Category: 624-73-7

In 2015,Xue, Xiaochao; Li, Wei; Yin, Zhaojun; Meng, Xiangbao; Li, Zhongjun published 《Concise and direct construction of cis-pyrano[4,3-b]pyran-5-one skeleton from glucal derivatives: synthesis of ent-4-deoxy-2,3-di-epi-dinemasone BC》.Tetrahedron Letters published the findings.COA of Formula: C2H4I2 The information in the text is summarized as follows:

(-)-Dinemasones B and C were isolated from a culture of the endophytic fungus Dinemasporium strigosum and had shown attractive antimicrobial activities in vitro. Described herein is the concise synthesis of their analog, ent-4-deoxy-2,3-di-epi-dinemasone BC, from glucal derivatives, including C-glycoside and 3-deoxy-glucal, and the strategies proceeded in 7 steps in 13% overall yield and in 9 steps in 17% overall yield resp. In the part of experimental materials, we found many familiar compounds, such as 1,2-Diiodoethane(cas: 624-73-7COA of Formula: C2H4I2)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.COA of Formula: C2H4I2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Formula: C2H4I2In 2015 ,《1,3,5-[(tBu2MeSi)2Si]3C6H3: isolable Si-centered triradical with a high-spin quartet ground state》 was published in Chemistry Letters. The article was written by Nozawa, Takeshi; Ichinohe, Masaaki; Sekiguchi, Akira. The article contains the following contents:

Reductive deiodination of 1,3,5-tris[2,2-di-tert-butyl-1-(di-tert-butylmethylsilyl)-1-iodo-2-methyldisilanyl]benzene (1) with KC8 results in the formation of isolable Si-centered triradical 1,3,5-[(t-Bu2MeSi)2Si]3C6H3 (2), which was characterized by x-ray crystallog. and ESR (EPR) spectroscopy. The quartet ground state for triradical 2 was established using EPR spectroscopy by Curie plots (5-60 K) for the characteristic Δm = 2 and Δm = 3 transitions. The experimental process involved the reaction of 1,2-Diiodoethane(cas: 624-73-7Formula: C2H4I2)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Formula: C2H4I2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Dalton Transactions included an article by Kikukawa, Yuji; Kitajima, Hiromasa; Hayashi, Yoshihito. Application of 624-73-7. The article was titled 《Evaluation of the chemo- and shape-selective association of a bowl-type dodecavanadate cage with an electron-rich group》. The information in the text is summarized as follows:

The host-guest interaction between a half spherical-type dodecavanadate (V12) and a neutral mol. guest was evaluated by monitoring the flip of a VO5 unit caused by the presence or absence of a guest in the cavity of V12. In N,N-dimethylformamide (DMF), V12 adopted the guest-free form (V12-free). By the addition of several guest mols., such as acetonitrile, nitromethane, and dichloromethane, the structural conversion to the guest-inserted form (V12(guest)) was observed with the affinity constants of 137 ± 10 M-1, 0.14 ± 0.1 M-1, and 0.15 ± 0.1 M-1, resp. In the case of 1,2-dichloroethane, 1,2-dibromoethane, and 1,2-diiodoethane, the constants were 35 ± 5 M-1, 114 ± 5 M-1, and 2.1 ± 0.5 M-1, resp., suggesting that the bromo group is the best fit to the cavity of the bowl. A cyclic carbonate, 5- and 6-membered lactones, cyclobutanone, and hexanal were inserted into the V12 host, while a non-cyclic carbonate, non-cyclic and 7-membered cyclic ester, a ketone with a 5-membered ring, and benzaldehyde showed no effect on the guest insertion. The V12 host preferred to hold a guest with an electron-rich group, and the bowl-type structure showed the unique shape-selective interaction with the guest. The results came from multiple reactions, including the reaction of 1,2-Diiodoethane(cas: 624-73-7Application of 624-73-7)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Application of 624-73-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2016,Sembera, Filip; Plutnar, Jan; Higelin, Alexander; Janousek, Zbynek; Cisarova, Ivana; Michl, Josef published 《Metal Complexes with Very Large Dipole Moments: the Anionic Carborane Nitriles 12-NC-CB11X11- (X = H, F, CH3) as Ligands on Pt(II) and Pd(II)》.Inorganic Chemistry published the findings.SDS of cas: 624-73-7 The information in the text is summarized as follows:

The anionic nitriles 1-R-12-NC-CB11H10- (R = H, CH3, I, COOH), 12-NC-1-H-CB11Me10-, and 12-NC-1-H-CB11F10- were prepared, and three of them were examined for complex formation with (Et3P)2Pt(II) and (Et3P)2Pd(II). Several stable internally charge-compensated zwitterionic complexes were obtained and characterized. RI-BP86/SV(P) calculations suggest that their dipole moments exceed 20 D. An attempt to measure the dipole moments in solution failed due to insufficient solubility in solvents of low polarity.1,2-Diiodoethane(cas: 624-73-7SDS of cas: 624-73-7) was used in this study.

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Oceanic alkyl iodides are believed to be the principal source of atmospheric iodine.SDS of cas: 624-73-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2015,Zirakzadeh, Afrooz; Herlein, Alexander; Gross, Manuela A.; Mereiter, Kurt; Wang, Yaping; Weissensteiner, Walter published 《Halide-Mediated Ortho-Deprotonation Reactions Applied to the Synthesis of 1,2- and 1,3-Disubstituted Ferrocene Derivatives》.Organometallics published the findings.Name: 1,2-Diiodoethane The information in the text is summarized as follows:

The ortho-deprotonation of halide-substituted ferrocenes by treatment with lithium tetramethylpiperidide (LiTMP) has been investigated. Iodo-, bromo-, and chloro-substituted ferrocenes were easily deprotonated adjacent to the halide substituents. The synthetic applicability of this reaction was, however, limited by the fact that, depending on the temperature and the degree of halide substitution, scrambling of both iodo and bromo substituents at the ferrocene core took place. Iodoferrocenes could not be transformed selectively into ortho-substituted iodoferrocenes since, in the presence of LiTMP, the iodo substituents scrambled efficiently even at -78°, and this process had occurred before electrophiles had been added. Bromoferrocene and certain monobromo-substituted derivatives, however, could be efficiently ortho-deprotonated at low temperature and reacted with a number of electrophiles to afford 1,2- and 1,2,3-substituted ferrocene derivatives For example, 2-bromo-1-iodoferrocene was synthesized by ortho-deprotonation of bromoferrocene and reaction with the electrophiles diiodoethane and diiodotetrafluoroethane, resp. In this and related cases the iodide scrambling process and further product deprotonation due to the excess LiTMP could be suppressed efficiently by running the reaction at low temperature and in inverse mode. In contrast to the low-temperature process, at room temperature bromo substituents in bromoferrocenes scrambled in the presence of LiTMP. Chloro- and 1,2-dichloroferrocene could be ortho-deprotonated selectively, but in neither case was scrambling of a chloro substituent observed As a further application of this ortho-deprotonation reaction, a route for the synthesis of 1,3-disubstituted ferrocenes was developed. 1,3-Diiodoferrocene was accessible from bromoferrocene in four steps. On a multigram scale an overall yield of 41% was achieved. 1,3-Diiodoferrocene was further transformed into sym. 1,3-disubstituted ferrocenes (1,3-R2Fc; R = CHO, COOEt, CN, CH:CH2).1,2-Diiodoethane(cas: 624-73-7Name: 1,2-Diiodoethane) was used in this study.

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Name: 1,2-Diiodoethane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Wong, Alice R.; Fastuca, Nicholas J.; Mak, Victor W.; Kerkovius, Jeffrey K.; Stevenson, Susan M.; Reisman, Sarah E. published their research in ACS Central Science in 2021. The article was titled 《Total Syntheses of the C19 Diterpenoid Alkaloids (-)-Talatisamine, (-)-Liljestrandisine, and (-)-Liljestrandinine by a Fragment Coupling Approach》.SDS of cas: 624-73-7 The article contains the following contents:

The C19 diterpenoid alkaloids (C19 DTAs) are a large family of natural products, many of which modulate the activity of ion channels in vivo and are therefore of interest for the study of neurol. and cardiovascular diseases. The complex architectures of these mols. continue to challenge the state-of-the-art in chem. synthesis, particularly with respect to efficient assembly of their polcyclic ring systems. Here, the authors report the total syntheses of (-)-talatisamine (I), (-)-liljestrandisine (II), and (-)-liljestrandinine (III), three aconitine-type C19 DTAs, using a fragment coupling strategy. Key to this approach is a 1,2-addition/semipinacol rearrangement sequence which efficiently joins two complex fragments and sets an all-carbon quaternary center. In the part of experimental materials, we found many familiar compounds, such as 1,2-Diiodoethane(cas: 624-73-7SDS of cas: 624-73-7)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.SDS of cas: 624-73-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Recommanded Product: 1,2-DiiodoethaneIn 2016 ,《A fast controlled synthesis of poly(p-phenyleneethynylene)s under transition-metal-free conditions》 appeared in Polymer Chemistry. The author of the article were Motoshige, Asahi; Kakinuma, Junko; Iyoda, Tomokazu; Sanji, Takanobu. The article conveys some information:

A transition-metal-free polymerization of an AB-type monomer for the synthesis of well-defined poly(p-phenyleneethynylene)s is described. The polymerization of 1-pentafluorophenylethynyl-4-[(trimethylsilyl)ethynyl]benzene with a catalytic amount of tetrabutylammonium fluoride or potassium t-butoxide in the presence of cryptand[2.2.2] affords polymers within a few minutes. When monitoring the polymerization, the mol. weight as a function of monomer conversion shows a linear relationship, where the polydispersity indexes are around 1.6. The polymerization proceeds predominantly via intramol. fluoride anion transfer to the polymer end. End capping of the active polymerization end is also demonstrated. The results came from multiple reactions, including the reaction of 1,2-Diiodoethane(cas: 624-73-7Recommanded Product: 1,2-Diiodoethane)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Recommanded Product: 1,2-Diiodoethane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2016,Broman, Soeren Lindbaek; Andersen, Cecilie Lindholm; Jevric, Martyn; Tortzen, Christian Gregers; Hammerich, Ole; Nielsen, Mogens Broendsted published 《Metal cation binding to acetylenic tetrathiafulvalene-pyridine conjugates: affinity tuned by preorganization and cavity size》.Tetrahedron published the findings.Electric Literature of C2H4I2 The information in the text is summarized as follows:

A series of three structurally related mono-, bidentate and macrocyclic TTF-pyridine hosts were prepared and titrated with several metal cations including Ag+ and Pb2+ and studied using NMR- and UV-vis spectroscopy and cyclic voltammetry. For Ag+, we found an eightfold increase in binding affinity between the bidentate and macrocyclic host and conversely, for Pb2+, a 100-fold drop. D. functional theory (DFT) calculations support the increased binding affinity for Ag+ is due to an N···N distance for the uncomplexed macrocycle very much suited for binding of Ag+ but being too small for Pb2+. The bidentate host, on the other hand, is of a suitable size for Pb2+.1,2-Diiodoethane(cas: 624-73-7Electric Literature of C2H4I2) was used in this study.

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Electric Literature of C2H4I2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2018,Pick, Fraser S.; Leznoff, Daniel B.; Fryzuk, Michael D. published 《Redox behaviour of ([fc(NPiPr2)2]Fe)2, formation of an iron-iron bond and cleavage of azobenzene》.Dalton Transactions published the findings.Recommanded Product: 1,2-Diiodoethane The information in the text is summarized as follows:

The redox behavior of the dimeric tetrairon complex, ([fc(NPiPr2)2]Fe)2 (where fc(NPiPr2)2 = 1,1′-(C5H4NPiPr2)2Fe) has been investigated. Upon reduction with KC8 an Fe-Fe bond is formed with the complex maintaining a high spin configuration and having the formula [K(THF)6]([fc(NPiPr2)2]Fe)2. In contrast, oxidation of the complex is ligand based; for example, addition of the 1,2-diiodoethane (I2 equivalent) results in the formation of the monomeric iron(II) diiodide [fc(NiPr2I)2]FeI2 wherein the phosphine is oxidized. The dimeric tetrairon complex reacts photolytically with azobenzene, cleaving the N:N double bond and forming the new monomeric bis(phosphoramidate) iron complex. [fc(NP(NPh)iPr2)2]Fe. Characterization of these paramagnetic complexes was accomplished by magnetic susceptibility studies and x-ray analyses. The experimental part of the paper was very detailed, including the reaction process of 1,2-Diiodoethane(cas: 624-73-7Recommanded Product: 1,2-Diiodoethane)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the Simmons–Smith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Recommanded Product: 1,2-Diiodoethane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Quality Control of 1,2-DiiodoethaneIn 2022 ,《Structural Reconstruction in Lead-Free Two-Dimensional Tin Iodide Perovskites Leading to High Quantum Yield Emission》 appeared in ACS Energy Letters. The author of the article were Ghimire, Sushant; Oldenburg, Kevin; Bartling, Stephan; Lesyuk, Rostyslav; Klinke, Christian. The article conveys some information:

The authors report a structural reconstruction-induced high photoluminescence quantum yield of 25% in colloidal 2-dimensional Sn iodide nanosheets that are synthesized by a hot-injection method. The as-synthesized red-colored nanosheets of octylammonium Sn iodide perovskites at room temperature transform to white hexagonal nanosheets upon washing or exposure to light. This structural change increases the bandgap from 2.0 to 3.0 eV, inducing a large Stokes shift and a broadband emission. Further, a long photoluminescence lifetime of ∼1 μs is measured for the nanosheets. Such long-lived broad and intense photoluminescence with a large Stokes shift is anticipated to originate from Sn iodide clusters that are formed during the structural reconstruction. The stereoactive 5s2 lone pair of Sn(II) ions perturbs the excited state geometry of the white hexagonal nanosheets and facilitates the formation of self-trapped excitons. Such broadband and intensely emitting metal halide nanosheets are promising for white light-emitting diodes. The experimental part of the paper was very detailed, including the reaction process of 1,2-Diiodoethane(cas: 624-73-7Quality Control of 1,2-Diiodoethane)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Quality Control of 1,2-Diiodoethane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com