Tag: 500-600

Flow Synthesis of Diaryliodonium Triflates was written by Laudadio, Gabriele;Gemoets, Hannes P. L.;Hessel, Volker;Noel, Timothy. And the article was included in Journal of Organic Chemistry in 2017.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:

A safe and scalable synthesis of diaryliodonium triflates was achieved using a practical continuous-flow design. A wide array of electron-rich to electron-deficient arenes could readily be transformed to their resp. diaryliodonium salts on a gram scale, with residence times varying from 2 to 60 s (44 examples). This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). HPLC of Formula: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Transition metal-free O-arylation of quinoxalin-2-ones with diaryliodonium salts was written by Kuriyama, Masami;Mochizuki, Yuki;Miyagi, Tsubasa;Yamamoto, Kosuke;Demizu, Yosuke;Onomura, Osamu. And the article was included in Heterocycles in 2021.Synthetic Route of C19H22F3IO3S The following contents are mentioned in the article:

The transition metal-free O-arylation reactions of quinoxalin-2-ones with diaryliodonium salts was achieved, and desired 2-aryloxyquinoxalines I [R = H, Me, Cl; Ar = Ph, 2-MeC₆H₄, 4-BrC₆H₄, etc.] were readily obtained in moderate to high yields. This method proved to be compatible with a series of diaryliodonium salts as well as a set of quinoxalin-2-ones. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Synthetic Route of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Synthetic Route of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-Free C-Arylation of Nitro Compounds with Diaryliodonium Salts was written by Dey, Chandan;Lindstedt, Erik;Olofsson, Berit. And the article was included in Organic Letters in 2015.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:

An efficient, mild, and metal-free arylation of nitroalkanes with diaryliodonium salts has been developed, giving easy access to tertiary nitro compounds The reaction proceeds in high yields without the need for excess reagents and can be extended to 伪-arylation of nitroesters. Nitroalkanes were selectively C-arylated in the presence of other easily arylated functional groups, such as phenols and aliphatic alcs. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). HPLC of Formula: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed One-Pot Synthesis of Unsymmetrical Arylurea Derivatives via Tandem Reaction of Diaryliodonium Salts with N-Arylcyanamide was written by Li, Pengfei;Cheng, Guolin;Zhang, Hong;Xu, Xianxiang;Gao, Jingyuan;Cui, Xiuling. And the article was included in Journal of Organic Chemistry in 2014.Reference of 139139-80-3 The following contents are mentioned in the article:

An efficient “one-pot” approach to multiple substituted ureas from N-arylcyanamide and diaryliodonium salts has been presented. The two-step procedure involved the weak base-promoted chemoselective arylation of secondary amines with diaryliodonium and Cu-catalyzed nucleophilic addition of N-arylcyanamide with second diaryliodonium. The diverse unsym. arylureas were obtained in up to 91% yield for 29 examples. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Reference of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Reference of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)₂-catalysis was written by Guo, Fenglou;Han, Jianwei;Mao, Song;Li, Juan;Geng, Xu;Yu, Jianjun;Wang, Limin. And the article was included in RSC Advances in 2013.Formula: C19H22F3IO3S The following contents are mentioned in the article:

A novel approach towards the Pd-catalyzed arylation of electron-deficient polyfluoroarenes with diaryliodonium salts was developed. The desired fluorinated biaryls were synthesized in good yields. The mechanistic insights involving the Pd^II/IV catalytic cycle for the present reaction were discussed, which will be helpful in the understanding of catalytic arylations with diaryliodonium salts. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

tert-Butoxide-Mediated Arylation of 1-Acetylindolin-3-ones with Diaryliodonium Salts was written by Zhang, Yanxia;Han, Jianwei;Liu, Zhen-Jiang. And the article was included in Synlett in 2015.Electric Literature of C19H22F3IO3S The following contents are mentioned in the article:

A procedure for the 2-arylations of indolinone derivatives with diaryliodonium salts mediated by potassium tert-butoxide is developed. Various monoarylated indolinone derivatives are readily obtained in 24-70% yield via this method. The alkylation of monoarylated indolinone derivatives with allyl bromide or benzyl bromide affords the corresponding 2,3-disubstituted products in 60% and 70% yield, resp. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Electric Literature of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Electric Literature of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Visible-light mediated 3-component synthesis of sulfonylated coumarins from sulfur dioxide was written by Chen, Zhengkai;Liu, Nai-Wei;Bolte, Michael;Ren, Hongjun;Manolikakes, Georg. And the article was included in Green Chemistry in 2018.Application of 139139-80-3 The following contents are mentioned in the article:

A novel 3-component synthesis of sulfonylated coumarins from diaryliodonium salts, arylpropynoates and DABSO was reported. The reaction proceeded under mild conditions at room temperature in the absence of any catalysts. This transformation was solely driven by visible light and opens a new opportunity for the sustainable synthesis of sulfones via the direct incorporation of sulfur dioxide. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Application of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-Free Arylation of Ethyl Acetoacetate with Hypervalent Diaryliodonium Salts: An Immediate Access to Diverse 3-Aryl-4(1H)-Quinolones was written by Monastyrskyi, Andrii;Namelikonda, Niranjan K.;Manetsch, Roman. And the article was included in Journal of Organic Chemistry in 2015.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:

A clean arylation protocol of Et acetoacetate was developed using hypervalent diaryliodonium salts under mild and metal-free conditions. The scope of the reaction, using sym. and unsym. iodonium salts with varying sterics and electronics, was examined Further, this method has been applied for the synthesis of antimalarial compound ELQ-300, which is currently in preclin. development. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.HPLC of Formula: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Synthesis of fused polycyclic indoles via Cu(II)-catalyzed intramolecular cyclization of N-(2-cyanophenyl)indoles in the presence of diaryliodonium salts was written by Zhang, Lei;Wang, Yunpeng;Zheng, Liyao;Guo, Biao;Hua, Ruimao. And the article was included in Tetrahedron in 2017.Formula: C19H22F3IO3S The following contents are mentioned in the article:

A novel and mild method for the synthesis of fused polycyclic indoles such as I [Ar = 4-MeC₆H₄, 4-FC₆H₄, 2,5-di-MeC₆H₃, etc.] of [1,2-a]indol-10-imines via a Cu(OTf)₂-catalyzed the intramol. cyclization of N-(2-cyanophenyl)indoles in the presence of diaryliodonium salts has been developed. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-Free Synthesis of Aryl Ethers in Water was written by Lindstedt, Erik;Ghosh, Raju;Olofsson, Berit. And the article was included in Organic Letters in 2013.Synthetic Route of C19H22F3IO3S The following contents are mentioned in the article:

The first arylation of allylic and benzylic alcs. with diaryliodonium salts is reported. The reaction yields alkyl aryl ethers under mild and metal-free conditions. Phenols are arylated to diaryl ethers in good to excellent yields. The reaction employs diaryliodonium salts and sodium hydroxide in water at low temperature, and excess amounts of the coupling partners are avoided. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Synthetic Route of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.Synthetic Route of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com