Category: 77350-52-8

Chemoselective Coupling of 1,1-Bis[(pinacolato)boryl]alkanes for the Transition-Metal-Free Borylation of Aryl and Vinyl Halides: A Combined Experimental and Theoretical Investigation was written by Lee, Yeosan;Baek, Seung-yeol;Park, Jinyoung;Kim, Seoung-Tae;Tussupbayev, Samat;Kim, Jeongho;Baik, Mu-Hyun;Cho, Seung Hwan. And the article was included in Journal of the American Chemical Society in 2017.HPLC of Formula: 77350-52-8 This article mentions the following:

A new transition-metal-free borylation of aryl and vinyl halides using 1,1-bis[(pinacolato)boryl]alkanes as boron sources is described. In this transformation one of the boron groups from 1,1-bis[(pinacolato)boryl]alkanes is selectively transferred to aryl and vinyl halides in the presence of sodium tert-butoxide as the only activator to form organoboronate esters. Under the developed borylation conditions, a broad range of organohalides are borylated with excellent chemoselectivity and functional group compatibility, thus offering a rare example of a transition-metal-free borylation protocol. Exptl. and theor. studies have been performed to elucidate the reaction mechanism, revealing the unusual formation of Lewis acid/base adduct between organohalides and 浼?borylcarbanion, generated in situ from the reaction of 1,1-bis[(pinacolato)boryl]alkanes with an alkoxide base, to facilitate the borylation reactions. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8HPLC of Formula: 77350-52-8).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. Polyiodoorganic compounds are sometimes employed as X-ray contrast agents, in fluoroscopy, a type of medical imaging. This application exploits the X-ray absorbing ability of the heavy iodine nucleus.HPLC of Formula: 77350-52-8

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol was written by Wang, Yulei;Huang, Zhidao;Huang, Zheng. And the article was included in Nature Catalysis in 2019.Safety of N,N-Diethyl-4-iodobenzamide This article mentions the following:

An iridium complex catalyzed semi-hydrogenation of internal alkynes using ethanol as hydrogen donor to afford E-alkenes and Et acetate was reported. Importantly, issues of over-reduction and stereoselection was successfully addressed by using a color change effect due to shift of catalyst resting states, thereby precisely detecting the endpoint of the reaction. This catalytic system was applicable to a wide variety of internal alkynes bearing many auxiliary functional groups, and its utility for synthesis of biol. relevant mols. was also demonstrated. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Safety of N,N-Diethyl-4-iodobenzamide).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons鑱砈mith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Safety of N,N-Diethyl-4-iodobenzamide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications was written by Wang, Dong-Yu;Wang, Chao;Uchiyama, Masanobu. And the article was included in Journal of the American Chemical Society in 2015.Synthetic Route of C11H14INO This article mentions the following:

We have developed a highly efficient, practical, polycyclic aromatic hydrocarbon (PAH)-catalyzed synthesis of stannyl lithium (Sn-Li), in which the tin resource (stannyl chloride or distannyl) is rapidly and quant. transformed into Sn-Li reagent at room temperature without formation of any (toxic) byproducts. The resulting Sn-Li reagent can be stored at ambient temperature for months and shows high reactivity toward various substrates, with quant. atom efficiency. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Synthetic Route of C11H14INO).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Synthetic Route of C11H14INO

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

C-H functionalization of amines with aryl halides by nickel-photoredox catalysis was written by Ahneman, Derek T.;Doyle, Abigail G.. And the article was included in Chemical Science in 2016.SDS of cas: 77350-52-8 This article mentions the following:

Synthesis of phenylpyrrolidines e.g., I via functionalization of α-amino C-H bonds with aryl halides using a combination of nickel and photoredox catalysis was described. This direct C-H, C-X coupling uses inexpensive and readily available starting materials to generate benzylic amines, an important class of bioactive mols. Mechanistically, this method features the direct arylation of α-amino radicals mediated by a nickel catalyst. This reactivity was demonstrated for a range of aryl halides and N-aryl amines, with orthogonal scope to existing C-H activation and photoredox methodologies. Reactions with several complex aryl halides, demonstrating the potential utility of this approach in late-stage functionalization was also reported. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8SDS of cas: 77350-52-8).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. A typical method for synthesis of aromatic iodides is diazotization of primary aromatic amines followed by treatment of potassium iodide. Aliphatic alcohols are converted to alkyl iodides by treating with hydrogen iodide.SDS of cas: 77350-52-8

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation was written by Roberts, Bryan;Liptrot, David;Alcaraz, Lilian;Luker, Tim;Stocks, Michael J.. And the article was included in Organic Letters in 2010.SDS of cas: 77350-52-8 This article mentions the following:

A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation A range of reactions illustrating the wide scope of this chem. were carried out and proceeded in good to excellent yields. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8SDS of cas: 77350-52-8).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.SDS of cas: 77350-52-8

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Excited-State Structure and Delocalization in Ruthenium(II)-Bipyridine Complexes That Contain Phenyleneethynylene Substituents was written by Wang, Yingsheng;Liu, Shengxia;Pinto, Mauricio R.;Dattelbaum, Dana M.;Schoonover, Jon R.;Schanze, Kirk S.. And the article was included in Journal of Physical Chemistry A in 2001.Category: iodides-buliding-blocks This article mentions the following:

A comprehensive photophys. study was carried out on the two prepared complexes [(bpy)₂Ru(4,4′-PE-bpy)]²⁺ and [(bpy)₂Ru(5,5′-PE-bpy)]²⁺ (44Ru and 55Ru, resp., where bpy = 2,2′-bipyridine and PE = phenyleneethynylene 4-Et₂NCOC₆H₄CC-). The objective of this work is to determine the effect of the phenyleneethynylene substituents on the properties of the metal-to-ligand charge-transfer excited state. The complexes were characterized by using UV-visible absorption, photoluminescence, and UV-visible and IR transient absorption spectroscopy. The results indicate that the MLCT excited state is localized on the PE-substituted bpy ligands. Also, the photophys. data indicate that in the MLCT excited state the excited electron is delocalized into the PE substituents and the manifestations of the electronic delocalization are larger when the substituents are in the 4,4′-positions. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Category: iodides-buliding-blocks).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

A Modular Approach to Arylazo-1,2,3-triazole Photoswitches was written by Tuck, Jeremy R.;Tombari, Robert J.;Yardeny, Noah;Olson, David E.. And the article was included in Organic Letters in 2021.Name: N,N-Diethyl-4-iodobenzamide This article mentions the following:

Azoheteroarenes make up an emerging class of photoswitchable compounds with unique photophys. properties and advantages over traditional azobenzenes. Therefore, methods for synthesizing azoheteroarenes are highly desirable. Here, we utilize azide-alkyne click chem. to access arylazo-1,2,3-triazoles, a previously unexplored class of azoheteroarenes that exhibit high thermal stabilities and near-quant. bidirectional photoconversion. Controlling the catalyst or 1,3-dipole grants access to both regioisomeric arylazotriazoles and arylazoisoxazoles, highlighting the versatility of our approach. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Name: N,N-Diethyl-4-iodobenzamide).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Name: N,N-Diethyl-4-iodobenzamide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Palladium-catalyzed asymmetric coupling cyclization of terminal γ-allenols with aryl iodides was written by Xie, Xi;Ma, Shengming. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2013.Quality Control of N,N-Diethyl-4-iodobenzamide This article mentions the following:

A Pd-catalyzed asym. coupling cyclization of γ-allenols with aryl iodides has been developed. α-(Tetrahydrofuran-2-yl)styrene derivatives can be prepared in 60-86% yields with ee values ranging from 85-92%. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Quality Control of N,N-Diethyl-4-iodobenzamide).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I. This periodic order also follows the atomic radius of halogens and the length of the carbon-halogen bond.Quality Control of N,N-Diethyl-4-iodobenzamide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group was written by Gulevich, Anton V.;Melkonyan, Ferdinand S.;Sarkar, Dhruba;Gevorgyan, Vladimir. And the article was included in Journal of the American Chemical Society in 2012.Recommanded Product: 77350-52-8 This article mentions the following:

The efficient Pd-catalyzed double-fold C-H oxygenation of arenes into resorcinols e. g., I using the newly developed 2-pyrimidyldiisopropylsilyl (PyrDipSi) directing group is described. Its use allows for the sequential introduction of OAc and OPiv groups in a one-pot manner to produce orthogonally protected resorcinol derivatives The PyrDipSi group is superior to the previously developed 2-pyridyldiisopropylsilyl (PyDipSi) group, as it is efficient for monooxygenation of ortho-substituted arenes. Notably, the PyrDipSi group can be easily installed into arene mols. and can be easily removed or modified after the oxygenation reaction. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8Recommanded Product: 77350-52-8).

N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Recommanded Product: 77350-52-8

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com