Category: 626-01-7

Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. COA of Formula: C6H6IN.

Zhang, Yuyan;Shamzhy, Mariya;Kubu, Martin;Cejka, Jiri research published 《 Nanosponge hierarchical micro-mesoporous MFI zeolites as a high-performance catalyst for the hydroamination of methyl acrylate with aniline》, the research content is summarized as follows. Zeolites catalyze the hydroamination of alkenes, alkynes and dienes, yielding valuable amines, enamines and imines with high efficiency and chemoselectivity (i.e., Markovnikov or anti-Markovnikov products) thanks to the architecture of their pore system and tunable acidity. However, their micropores may impose mass-transfer constraints on reaction rates. Nevertheless, the high external surface area of hierarchical micro-mesoporous zeolites should enable them to outperform conventional zeolites. To test our hypothesis, we compared the activity of hierarchical MFI zeolites of different crystal morphologies (i.e., nanosponge, nanosheet and microcrystalline desilicated samples) with that of conventional medium- (MFI) and large-pore (MOR and Beta) zeolites in the hydroamination of Me acrylate with aniline. The results showed that nanosponge MFI had the highest activity (TOF = 32.9 h^-1), reaching 57% yield of the anti-Markovnikov product N-[2-(methoxycarbonyl)ethyl]aniline. Furthermore, our kinetic study revealed a pseudo-second-order rate law with respect to aniline over the most active nanosponge MFI catalyst, with an apparent activation energy of 68.9 kJ/mol. The high external surface of this catalyst (371 m²/g) and its developed inter-crystalline mesopores (4.8 nm) suggest a kinetic-driven hydroamination reaction. Therefore, hierarchical nanosponge aluminosilicate MFI zeolites stand out as promising heterogeneous catalysts of hydroamination reactions involving bulky substrates.

626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., COA of Formula: C6H6IN

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Reference of 626-01-7.

Zhao, Bin;Hammond, Gerald B.;Xu, Bo research published 《 Modulation of photochemical oxidation of thioethers to sulfoxides or sulfones using an aromatic ketone as the photocatalyst》, the research content is summarized as follows. An eco-friendly and chemo-selective photocatalytic synthesis of sulfoxides, e.g., 2-(methylsulfinyl)quinoline or sulfones, e.g., 2-(methylsulfonyl)quinoline via oxidation of sulfides, e.g., 2-(methylthio)quinoline (thioethers) at ambient temperature using air or O₂ as the oxidant has been described. An inexpensive thioxanthone was used as the photocatalyst. This method offers excellent chem. yields and good functional group tolerance. The hydrogen bonding between hexafluoro-2-propanol (HFIP) and sulfoxides may play an important role in minimizing the over-oxidization of sulfoxides.

Reference of 626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Iodide is one of the largest monatomic anions. It is assigned a radius of around 206 picometers. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.For comparison, the lighter halides are considerably smaller: bromide (196 pm), chloride (181 pm), and fluoride (133 pm). In part because of its size, iodide forms relatively weak bonds with most elements. Recommanded Product: 3-Iodoaniline.

Zhong, Shuting;Fang, Xianfu;Wang, Yiting;Zhang, Gong;Li, Yangfeng;Li, Yizhou research published 《 DNA-compatible diversification of indole π-activated alcohols via a direct dehydrative coupling strategy》, the research content is summarized as follows. Indole-based diversification is highly desired in the DNA-encoded chem. library construction. Herein, we present a general strategy for on-DNA synthesis of diverse C3-functionalized indole derivatives via indole π-activated alc. formation followed by direct dehydrative coupling. Highly efficient bond linkages of C-C, C-N, and C-S were achieved to fuse building blocks that are widely com. available. DNA-encoding compatibility of the method has been further demonstrated to pave an avenue for application in constructing indole-focused three-dimensional libraries.

Recommanded Product: 3-Iodoaniline, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Product Details of C6H6IN.

Zhou, Shengbin;Zhang, Zhichao;Bai, Dongjie;Li, Jingzhe;Cui, Xiang;Xu, Zhichuan J.;Tang, Yu;Tang, Xiaoliang;Liu, Weisheng research published 《 A Discrete 3d-4f Metallacage as an Efficient Catalytic Nanoreactor for a Three-Component Aza-Darzens Reaction》, the research content is summarized as follows. The exploration and development of coordination nanocages can provide an approach to control chem. reactions beyond the bounds of the flask, which has aroused great interest due to their significant applications in the field of mol. recognition, supramol. catalysis, and mol. self-assembly. Herein, the authors employ a semirigid and nonsym. bridging ligand (H₅L) with rich metal-chelating sites to construct an unusual and discrete 3d-4f metallacage, [Zn₂Er₄(H₂L)₄(NO₃)Cl₂(H₂O)]·NO₃·xCH₃OH·yH₂O (Zn₂Er₄). The 3d-4f Zn₂Er₄ cage possesses a quadruple-stranded structure, and all of the ligands wrap around an open spherical cavity within the core. The self-assembly of the unique cage not only ensures the structural stability of the Zn₂Er₄ cage as a nanoreactor in solution but also makes the bimetallic lanthanide cluster units active sites that are exposed in the medium-sized cavity. It is important to note that the Zn₂Er₄ cage as a homogeneous catalyst was successfully applied to catalyze three-component aza-Darzens reactions of formaldehyde, anilines, and α-diazo esters without another additive under mild conditions, displaying better catalytic activity, higher specificity, short reaction time, and low catalyst loadings. A possible mechanism for this three-component aza-Darzens reaction catalyzed by the Zn₂Er₄ cage is proposed. These exptl. results demonstrated the great potential of the discrete 3d-4f metallacage as a host nanoreactor for the development of supramol. or mol. catalysis.

Product Details of C6H6IN, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Computed Properties of 626-01-7.

Zhou, Wenting;Li, Laiyang;Qin, Ruixuan;Zhu, Jiaxin;Liu, Shengjie;Mo, Shiguang;Shi, Zaifa;Fang, Huihuang;Ruan, Pengpeng;Cheng, Jun;Fu, Gang;Zheng, Nanfeng research published 《 Non-contact biomimetic mechanism for selective hydrogenation of nitroaromatics on heterogeneous metal nanocatalysts》, the research content is summarized as follows. While the enzymic reduction of unsaturated compounds usually has high specificity, highly selective reduction processes are hardly realized by heterogeneous industrial catalysts, which is critical for the green production of many fine chems. Here, we report an unexpected discovery of a biomimetic behavior of dicyandiamide (DICY)-modified Pt nanocatalysts for the green hydrogenation of a wide range of nitroaroms. We demonstrate that the surface modification by DICY not only prevents the direct contact of nitroarom. reactants with Pt surface but also induces an effective non-contact hydrogenation mechanism mediated by protons and electrons. In such a process, the DICY layer serves as a “semi-permeable membrane” to allow the permeation of H₂ mols. for being activated into electrons and protons at the Pt-DICY interface. With the generation of separated protons and electrons, the nitro group with strong electrophilic properties can be hydrogenated through the electron transfer followed by the proton transfer, which is facilitated by the hydrogen bonding network formed by protonated DICY. The unique mechanism makes it highly directional toward the hydrogenation of nitro groups without side reactions. Owing to its capability to largely eliminate the waste generation, the developed Pt-DICY catalysts have been successfully applied for the green industrial production of many important aniline intermediates.

626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Computed Properties of 626-01-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. Safety of 3-Iodoaniline.

Zhu, Changlei;Nurko, Max;Day, Cynthia S.;Lukesh, John C. III research published 《 Arylselenyl Radical-Mediated Cyclization of N-(2-Alkynyl)anilines: Access to 3-Selenylquinolines》, the research content is summarized as follows. An efficient and novel approach to accessing 3-selenylquinolines I [R¹ = H, 6-I, 8-Me, etc.; R² = n-Bu, Ph, 3-thienyl, etc.; R³ = Ph, 2-MeC₆H₄, 3-thienyl, etc.] from diaryl diselenides and acyclic, selenium-free substrates was described. Preliminary mechanistic studies indicated that the combination of CuCl₂ and air afforded an appropriate environment for producing arylselenyl radicals that initiated the cascade cyclization of N-(2-alkynyl)anilines, forming key Se-C and C-C bonds in a single step. Using this chem., a wide variety of 3-selenylquinolines were produced in moderate to excellent yield under mild conditions, highlighting the versatility and usefulness of this new method.

626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Safety of 3-Iodoaniline

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Recommanded Product: 3-Iodoaniline.

Yasui, Kosuke;Kamitani, Miharu;Fujimoto, Hayato;Tobisu, Mamoru research published 《 N-Heterocyclic Carbene-Catalyzed Truce-Smiles Rearrangement of N-Arylacrylamides via the Cleavage of Unactivated C(aryl)-N Bonds》, the research content is summarized as follows. N-heterocyclic carbene (NHC)-catalyzed Truce-Smiles rearrangement of aniline derivatives was reported, in which an unactivated C(aryl)-N bond was cleaved, leading to the formation of a new C(aryl)-C bond. The key to the success of this reaction was the utilization of a highly nucleophilic NHC, which enabled the formation of a highly nucleophilic ylide intermediate that was generated from an α,β-unsaturated amide.

Recommanded Product: 3-Iodoaniline, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Electric Literature of 626-01-7.

Zeng, Linwei;Li, Jiaming;Cui, Sunliang research published 《 Rhodium-Catalyzed Atroposelective Click Cycloaddition of Azides and Alkynes》, the research content is summarized as follows. Herein, a rhodium-catalyzed enantioselective click cycloaddition of azides R¹N₃ (R¹ = benzyl, 2-naphthyl, pyridin-3-yl, etc.) and alkynes R³CCR² (R² = Ph, 2-naphthyl, cyclopropyl, etc.; R³ = 2-hydroxynaphthalen-1-yl, 6-bromo-2-hydroxynaphthalen-1-yl, 6-hydroxyquinolin-5-yl, etc.) for rapid and modular access to atropisomeric triazoles I in excellent yields and enantioselectivities was reported. The process is mild, efficient and scalable, and features broad substrate scope.

626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Electric Literature of 626-01-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Application In Synthesis of 626-01-7.

Zhai, Shuyang;Hu, Wei;Wang, Weibo;Chai, Li;An, Qian;Li, Chunya;Liu, Zhihong research published 《 Tracking autophagy process with a through bond energy transfer-based ratiometric two-photon viscosity probe》, the research content is summarized as follows. Autophagy is a self-degradation process in cells, which is of vital significance to the health and operation of organisms. Due to the increase of lysosomal viscosity during autophagy, viscosity probes that specifically accumulate in lysosome are powerful tools for monitoring autophagy and investigating related diseases. However, there is still a lack of viscosity-sensitive ratiometric autophagy probes, which restricts the tracking of autophagy with high accuracy in complex physiol. environment. Herein, a viscosity-responsive, lysosome targeted two-photon fluorescent probe Lyso-Vis was designed based on through bond energy transfer (TBET) mechanism. The TBET-based probe achieved the separation of two emission baselines, which greatly improved the resolution and reliability of sensing and imaging. Under 810 nm two-photon excitation, the emission intensity ratio of the red and green channel increased with a viscosity dependent manner. Lyso-Vis not only for the first time realized ratiometric sensing of lysosomal viscosity during autophagy process, but also visualized the association of autophagy with inflammation and stroke, and it was applied to explore the activation and inhibition of autophagy during stroke in mice.

Application In Synthesis of 626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons-Smith reaction (cyclopropanation using iodomethane), 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction. Formula: C6H6IN.

Zhang, Hongquan;Wen, Chunxi;Li, Bingting;Yan, Xinlin;Xu, Yangrong;Guo, Jialin;Hou, Shi;Chang, Jiajia;Li, Song;Xiao, Junhai research published 《 Phenoxyaromatic Acid Analogues as Novel Radiotherapy Sensitizers: Design, Synthesis and Biological Evaluation》, the research content is summarized as follows. Radiotherapy is a vital approach for brain tumor treatment. The standard treatment for glioblastoma (GB) is maximal surgical resection combined with radiotherapy and chemotherapy. However, the non-sensitivity of tumor cells in the hypoxic area of solid tumors to radiotherapy may cause radioresistance. Therefore, radiotherapy sensitizers that increase the oxygen concentration within the tumor are promising for increasing the effectiveness of radiation. Inspired by Hb allosteric oxygen release regulators, a series of novel phenoxyacetic acid analogs were designed and synthesized. A numerical method was applied to determine the activity and safety of newly synthesized compounds In vitro studies on the evaluation of red blood cells revealed that compounds 19c (ΔP₅₀ = 45.50 mmHg) and 19t (ΔP₅₀ = 44.38 mmHg) improve the oxygen-releasing property effectively compared to pos. control efaproxiral (ΔP₅₀ = 36.40 mmHg). Preliminary safety evaluation revealed that 19c exhibited no cytotoxicity towards HEK293 and U87MG cells, while 19t was cytotoxic toward both cells with no selectivity. An in vivo activity assay confirmed that 19c exhibited a radiosensitization effect on orthotopically transplanted GB in mouse brains. Moreover, a pharmacokinetic study in rats showed that 19c was orally available.

626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.

3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Formula: C6H6IN

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com