Category: 591-18-4

In 2019,Polymer included an article by Zeng, Wang; Zhang, Yue; Zhao, Xuebo; Qin, Minglin; Li, Xianying; Jin, Wusong; Zhang, Dengqing. SDS of cas: 591-18-4. The article was titled 《One-pot synthesis of conjugated microporous polymers based on extended molecular graphenes for hydrogen storage》. The information in the text is summarized as follows:

Incorporation of highly extended π-conjugated mols. into conjugated microporous polymers (CMPs) is one of the important aspects in material science. Herein we synthesize conjugated microporous polymers (CMP-Gs) with covalently linked mol. graphenes by an efficient tandem oxidative reaction in one-pot, which comprising Scholl-type cyclodehydrogenation and oxidative polymerization Oxidation of m- or p-thienyl decorated hexaphenylbenzene derivatives with excess of FeCl3 allowing in situ generation of size-controlled graphitic segments form CMP-G1 and CMP-G2 in high yields, resp. CMP-Gs possess large surface areas and micropore size from 0.5 to 1.5 nm. Gravimetric hydrogen adsorption isotherms show that the adsorption capacity for hydrogen is up to 2.69 wt% for CMP-G1 and 2.14 wt% for CMP-G2 at 20 bar and 77 K, resp. The experimental process involved the reaction of 1-Bromo-3-iodobenzene(cas: 591-18-4SDS of cas: 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.SDS of cas: 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Synlett included an article by Wu, Xiang-mei; Yan, Guo-bing. Related Products of 591-18-4. The article was titled 《Copper-Catalyzed Synthesis of S-Aryl Dithiocarbamates from Tetraalkylthiuram Disulfides and Aryl Iodides in Water》. The information in the text is summarized as follows:

An efficient approach for the copper-catalyzed synthesis of aryl dithiocarbamates R1SC(S)N(R2)2 (R1 = 2-BrC6H4, 1,3,5-(Me)3C6H2, thiophen-2-yl, etc.; R2 = Me, Et) from aryl iodides R1I and tetraalkylthiuram disulfides N((R2)2)C(S)SSC(S)N((R2)2) in water is described. Without addnl. ligand and organic solvent, the coupling reaction could provide a series of S-aryl dithiocarbamates in moderate to good yields. In the experimental materials used by the author, we found 1-Bromo-3-iodobenzene(cas: 591-18-4Related Products of 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Related Products of 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Gold(I)-catalyzed domino reaction for furopyrans synthesis》 was written by Ruch, Marie; Brach, Nicolas; Galea, Romeric; Wagner, Patrick; Blond, Gaelle. Recommanded Product: 1-Bromo-3-iodobenzene And the article was included in Molecules in 2020. The article conveys some information:

Herein an efficient synthesis of furopyran derivatives through a gold(I)-catalyzed domino reaction were reported. The cascade reaction started with two regioselective cyclizations, a 5-endo-dig and a 8-endo-dig, followed with a Grob-type ragmentation and a hetero Diels-Alder. The obtained furopyran derivatives contain fused and spiro-heterocycles. During this one-pot process, four bonds and four controlled stereogenic centers including a quaternary center were formed.1-Bromo-3-iodobenzene(cas: 591-18-4Recommanded Product: 1-Bromo-3-iodobenzene) was used in this study.

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Recommanded Product: 1-Bromo-3-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2022,Adachi, Yohei; Kondo, Keisuke; Yin, Xiaodong; Jakle, Frieder; Ohshita, Joji published an article in Polymer. The title of the article was 《m-Phenylene linked macrocycle composed of electron-rich dithienogermole and electron-deficient tricoordinate boron units》.Electric Literature of C6H4BrI The author mentioned the following in the article:

Incorporation of non-conventional elements into π-conjugated systems is a powerful tool to control the electronic structures. In this work, electron-deficient tricoordinate boron units were combined with electron-rich dithienogermole units to provide an element-hybrid conjugated macrocycle with m-phenylene linkers. In contrast to the absorption spectra which were unaffected by solvent polarity, the element-hybrid macrocycle exhibited clear solvatochromism in the fluorescence spectra originating from the charge transfer (CT) transition between the dithienogermole and tricoordinate boron units. The addition of fluoride to the solution of the macrocycle resulted in the stoichiometric formation of tetracoordinate borate species. Interestingly, the fluorescence was intensified by the addition of fluoride, and the mechanism was confirmed by fluorescence spectroscopy and TD-DFT calculations In addition to this study using 1-Bromo-3-iodobenzene, there are many other studies that have used 1-Bromo-3-iodobenzene(cas: 591-18-4Electric Literature of C6H4BrI) was used in this study.

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Electric Literature of C6H4BrI

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The author of 《One-Pot Synthesis of Spiro-2H-pyrroles from N-Propargylic β-Enaminones》 were Karadeniz, Eda; Zora, Metin. And the article was published in Synlett in 2019. Computed Properties of C6H4BrI The author mentioned the following in the article:

A simple and general one-pot method for the synthesis of spiro-2H-pyrroles has been developed. Initially, cyclohexane-embedded β-enaminones with internal alkyne functionality were synthesized by conjugate addition of 1-ethynylcyclohexylamine to α,β-alkynic ketones, followed by palladium-catalyzed coupling of the resulting N-propargylic β-enaminones with aryl iodides. When subjected to basic conditions, the cyclohexane-embedded β-enaminones with internal alkyne functionality underwent tandem nucleophilic cyclization and benzylic C-H oxidation to furnish 3,4-diaryloyl-1-azaspiro[4.5]deca-1,3-diene derivatives I (R1 = Ph; R2 = Ph, 4-ClC6H4; R3 = Ph, 4-MeC6H4, 4-FC6H4, 3-BrC6H4, 4-O2NC6H4) in good yields. In the part of experimental materials, we found many familiar compounds, such as 1-Bromo-3-iodobenzene(cas: 591-18-4Computed Properties of C6H4BrI)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Computed Properties of C6H4BrI

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,ChemistrySelect included an article by Liu, Na; Tian, An-Qi; Ren, Zhi-Lin; Wang, Long. Related Products of 591-18-4. The article was titled 《Efficient Synthesis of Sulfonyl Diphenylsulfides Catalyzed via Cu-MOF of PCN-6’》. The information in the text is summarized as follows:

A metal organic framework of PCN-6′ was used, prepared from copper compound and triazine-2,4,6-triyl-benzoate (H3TATB) ligand, to catalyze the tandem reaction of disulfide with aryl iodide and sulfonyl chloride to synthesize of sulfonyl diphenylsulfides. A series of sulfonyl diphenylsulfide derivatives were synthesized with medium or high yields. The results came from multiple reactions, including the reaction of 1-Bromo-3-iodobenzene(cas: 591-18-4Related Products of 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Related Products of 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Yang, Ke; Li, Zhi; Liu, Chong; Li, Yunjian; Hu, Qingyue; Elsaid, Mazen; Li, Bijin; Das, Jayabrata; Dang, Yanfeng; Maiti, Debabrata; Ge, Haibo published an article in 2022. The article was titled 《Ligand-promoted palladium-catalyzed β-methylene C-H arylation of primary aldehydes》, and you may find the article in Chemical Science.Product Details of 591-18-4 The information in the text is summarized as follows:

The development of a direct Pd-catalyzed methylene β-C-H arylation of linear unmasked aldehydes were synthesized using 3-amino-3-methylbutanoic acid as a TDG (Transient Directing Group) and 2-pyridone as an external ligand. D. functional theory calculations provided insights into the reaction mechanism and shed light on the roles of the external and transient directing ligands in the catalytic transformation. In the experimental materials used by the author, we found 1-Bromo-3-iodobenzene(cas: 591-18-4Product Details of 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Product Details of 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2022,Zhang, Xu; Fang, Wan-Yin; Qin, Hua-Li published an article in Organic Letters. The title of the article was 《Regio- and Stereoselective Installation of Bromide onto Vinyl Sulfonyl Fluorides: Construction of a Class of Versatile Sulfur Fluoride Exchange Hubs》.Related Products of 591-18-4 The author mentioned the following in the article:

A convenient protocol for the exclusively regio- and stereoselective installation of a bromine atom on the 2-arylvinylsulfonyl fluorides using lithium bromide (LiBr) as the bromine source was described, providing (Z)-1-bromo-2-arylethene-1-sulfonyl fluorides (Z-BASF) with versatile reactive handles (bromide, vinyl, and sulfonyl fluoride) in ≤88% yield. Meanwhile, Z-BASF mols. displayed various reactivities in a series of chem. transformations. The results came from multiple reactions, including the reaction of 1-Bromo-3-iodobenzene(cas: 591-18-4Related Products of 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Related Products of 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Organic Letters included an article by Gou, Bo-Bo; Liu, Hang-Fan; Chen, Jie; Zhou, Ling. Recommanded Product: 1-Bromo-3-iodobenzene. The article was titled 《Palladium-Catalyzed Site-Selective C(sp3)-H Arylation of Phenylacetaldehydes》. The information in the text is summarized as follows:

A Pd-catalyzed selective C-H arylation reaction of phenylacetaldehydes using L-valine as the transient directing group, is described.. This process showed a broad substrate scope and excellent selectivity in which a ligand-controlled functionalization of the unactivated β-C(sp3)-H bond. In addition, enantioselective arylation of phenylacetaldehydes was preliminarily explored by utilizing a bulky chiral transient directing group. In the part of experimental materials, we found many familiar compounds, such as 1-Bromo-3-iodobenzene(cas: 591-18-4Recommanded Product: 1-Bromo-3-iodobenzene)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Recommanded Product: 1-Bromo-3-iodobenzene Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Miao, Xinrui; Cai, Zhengkai; Li, Jinxing; Liu, Liqian; Wu, Juntian; Li, Bang; Ying, Lei; Silly, Fabien; Deng, Wenli; Cao, Yong published their research in ChemPhotoChem in 2021. The article was titled 《Elucidating Halogen-Assisted Self-Assembly Enhanced Mechanochromic Aggregation-Induced Emission》.HPLC of Formula: 591-18-4 The article contains the following contents:

We present a successful strategy to obtain a self-assembled material stabilized by halogen bonding with enhanced mechanochromic aggregation-induced emission (AIE). The meta-bromophenyl-substituted tetraphenylethene fluorophore (m-BrTBE) exhibits an emission which is more red-shifted compared to the phenyl-ring-substituted tetraphenylethene fluorophore (TBE) in film. Remarkably, m-BrTBE mols. self-assemble into uniform ball-like aggregates with high photoluminescence quantum yield up to 85.3%, which indicates that the mol. conformation and intermol. interactions are different from those in the crystalline state. Based on single-crystal anal., scanning tunneling microscopic observations, and theor. calculations, the unusual self-assembly enhanced AIE behavior is attributed to the important effect of meta-bromide substituents which not only form intermol. Br···π halogen bonding and H···Br hydrogen bonding interactions to block nonradiative relaxation pathways effectively but also promote radiative processes. After reading the article, we found that the author used 1-Bromo-3-iodobenzene(cas: 591-18-4HPLC of Formula: 591-18-4)

1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.HPLC of Formula: 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com