Tag: 500-600

Diverse Tandem Cyclization Reactions of o-Cyanoanilines and Diaryliodonium Salts with Copper Catalyst for the Construction of Quinazolinimine and Acridine Scaffolds was written by Pang, Xinlong;Chen, Chao;Su, Xiang;Li, Ming;Wen, Lirong. And the article was included in Organic Letters in 2014.Related Products of 139139-80-3 The following contents are mentioned in the article:

Two cyclization modes are realized to produce different nitrogen-containing heterocycles, i.e., quinazolin-4(3H)-imines, e.g., I, and acridines, e.g., II, by assembling o-cyanoanilines and diaryliodonium salts via tandem reaction pathways. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Related Products of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Related Products of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Direct Arylation of Arene and N-Heteroarenes with Diaryliodonium Salts without the Use of Transition Metal Catalyst was written by Wen, Jun;Zhang, Ruo-Yi;Chen, Shan-Yong;Zhang, Ji;Yu, Xiao-Qi. And the article was included in Journal of Organic Chemistry in 2012.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

A novel and simple transition metal-free direct arylation of arene and N-heteroarenes with diaryliodonium salts has been developed. This cross-coupling reaction is promoted only by base and gives the desired products, e.g., I, in moderate to good yields. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Transition-Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts was written by Yu, Hao;Li, Zhen;Bolm, Carsten. And the article was included in Organic Letters in 2018.Recommanded Product: 139139-80-3 The following contents are mentioned in the article:

A transition-metal-free arylation of sulfenate anions generated from 尾-sulfinyl esters with diaryliodonium salts was developed. In this process, a new C-S bond is formed under mild reaction conditions providing a wide range of S,S-diaryl and S-alkyl S-aryl sulfoxides. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Recommanded Product: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole produced by Proteus, Pseudomonas, Escherichia and other species was shown to be a growth promoting factor in Arabidopsis thaliana.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Recommanded Product: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Microwave-Assisted Metal- and Ligand-Free O-Arylation of Quinolones Using Diaryliodonium Salts: An Easy and Rapid Synthesis of Aryloxyquinolines was written by Mehra, Manish Kumar;Tantak, Mukund P.;Kumar, Indresh;Kumar, Dalip. And the article was included in Synlett in 2016.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:

A microwave-assisted metal- and ligand-free direct O-arylation of quinolones has been achieved by employing easily accessible diaryliodonium salts in the presence of a base to afford various aryloxyquinolines in good yields. The operationally simple and rapid protocol has also been utilized for the construction of biol. important benzofuro[3,2-c]quinolines. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.HPLC of Formula: 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper(I)-catalyzed intermolecular cyanoarylation of alkenes: convenient access to 伪-alkylated arylacetonitriles was written by Chen, Xin-Jie;Gui, Qing-Wen;Yi, Rongnan;Yu, Xianyong;Wu, Zhi-Lin;Huang, Ying;Cao, Zhong;He, Wei-Min. And the article was included in Organic & Biomolecular Chemistry in 2020.Synthetic Route of C19H22F3IO3S The following contents are mentioned in the article:

A novel Cu(I)-catalyzed intermol. cyanoarylation of alkenes with diaryliodonium salts as a radical arylating reagent and tetra-butylammonium cyanide as an electrophilic cyanating reagent was established. A broad range of 伪-alkylated arylacetonitriles were efficiently constructed in good to excellent yields under base- and oxidant-free and mild conditions. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Synthetic Route of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Synthetic Route of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed Electrophilic Arylation of Isatoic Anhydride with Diaryliodonium Salts for Synthesis of N-Phenylated Isatoic Anhydrides was written by Wu, Xi-Xi;He, Yonghui;Zhao, Xiao-Jing;Li, Ganpeng. And the article was included in Asian Journal of Organic Chemistry in 2022.Formula: C19H22F3IO3S The following contents are mentioned in the article:

A copper-catalyzed N-arylation of various isatoic anhydrides with diaryliodonium salts was developed by using inexpensive CuI as the catalyst under mild conditions. The method provided diverse N-phenylated isatoic anhydrides in high yields (up to 97%). The mechanism of the N-arylation reaction was proposed to involve an electrophilic addition process. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Arylation of Lithium Sulfinates with Diaryliodonium Salts: A Direct and Versatile Access to Arylsulfones was written by Umierski, Natalie;Manolikakes, Georg. And the article was included in Organic Letters in 2013.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

An efficient, transition-metal-free arylation of lithium sulfinates, which are readily accessible from reactions of organolithium reagents with sulfur dioxide, is described. Based on this method, a practical protocol for the direct transformation of (hetero)arenes and (hetero)aromatic halides into diarylsulfones was developed. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Cesium Carbonate Promoted Direct Arylation of Hydroxylamines and Oximes with Diaryliodonium Salts was written by Yang, Yang;Wu, Xunshen;Han, Jianwei;Mao, Song;Qian, Xiaofei;Wang, Limin. And the article was included in European Journal of Organic Chemistry in 2014.Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:

A transition-metal-free approach for the arylation of hydroxylamines and oximes with diaryliodonium salts was developed. The reaction proceeded smoothly at room temperature in the presence of cesium carbonate. As a result, a wide range of N- and O-arylated hydroxylamines were synthesized in good to excellent yields (45-98 %). This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Base-Promoted Coupling of Carbon Dioxide, Amines and Diaryliodonium Salts: A Phosgene- and Metal-Free Route to O-Aryl Carbamates was written by Xiong, Wenfang;Qi, Chaorong;Peng, Youbin;Guo, Tianzuo;Zhang, Min;Jiang, Huanfeng. And the article was included in Chemistry – A European Journal in 2015.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:

A phosgene- and metal-free synthesis of O-aryl carbamates is realized through a three-component coupling of carbon dioxide, amines, and diaryliodonium salts. The reaction only requires a base as the promoter, providing access to a diverse array of O-aryl carbamates in moderate to high yields with excellent chemoselectivity. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Name: Bis(2,4,6-trimethylphenyl)iodonium triflate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-Free N-Arylation of Secondary Amides at Room Temperature was written by Tinnis, Fredrik;Stridfeldt, Elin;Lundberg, Helena;Adolfsson, Hans;Olofsson, Berit. And the article was included in Organic Letters in 2015.Application of 139139-80-3 The following contents are mentioned in the article:

The arylation of secondary acyclic amides has been achieved with diaryliodonium salts under mild and metal-free conditions. The methodol. has a wide scope, allows synthesis of tertiary amides with highly congested aryl moieties, and avoids the regioselectivity problems observed in reactions with (diacetoxyiodo)benzene. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Application of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com