Li, Hongbo et al. published their research in Chemical Science in 2018 | CAS: 77350-52-8

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Quality Control of N,N-Diethyl-4-iodobenzamide

Silylation reactions on nanoporous gold via homolytic Si-H activation of silanes was written by Li, Hongbo;Guo, Huifang;Li, Zhiwen;Wu, Cai;Li, Jing;Zhao, Chunliang;Guo, Shuangxi;Ding, Yi;He, Wei;Li, Yadong. And the article was included in Chemical Science in 2018.Quality Control of N,N-Diethyl-4-iodobenzamide This article mentions the following:

Si-H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein, homolytic activation of Si-H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]-[Si] intermediates is discovered. By virtue of this new reactivity, highly selective mono and sequential alcoholysis of dihydrosilane is achieved. In addition, the amphiphilic nature of the [Au]-[Si] intermediate allows for a new bis-silylation reaction of cyclic ethers. The present work showcased that the surface reactivity of nanocatalysts may provide exciting opportunity for new reaction discovery. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Quality Control of N,N-Diethyl-4-iodobenzamide).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Quality Control of N,N-Diethyl-4-iodobenzamide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Kunz, Peter C. et al. published their research in Journal of Organometallic Chemistry in 2012 | CAS: 15813-09-9

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Application of 15813-09-9

Ruthenium piano-stool complexes bearing imidazole-based PN ligands was written by Kunz, Peter C.;Thiel, Indre;Noffke, Anna Louisa;Reiss, Guido J.;Mohr, Fabian;Spingler, Bernhard. And the article was included in Journal of Organometallic Chemistry in 2012.Application of 15813-09-9 This article mentions the following:

A variety of piano-stool complexes of cyclopentadienyl Ru(II) with imidazole-based PN ligands were synthesized starting from the precursor complexes [CpRu(C10H8)]PF6, [CpRu(NCMe)3]PF6 and [CpRu(PPh3)2Cl]. PN ligands used are imidazol-2-yl, -4-yl and -5-yl phosphines. Depending on the ligand and precursor different types of coordination modes were observed; in the case of polyimidazolyl PN ligands these were κ1P-monodentate, κ2P,N-, κ2N,N- and κ3N,N,N-chelating and μ-κP:κ2N,N-bridging. The solid-state structures of [CpRu(1a)2Cl]·H2O (5·H2O, 1a = imidazol-2-yldiphenylphosphine), [{CpRu(μ-κP:κ2N,N-2b)}2](C6H5PO3H)2(C6H5PO3H2)2 (2b = bis(1-methylimidazol-2-yl)phenylphosphine), a hydrolysis product of the as well determined [{CpRu(μ-κP:κ2N,N-2b)}2](PF6)2·2MeCN (7b·2MeCN), [CpRu(κ1P-3a)(PPh3)]Cl·CH2Cl2 (9·CH2Cl2, 3a = tris(imidazol-2-yl)phosphine) and [CpRu(PPh3)2Cl]·CHCl3 were determined Furthermore, [CpRu(L)2]PF6 (L = imidazol-2-yl or imidazol-4-yl phosphine) were screened for their catalytic activity in the hydration of 1-octyne. In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9Application of 15813-09-9).

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Application of 15813-09-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Sohmiya, Hajime et al. published their research in Chemistry Letters in 1991 | CAS: 3268-21-1

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.COA of Formula: C10H12I2

Solid-state organic reactions proceeding by pulverization of inorganic solid-supports. Reactions of iodosobenzene with unsaturated hydrocarbons on acid-treated silica gel was written by Sohmiya, Hajime;Kimura, Takahide;Bauchat, Patrick;Fujita, Mitsue;Ando, Takashi. And the article was included in Chemistry Letters in 1991.COA of Formula: C10H12I2 This article mentions the following:

Pulverization of solid mixtures of hydrogen halide-treated silica gels, PhIO, and alkenes or an alkyne in the absence of a solvent causes smooth and rapid reaction to give halogenated or oxidized products in good yields. Thus, treating trans-PhCH:CHPh with HCl-treated silica gel and PhIO in the solid state gives meso– and dl-PhCCl:CClPh in 65% overall yield. In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1COA of Formula: C10H12I2).

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.COA of Formula: C10H12I2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Ito, Akitaka et al. published their research in Inorganic Chemistry in 2012 | CAS: 3268-21-1

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.Safety of 1,4-Diiodo-2,3,5,6-tetramethylbenzene

Photophysical and Photoredox Characteristics of a Novel Tricarbonyl Rhenium(I) Complex Having an Arylborane-Appended Aromatic Diimine Ligand was written by Ito, Akitaka;Kang, Yuanyuan;Saito, Shota;Sakuda, Eri;Kitamura, Noboru. And the article was included in Inorganic Chemistry in 2012.Safety of 1,4-Diiodo-2,3,5,6-tetramethylbenzene This article mentions the following:

We report the synthesis and photophys./photoredox characteristics of a novel tricarbonyl rhenium(I) complex having a (dimesityl)boryldurylethynyl (DBDE) group at the 4-position of a 1,10-phenanthroline (phen) ligand, [Re(CO)3(4-DBDE-phen)Br] (ReB). ReB in THF at 298 K showed the metal-to-ligand charge transfer (MLCT) emission at around 681 nm with the lifetime (τem) of 900 ns. The relatively long emission lifetime of ReB compared with that of [Re(CO)3(phen)Br] (RePhen, τem = 390 ns) was discussed on the basis of the temperature dependent τem and Franck-Condon anal. of the emission spectra of the two complexes. Emission quenching studies of both ReB and RePhen by a series of electron donors revealed that the photoinduced electron transfer (PET) quenching rate constant of ReB was faster than that of RePhen at a given Gibbs free energy change of the PET reaction (ΔGET0 > -0.5 eV). All of the results on ReB were discussed in terms of the contribution of the CT interaction between the π-orbital(s) of the aryl group(s) and the vacant p-orbital on the boron atom in DBDE to the MLCT state of the complex. In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1Safety of 1,4-Diiodo-2,3,5,6-tetramethylbenzene).

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.Safety of 1,4-Diiodo-2,3,5,6-tetramethylbenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Gai, Xinjie et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2001 | CAS: 77350-52-8

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Iodide-containing intermediates are common in organic synthesis, because of the easy formation and cleavage of the C–I bond. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Recommanded Product: N,N-Diethyl-4-iodobenzamide

Palladium catalysed 3-component cascade synthesis of bis(2-arylallyl) tertiary amines from aryl iodides, allene and primary amines was written by Gai, Xinjie;Grigg, Ronald;Collard, Simon;Muir, Jayne E.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2001.Recommanded Product: N,N-Diethyl-4-iodobenzamide This article mentions the following:

A 3-component cascade synthesis of bis(2-arylallyl) tertiary amines from aryl iodide, allene, and primary aliphatic amines is described. Chiral amines give analogous products with no detectable racemization. Mixtures of two different aryl iodides can be utilized to give the mixed tertiary amines as the sole, or major, product. The reaction is sensitive to stereoelectronic effects which lead to mono(2-arylallyl) secondary amines. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Recommanded Product: N,N-Diethyl-4-iodobenzamide).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Iodide-containing intermediates are common in organic synthesis, because of the easy formation and cleavage of the C–I bond. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Recommanded Product: N,N-Diethyl-4-iodobenzamide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Chaikovski, V. K. et al. published their research in Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya) in 2001 | CAS: 3268-21-1

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.Application In Synthesis of 1,4-Diiodo-2,3,5,6-tetramethylbenzene

2,4,6,8-Tetraiodo-2,4,6,8-tetraazabicyclo[3.3.0]octane-3,7-dione as a mild and convenient reagent for iodination of aromatic compounds was written by Chaikovski, V. K.;Filimonov, V. D.;Yagovkin, A. Yu.;Ogorodnikov, V. D.. And the article was included in Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya) in 2001.Application In Synthesis of 1,4-Diiodo-2,3,5,6-tetramethylbenzene This article mentions the following:

2,4,6,8-Tetraiodo-2,4,6,8-tetraazabicyclo[3.3.0]octane-3,7-dione (tetraiodoglycoluril) is a convenient reagent for preparative iodination of benzene, alkylbenzenes, polycyclic hydrocarbons, aromatic amines, and phenol ethers in organic solvents under mild conditions. In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1Application In Synthesis of 1,4-Diiodo-2,3,5,6-tetramethylbenzene).

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.Application In Synthesis of 1,4-Diiodo-2,3,5,6-tetramethylbenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Januszewski, Estera et al. published their research in Organometallics in 2012 | CAS: 3268-21-1

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Related Products of 3268-21-1

Influence of the Bridging Elements on the Optical Properties of Linked 9,10-Dihydro-9,10-diboraanthracenes was written by Januszewski, Estera;Bolte, Michael;Lerner, Hans-Wolfram;Wagner, Matthias. And the article was included in Organometallics in 2012.Related Products of 3268-21-1 This article mentions the following:

Starting from the monofunctionalized 9,10-dihydro-9,10-diboraanthracene derivatives MesB(C6H4)2BX (X = H, Br), the bridged systems MesB(C6H4)2B-L-B(C6H4)2BMes have been synthesized with L = -C(H):C(H)(p-C6Me4)C(H):C(H)- (5), -CC(p-C6Me4)CC- (6), and -(p-C6H4)(p-C6Me4)(p-C6H4)- (7). The compounds were characterized by NMR, IR, UV/vis, and fluorescence spectroscopy. The vinyl- and phenylboranes 5 and 7 are pale yellow solids, whereas the alkynylborane 6 possesses a bright yellow color. The emission maxima of 57 in toluene are λmax(em) 477, 460, and 461 nm with quantum yields ϕf of 0.02, 0.30, and 0.04, resp. Alkynylborane 6 was the least air- and moisture-sensitive of the three derivatives In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1Related Products of 3268-21-1).

1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Related Products of 3268-21-1

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Garden, S. J. et al. published their research in Tetrahedron Letters in 2001 | CAS: 15813-09-9

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.COA of Formula: C3H2I2N2

Aromatic iodination in aqueous solution. A new lease of life for aqueous potassium dichloroiodate was written by Garden, S. J.;Torres, J. C.;de Souza Melo, S. C.;Lima, A. S.;Pinto, A. C.;Lima, E. L. S.. And the article was included in Tetrahedron Letters in 2001.COA of Formula: C3H2I2N2 This article mentions the following:

A re-investigation of the use of aqueous KICl2 as an iodinating agent for aromatic compounds has found the reagent to be more generally applicable than previously known. The reagent gives excellent yields of iodinated heterocyclic compounds, such as isatin, imidazole, and pyrazole. In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9COA of Formula: C3H2I2N2).

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.COA of Formula: C3H2I2N2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

He, Chunlin et al. published their research in Inorganic Chemistry in 2016 | CAS: 15813-09-9

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Category: iodides-buliding-blocks

Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents was written by He, Chunlin;Hooper, Joseph P.;Shreeve, Jean’ne M.. And the article was included in Inorganic Chemistry in 2016.Category: iodides-buliding-blocks This article mentions the following:

Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3) or periodate (IO4) anions were synthesized. The synthesis of analogous I3O8 salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by IR, 1H NMR, and 13C NMR spectroscopy as well as elemental analyses. The mol. structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Addnl., the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7. In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9Category: iodides-buliding-blocks).

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Benson, Timothy J. et al. published their research in Journal of the Chemical Society in 1992 | CAS: 15813-09-9

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.COA of Formula: C3H2I2N2

A new and unequivocal method for establishing the position of N-glycosylation of unsymmetrically C-substituted imidazoles was written by Benson, Timothy J.;Robinson, Brian. And the article was included in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) in 1992.COA of Formula: C3H2I2N2 This article mentions the following:

N-Substitution of an unsym. C-substituted imidazole can give rise to a pair of structurally isomeric derivatives and to differentiate between such related compounds can be difficult. Two methods, one spectroscopic and one chem., for ascertaining the orientation of such N-substitutions are described, with particular application to the establishment of the direction of N-ribosidation of a series of halogeno nitroimidazoles. In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9COA of Formula: C3H2I2N2).

4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.COA of Formula: C3H2I2N2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com