Category: 64248-57-3

Intramolecular Through-Space Charge Transfer Based TADF-Active Multifunctional Emitters for High Efficiency Solution-Processed OLED was written by Li, Bing;Yang, Zhan;Gong, Wenqi;Chen, Xinhui;Bruce, Duncan W.;Wang, Shengyue;Ma, Huili;Liu, Yu;Zhu, Weiguo;Chi, Zhenguo;Wang, Yafei. And the article was included in Advanced Optical Materials in 2021.COA of Formula: C6H3F2I This article mentions the following:

Thermally activated delayed fluorescence (TADF) has been explored actively in luminescent organic materials. Yet, realizing such TADF-active, multifunctional emitters with high emission efficiency still remains hugely challenging. In this context, a series of twist-conjugated organic mols. bearing diphenylsulfone and 9,9-dimethylacridine moieties are designed and prepared, and are found to show, in one mol., TADF, room-temperature phosphorescence, triboluminescence, and aggregation-induced emission enhancement. In addition, remarkably high photoluminescence quantum efficiency, up to 閳?00%, is achieved for these novel mols. Single-crystal anal. and theor. calculations reveal that the through-space charge transfer (TSCT) effect in these mols. is responsible for both the multifunctional emission and high emission efficiency. A maximum external quantum efficiency of 20.1% is achieved, which is among the highest recorded in a solution-processable device containing TSCT-based TADF materials. These results illustrate a new approach to achieving highly efficient TADF-active, multifunctional emitters. In the experiment, the researchers used many compounds, for example, 1,2-Difluoro-3-iodobenzene (cas: 64248-57-3COA of Formula: C6H3F2I).

1,2-Difluoro-3-iodobenzene (cas: 64248-57-3) belongs to iodide derivatives. Organoiodine compounds occur widely in organic chemistry, but are relatively rare in nature. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.COA of Formula: C6H3F2I

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Palladium-Catalyzed Carbonylative Four-Component Synthesis of Thiochromenones: The Advantages of a Reagent Capsule was written by Shen, Chaoren;Spannenberg, Anke;Wu, Xiao-Feng. And the article was included in Angewandte Chemie, International Edition in 2016.Safety of 1,2-Difluoro-3-iodobenzene This article mentions the following:

Multicomponent reactions, especially those involving four or even more reagents, have been a long-standing challenge because of the issues associated with balancing reactivity, selectivity, and compatibility. Herein, we demonstrate how the use of a reagent capsule provides straightforward access to synthetically valuable thiochromenone derivatives by a palladium-catalyzed carbonylative four-component reaction. To the best of our knowledge, this is the first example of applying a capsule to prevent catalyst poisoning and undesired side reactions of the multicomponent reaction. In the experiment, the researchers used many compounds, for example, 1,2-Difluoro-3-iodobenzene (cas: 64248-57-3Safety of 1,2-Difluoro-3-iodobenzene).

1,2-Difluoro-3-iodobenzene (cas: 64248-57-3) belongs to iodide derivatives. Iodide-containing intermediates are common in organic synthesis, because of the easy formation and cleavage of the C–I bond. Polyiodoorganic compounds are sometimes employed as X-ray contrast agents, in fluoroscopy, a type of medical imaging. This application exploits the X-ray absorbing ability of the heavy iodine nucleus.Safety of 1,2-Difluoro-3-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Liquid crystals for IR: Part II synthesis and properties of perfluoroalkyl- or perfluoroalkoxy-terminated tolanes was written by Harmata, Piotr;Herman, Jakub;Kula, Przemyslaw. And the article was included in Liquid Crystals in 2020.COA of Formula: C6H3F2I This article mentions the following:

Several homologous series of laterally halogenated and perfluoroalkyl- or perfluoroalkoxy-terminated tolanes derivatives were synthesized. Obtained compounds were divided into three families, i.e. tolanes, phenyltolanes, bistolanes and their mesomorphic properties, phase transition temperatures and enthalpies were determined The influence of the length of the core, type and position of substituents in the mol. core has been analyzed. The lack of aliphatic protons in mol. structure generates unique IR properties of presented materials and their mixtures In the experiment, the researchers used many compounds, for example, 1,2-Difluoro-3-iodobenzene (cas: 64248-57-3COA of Formula: C6H3F2I).

1,2-Difluoro-3-iodobenzene (cas: 64248-57-3) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. A typical method for synthesis of aromatic iodides is diazotization of primary aromatic amines followed by treatment of potassium iodide. Aliphatic alcohols are converted to alkyl iodides by treating with hydrogen iodide.COA of Formula: C6H3F2I

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Highly Z-selective synthesis of 1,3-oxathiol-2-ylidenes and 4-methylene-oxazolidine-2-thiones via atom-specific 5-exo-dig cyclization of propargyl alcohol with isothiocyanate was written by Antony Savarimuthu, S.;Leo Prakash, D. G.;Augustine Thomas, S.;Gandhi, Thirumanavelan;Bera, Mrinal K.. And the article was included in Organic & Biomolecular Chemistry in 2020.Application In Synthesis of 1,2-Difluoro-3-iodobenzene This article mentions the following:

A series of 3,4,5-trisubstituted (Z)-1,3-oxathiol-2-ylidenes I (R = 2-ClC₆H₄, 4-t-BuC₆H₄, etc.; R¹ = Ph, 2-FC₆H₄, 4-BrC₆H₄, etc.; R² = Ph, 4-FC₆H₄) was synthesized via DBU-mediated 5-exo-dig cyclization of isothiocyanates RNCS and propargyl alcs. R¹CH(OH)CCR². Exclusive S-nucleophilic cyclization was observed with propargyl alcs. R³CCCH₂OH (R³ = Ph, 2,3-F₂C₆H₃, 4-O₂NC₆H₄, etc.) and isothiocyanates RNCS to produce the corresponding 3,4-disubstituted (Z)-N-(Z)-4-ethylidene-1,3-oxathiolan-2-ylidenes II. Also, the parent propargyl alc. and isothiocyanates underwent an N-nucleophilic attack to afford 4-methyleneoxazolidine-2-thiones III. In the experiment, the researchers used many compounds, for example, 1,2-Difluoro-3-iodobenzene (cas: 64248-57-3Application In Synthesis of 1,2-Difluoro-3-iodobenzene).

1,2-Difluoro-3-iodobenzene (cas: 64248-57-3) belongs to iodide derivatives. Iodide-containing intermediates are common in organic synthesis, because of the easy formation and cleavage of the C–I bond. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Application In Synthesis of 1,2-Difluoro-3-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Fine electronic state tuning of cobaltadithiolene complexes by substituent groups on the benzene ring was written by Tsukada, Satoru;Kondo, Masataka;Sato, Hironobu;Gunji, Takahiro. And the article was included in Polyhedron in 2016.Electric Literature of C6H3F2I This article mentions the following:

A series of 3,6- and 4,5-dihalogen-substituted 1,2-benzenedithiol (H₂bdt) ligands, (3,6-X¹₂-4,5-X²₂-1,2-H₂bdt) (X² = H, X¹ = F (1a), Cl (1b), Br (1c); X¹ = H, X² = Cl (4)), and their cobalt complexes, [Cp^*Co(3,6-X¹₂-4,5-X²₂-1,2-bdt)] (X² = H, X¹ = F (2a), Cl (2b), Br (2c); X¹ = H, X² = Cl (5)), were synthesized by a modified selective thiolation reaction. The 1,2-diphenyl-substituted cobaltadithiolene complex (2d) was also synthesized. The mol. structures of all cobaltadithiolene complexes were determined by single crystal X-ray diffraction anal. Compounds 2a, 5 and 12 showed unique packing structures with intermol. interactions that confirmed them as the first examples of half-sandwich-type metalladithiolene complexes with a Cp^* ligand. The effects of the benzene substituent type and position on the metalladithiolene ring were investigated using UV-vis spectroscopy measurements and cyclic voltammetry. The results indicate that substitution of halogen atoms at the 3 and 6 position of the benzene ring had a larger effect on the dithiolene ring than substitution at the 4 and 5 positions. In the experiment, the researchers used many compounds, for example, 1,2-Difluoro-3-iodobenzene (cas: 64248-57-3Electric Literature of C6H3F2I).

1,2-Difluoro-3-iodobenzene (cas: 64248-57-3) belongs to iodide derivatives. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Electric Literature of C6H3F2I

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com