from the reaction of the corresponding organometallic reagents and sulfur dioxide. Combination of the three single steps (preparation of the organometallic compound, sulfinate formation, and arylation) leads to a one-pot sequence for the synthesis of aryl sulfones from simple starting materials. The chemoselectivity of unsym. diaryliodonium salts has been investigated. Potential and limitations of this method will be discussed. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed S-Arylation of Tetraalkylthiuram Disulfides by Using Diaryliodonium Salts was written by Zeng, Meng-Tian;Xu, Wan;Liu, Xing;Chang, Cai-Zhu;Zhu, Hui;Dong, Zhi-Bing. And the article was included in European Journal of Organic Chemistry in 2017.Related Products of 139139-80-3 The following contents are mentioned in the article:

An efficient and convenient procedure for the S-arylation of tetraalkylthiuram disulfides by using diaryliodonium salts was explored. In the presence of CuI/KOtBu, two kinds of S-aryl dithiocarbamates I (R¹ = H, 4-Me, 4-OMe, etc.; R² = Me, Et, n-Bu) could be obtained in good to excellent yields at one time with no clear selectivity. This method has the advantages of efficiency, good atom economy, and broad substrate scope. This protocol allows the facile and convenient preparation of some potentially biol. active compounds This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Related Products of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Related Products of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-Free Synthesis of Aryl Esters from Carboxylic Acids and Diaryliodonium Salts was written by Petersen, Tue B.;Khan, Rehan;Olofsson, Berit. And the article was included in Organic Letters in 2011.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

An efficient arylation of carboxylic acids with diaryliodonium salts has been developed, giving aryl esters in high yields within short reaction times for both aromatic and aliphatic substrates. The transition-metal-free conditions are compatible with a range of functional groups, and good chemoselectivity is observed with unsym. diaryliodonium salts. Furthermore, steric hindrance in the ortho positions is well tolerated both in the carboxylic acid and in the diaryliodonium salt, yielding aryl esters that cannot be obtained via other esterification protocols. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Palladium(II)-catalyzed ortho-arylation via phosphate-group-directed C-H activation was written by Jeon, Woo Hyung;Lee, Tae Seob;Kim, Eun Jin;Moon, Bongjin;Kang, Jahyo. And the article was included in Tetrahedron in 2013.SDS of cas: 139139-80-3 The following contents are mentioned in the article:

Aryl dialkyl phosphate, which is readily available from phenol, was a good substrate for the Pd(II) catalyzed aryl-aryl coupling reaction through ortho-C-H activation. Although a phosphate group is regarded as a poor coordinating group, highly regioselective ortho-arylation could be achieved by employing Pd(OTf)₂·2H₂O and Ar₂IOTf as a catalyst and an aryl group source, resp. The phosphate group of the resulting coupled product can be transformed into an aryl anion via reductive cleavage and used for further C-C bond formation. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3SDS of cas: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole produced by Proteus, Pseudomonas, Escherichia and other species was shown to be a growth promoting factor in Arabidopsis thaliana. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.SDS of cas: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com