Synergistic and Selective Copper/ppm Pd-Catalyzed Suzuki-Miyaura Couplings: In Water, Mild Conditions, with Recycling was written by Handa, Sachin;Smith, Justin D.;Hageman, Matthew S.;Gonzalez, Monica;Lipshutz, Bruce H.. And the article was included in ACS Catalysis in 2016.Category: iodides-buliding-blocks This article mentions the following:
Copper-catalyzed Suzuki-Miyaura couplings can be carried out exclusively on aryl iodides under very mild conditions, which is made possible by synergistic effects due to the presence of ppm levels of palladium as cocatalyst. The coupling requires a hemilabile P(O)-N ligand, together with the benefits of micellar catalysis using water as the recyclable reaction medium. In the experiment, the researchers used many compounds, for example, 2,2-Difluoro-4-iodobenzo[d][1,3]dioxole (cas: 531508-54-0Category: iodides-buliding-blocks).
2,2-Difluoro-4-iodobenzo[d][1,3]dioxole (cas: 531508-54-0) belongs to iodide derivatives. Organoiodine compounds occur widely in organic chemistry, but are relatively rare in nature. Polyiodoorganic compounds are sometimes employed as X-ray contrast agents, in fluoroscopy, a type of medical imaging. This application exploits the X-ray absorbing ability of the heavy iodine nucleus.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com