Category: 589-87-7

The author of 《Teaching an Old Poly(arylene ether) New Tricks: Efficient Blue Thermally Activated Delayed Fluorescence》 were Liu, Xinrui; Rao, Jiancheng; Li, Xuefei; Wang, Shumeng; Ding, Junqiao; Wang, Lixiang. And the article was published in iScience in 2019. Category: iodides-buliding-blocks The author mentioned the following in the article:

Polymer light-emitting diodes are attractive for optoelectronic applications owing to their brightness and ease of processing. However, often metals have to be inserted to increase the luminescence efficiency, and producing blue emitters is a challenge. Here we present a strategy to make blue thermally activated delayed fluorescence (TADF) polymers by directly embedding a small mol. blue TADF emitter into a poly(aryl ether) (PAE) backbone. Thanks to the oxygen-induced negligible electronic communication between neighboring TADF fragments, its corresponding blue delayed fluorescence can be inherited by the developed polymers. These polymers are free from metal catalyst contamination and show improved thermal stability. Through device optimization, a current efficiency of 29.7 cd/A (21.2 lm/W, 13.2%) is realized together with Commission Internationale de L′Eclairage coordinates of (0.18, 0.32). The value is competitive with blue phosphorescent polymers, highlighting the importance of the PAE backbone in achieving high-performance blue delayed fluorescence at a macromol. level. The experimental process involved the reaction of 1-Bromo-4-iodobenzene(cas: 589-87-7Category: iodides-buliding-blocks)

1-Bromo-4-iodobenzene(cas: 589-87-7) is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone..Category: iodides-buliding-blocks It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Reference of 1-Bromo-4-iodobenzeneIn 2021 ,《Visible-light-driven radical 1,3-addition of selenosulfonates to vinyldiazo compounds》 was published in Green Chemistry. The article was written by Li, Weiyu; Zhou, Lei. The article contains the following contents:

Herein, the authors report a visible light-driven radical 1,3-selenosulfonylation of vinyldiazo compounds with selenosulfonates, providing various γ-seleno allylic sulfones in good yields. This photochem. reaction was carried out at room temperature in an open flask using Et acetate as the solvent without any photocatalysts or additives. The control experiments corroborated that the 1,3-addition proceeded via a radical-chain propagation process. The synthetic applications of the resulting products were demonstrated by deselenization, reduction, bromination and allylation. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-iodobenzene(cas: 589-87-7Reference of 1-Bromo-4-iodobenzene)

1-Bromo-4-iodobenzene(cas: 589-87-7) is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone..Reference of 1-Bromo-4-iodobenzene It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Synthesis included an article by Sarie, Jerome C.; Neufeld, Jessica; Daniliuc, Constantin G.; Gilmour, Ryan. Safety of 1-Bromo-4-iodobenzene. The article was titled 《Willgerodt-Type Dichloro(aryl)-λ3-Iodanes: A Structural Study》. The information in the text is summarized as follows:

Crystallog. structural anal. of four electronically diverse Willgerodt-type reagents is disclosed together with a solution-phase NMR anal. These data reveal a plethora of intermol. non-covalent interactions and confirm the expected T-shape geometry of the reagents. In all cases the I-Cl bonds are orthogonal to the plane of the aryl ring. This study provides important structural insights into this venerable class of dichlorination reagent and has implications for crystal engineering. After reading the article, we found that the author used 1-Bromo-4-iodobenzene(cas: 589-87-7Safety of 1-Bromo-4-iodobenzene)

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesSafety of 1-Bromo-4-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《STM apparent height measurements of molecular wires with different physical length attached on 2-D phase separated templates for evaluation of single molecular conductance》 was written by Iizuka, Tomoya; Shimizu, Daiki; Matsuda, Kenji. Recommanded Product: 1-Bromo-4-iodobenzene And the article was included in RSC Advances in 2020. The article conveys some information:

Single mol. conductance of mol. wires is effectively evaluated by the combination of STM apparent height measurement and a 2-D phase separation technique. Previously the method was only applied to a set of mol. wires with the same phys. length, but herein we applied the method to thienylene-based and phenylene-based mol. wires with different phys. lengths. By considering the difference in phys. mol. height including thermal contribution of conformational isomers, the conductance ratio was determined to be 1.3 ± 0.7, which is in agreement with the reported value determined by a break-junction method. The experimental process involved the reaction of 1-Bromo-4-iodobenzene(cas: 589-87-7Recommanded Product: 1-Bromo-4-iodobenzene)

1-Bromo-4-iodobenzene(cas: 589-87-7) is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone..Recommanded Product: 1-Bromo-4-iodobenzene It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Tetrahedron Letters included an article by Fu, Fang; Gurung, Laxman; Czaun, Miklos; Mathew, Thomas; Prakash, G. K. Surya. Synthetic Route of C6H4BrI. The article was titled 《ipso-Bromination/iodination of arylboronic acids: Poly(4-vinylpyridine)-Br2/I2 complexes as safe and efficient reagents》. The information in the text is summarized as follows:

Poly(4-vinyl pyridine) supported bromine/iodine complexes were prepared and probed for ipso-bromination/iodination of arylboronic acids ArB(OH)2 (Ar = 4-methylphenyl, 3-nitrophenyl, naphthalen-2-yl, etc.). These solid complexes with catalytic amount of additive are found to be safe and efficient reagent system for the ipso-bromination/iodination. The reaction occurs under mild conditions and tolerates various functional groups resulting in products ArX (X = Br, I) with high selectivity and yields. The results came from multiple reactions, including the reaction of 1-Bromo-4-iodobenzene(cas: 589-87-7Synthetic Route of C6H4BrI)

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesSynthetic Route of C6H4BrI

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

An, Guoqiang; Wang, Limin; Han, Jianwei published their research in Organic Letters in 2021. The article was titled 《Palladium Catalyzed Regioselective Cyclization of Arylcarboxylic Acids via Radical Intermediates with Diaryliodonium Salts》.HPLC of Formula: 589-87-7 The article contains the following contents:

Palladium-catalyzed C2-arylation/intramol. acylation with arylcarboxylic acids was developed by using diaryliodonium salts. The protocol has the advantage of good step-economy by two chem. bonds formation in one pot. The experimental process involved the reaction of 1-Bromo-4-iodobenzene(cas: 589-87-7HPLC of Formula: 589-87-7)

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesHPLC of Formula: 589-87-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The author of 《Accelerating Effect of DMAP on CuI Catalyzed Buchwald-Hartwig C-N Coupling: Mechanistic Insight to the Reaction Pathway》 were Roy, Subhasish; Dutta, Mintu Maan; Sarma, Manas Jyoti; Phukan, Prodeep. And the article was published in ChemistrySelect in 2019. Quality Control of 1-Bromo-4-iodobenzene The author mentioned the following in the article:

An efficient methodol. was developed for C-N cross-coupling reaction between aryl halides and amines using a catalytic system comprised of CuI and N,N-dimethylaminopyridine (DMAP). Coupling reactions were carried out in DMSO at 120°C in the presence of 5 mol% CuI, 20 mol% DMAP and 2.5 equiv of KOH. Addition of DMAP was found to be beneficial in significantly accelerating the reaction rate. Both aryl iodides and aryl bromides were successfully coupled with different primary and secondary amines to furnish the desired cross-coupling product in high yield. A copper complex [Cu(DMAP)4I]I, made by combining CuI and DMAP, was found to produce superior results for the Buchwlad-Hartwig cross-coupling reaction. The use of 2 mol% of the copper complex was sufficient to produce high yields of product. In the part of experimental materials, we found many familiar compounds, such as 1-Bromo-4-iodobenzene(cas: 589-87-7Quality Control of 1-Bromo-4-iodobenzene)

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesQuality Control of 1-Bromo-4-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Electrochemical intramolecular C-H/N-H functionalization for the synthesis of isoxazolidine-fused isoquinolin-1(2H)-ones》 was written by Zhang, Lin-Bao; Geng, Rui-Sen; Wang, Zi-Chen; Ren, Guang-Yi; Wen, Li-Rong; Li, Ming. SDS of cas: 589-87-7 And the article was included in Green Chemistry in 2020. The article conveys some information:

A general and practical protocol for the construction of isoxazolidine-fused isoquinolin-1(2H)-ones I (R = H, Me; R1 = H, Cl, F, SMe, etc.; R2 = H, Me, OMe; R3 = H, F, Cl, Br, Me; R4 = C6H5, 4-FC6H4, CCC6H5, etc.; R1R2 = -OCH2O-; R2R3 = CH=CHCH=CH; n = 1, 2) has been described by electrochem.-oxidation-induced intramol. annulation via amidyl radicals. In an undivided cell, isoquinolinones I could be easily generated from various available amides R5CONHO(CH2)nCCR4 (R5 = 4-Cl, 2H-1,3-benzodioxol-5-yl, naphthalen-1-yl, etc.) bearing CONHOR groups under metal-free, additive-free and external oxidant-free conditions. Moreover, this transformation proceeded smoothly by using cheap 95% ethanol as the green solvent and could be extended to the gram scale.1-Bromo-4-iodobenzene(cas: 589-87-7SDS of cas: 589-87-7) was used in this study.

1-Bromo-4-iodobenzene(cas: 589-87-7) is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone..SDS of cas: 589-87-7 It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Ye, Shaofeng; Guo, Runda; Wang, Yaxiong; Duan, Yalei; Wang, Lei published their research in Dyes and Pigments in 2021. The article was titled 《Exploiting novel electron-deficient moiety 2,5-diazarcarbazole to functionally construct DPA-containing electron transporting materials for highly efficient sky-blue fluorescent OLEDs》.Related Products of 589-87-7 The article contains the following contents:

A span-new electron-deficient moiety 2,5-diazarcarbazole (25NCz) with high T1 = 2.77 eV was firstly designed and synthesized, which had enormous potential to construct organic electronic materials in photoelec. field. Herein, 25NCz as large rigid-type periphery functionalized group, was introduced to develop novel electron transporting materials (ETMs) by grafting large rigid-type π-conjugated core anthracene. Two novel ETMs p-S25NCzDPA and p-D25NCzDPA were designed and developed. Due to the dual characteristics of rigidity and electron-accepting of the 25NCz, as expected, these two ETMs possessed good thermal stability and high electron mobility. When triplet-triplet fusion (TTF) sky-blue fluorescent OLEDs based on these two novel ETMs were manufactured, they exhibited superior performances. In particular, the maximum external quantum efficiency (EQE) reached 7.45% and the EQE kept 7.45% at the luminance of 50,000 cd m-2 for p-S25NCzDPA based device. This work rationally demonstrated that the significance of newly developed electron-deficient moiety 25NCz in designing ETMs for high-performance OLEDs. In addition to this study using 1-Bromo-4-iodobenzene, there are many other studies that have used 1-Bromo-4-iodobenzene(cas: 589-87-7Related Products of 589-87-7) was used in this study.

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesRelated Products of 589-87-7

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Green Chemistry included an article by Lang, Xian-Dong; You, Fei; He, Xing; Yu, Yi-Chen; He, Liang-Nian. Quality Control of 1-Bromo-4-iodobenzene. The article was titled 《Rhodium(I)-catalyzed Pauson-Khand-type reaction using formic acid as a CO surrogate: an alternative approach for indirect CO2 utilization》. The information in the text is summarized as follows:

Formic acid was found to be an ideal CO surrogate for the rhodium(I)-catalyzed Pauson-Khand-type (PK-type) reaction of various substituted 1,6-enynes to afford bicyclic cyclopentenones I [R = Ph, 2-MeOC6H4, 4-BrC6H4, etc.] and II [R1 = Ph, 4-FC6H4 2-ClC6H4, etc.] in moderate to good yields. High TON value up to 263 and good results in the gram-scale experiment were also obtained. In addition, heterocyclic mols. of pharmaceutical importance were also furnished via inter- or intra-mol. hetero-PK-type reactions, further broadening the application of current strategy. Formic acid was utilized as a bridging mol. for the conversion of CO2 to CO, since formic acid was manufactured via catalytic hydrogenation of CO2 and released CO in the presence of acetic anhydride readily. Therefore, this methodol. represented a green and indirect approach for chem. valorization of CO2 in the preparation of value-added compounds In addition to this study using 1-Bromo-4-iodobenzene, there are many other studies that have used 1-Bromo-4-iodobenzene(cas: 589-87-7Quality Control of 1-Bromo-4-iodobenzene) was used in this study.

1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesQuality Control of 1-Bromo-4-iodobenzene

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com