516-12-1 Archives - Page 4 of 10 - Iodides-buliding-blocks

Keelawat, Somboon’s team published research in Virchows Archiv in 2019 | CAS: 516-12-1

1-Iodopyrrolidine-2,5-dione(cas: 516-12-1) is used in the preparation of vinyl sulfones from olefins and benzenesulfinic acid. It acts as a source for I+ and involved in Hunsdiecker reactions for the conversion of cinnamic acids, and propiolic acids to the corresponding alfa-halostyrenes and 1-halo-1-alkynes respectively. Reference of 1-Iodopyrrolidine-2,5-dione

In 2019,Virchows Archiv included an article by Keelawat, Somboon; Bychkov, Andrey. Reference of 1-Iodopyrrolidine-2,5-dione. The article was titled 《Compact buds with biphasic differentiation and calcitonin-expressing neuroendocrine cells-previously unrecognized structures of thyroglossal duct unveiled by immunohistochemistry》. The information in the text is summarized as follows:

Immunophenotype of thyroglossal duct (TGD) cysts, including lining epithelium and thyroid remnants, is scarcely addressed in the literature. There is indirect evidence that C cells may be derived from progenitor cells of the midline thyroid primordium. This is supported by the recent concept of the endodermal origin of lateral thyroid anlagen and several case reports. We aimed to search for neuroendocrine cells in TGD cysts and to characterize immunophenotype of the thyroid follicles and epithelial lining of TGD. Out of 98 TGD cysts, 70% contained both cyst-lining epithelium and thyroid follicles, whereas 30% possessed only cyst-lining epithelium. Specimens eligible for immunohistochem. (n = 61) were stained for thyroid-specific and neuroendocrine markers. Thyroid remnants were pos. for thyroid transcription factor 1 (TTF-1) and other thyroid tissue-specific markers and neg. for calcitonin. TGD epithelium showed strong p63 positivity. We found that respiratory epithelium in 9.8% of TGDs contained neuroendocrine cells pos. for calcitonin, chromogranin A, and synaptophysin but neg. for carcinoembryonic antigen. In 44.2% of the cases, we detected compact buds, microscopic structures appearing as nests of epithelial cells with a biphasic population of basal (p63+) and central (TTF-1+) cells. Thyroid remnants in TGD expressed full spectrum of thyroid-specific markers and contained no C cells. Instead, calcitonin-expressing neuroendocrine cells were found among the respiratory epithelium of TGD. These cells can be a potential source of neuroendocrine tumors mimicking medullary carcinoma in median anlage derivatives We also discovered precursor compact buds with dual immunophenotype and proposed a concept of their morphogenesis. In the experimental materials used by the author, we found 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Reference of 1-Iodopyrrolidine-2,5-dione)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Przypis, Lukasz’s team published research in Scientific Reports in 2020 | CAS: 516-12-1

《Enhancing near-infrared photoluminescence from single-walled carbon nanotubes by defect-engineering using benzoyl peroxide》 was published in Scientific Reports in 2020. These research results belong to Przypis, Lukasz; Krzywiecki, Maciej; Niidome, Yoshiaki; Aoki, Haruka; Shiraki, Tomohiro; Janas, Dawid. Category: iodides-buliding-blocks The article mentions the following:

Single-walled carbon nanotubes (SWCNTs) have been modified with ester groups using typical organic radical chem. Consequently, traps for mobile excitons have been created, which enhanced the optical properties of the material. The proposed methodol. combines the benefits of mainstream approaches to create luminescent defects in SWCNTs while it simultaneously avoids their limitations. A step change was achieved when the aqueous medium was abandoned. The selection of an appropriate organic solvent enabled much more facile modification of SWCNTs. The presented technique is quick and versatile as it can engage numerous reactants to tune the light emission capabilities of SWCNTs. Importantly, it can also utilize SWCNTs sorted by chirality using conjugated polymers to enhance their light emission capabilities. Such differentiation is conducted in organic solvents, so monochiral SWCNT can be directly functionalized using the demonstrated concept in the same medium without the need to redisperse the material in water. In the part of experimental materials, we found many familiar compounds, such as 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Category: iodides-buliding-blocks)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Javed’s team published research in Journal of Organic Chemistry in 2022 | CAS: 516-12-1

In 2022,Javed; Khanam, Ariza; Mandal, Pintu Kumar published an article in Journal of Organic Chemistry. The title of the article was 《Glycosyl 3-Phenyl-4-pentenoates as Versatile Glycosyl Donors: Reactivity and Their Application in One-Pot Oligosaccharide Assemblies》.Product Details of 516-12-1 The author mentioned the following in the article:

Both glycoconjugates and oligosaccharides are important biomols. having significant roles in several biol. processes, and a new strategy for their synthesis is crucial. Here, we report a versatile N-iodosuccinimide/trimethylsilyl triflate (NIS/TMSOTf) promoted glycosidation approach with shelf-stable 3-phenyl-4-pentenoate glycosyl as a donor for the efficient synthesis of O/C-glycosides with free alcs., silylated alcs., and C-type nucleophile acceptors in good to excellent yields. The mild activation conditions and outstanding reactivity of Ph substituted pentenoate donors analogous to 4-pentenoate glycosyl donors enhance their applicability to various one-pot strategies for the synthesis of oligosaccharides, such as single-catalyst one-pot and acceptor reactivity-controlled one-pot strategies. The experimental process involved the reaction of 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Product Details of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Li, Ze-Lin’s team published research in New Journal of Chemistry in 2019 | CAS: 516-12-1

In 2019,New Journal of Chemistry included an article by Li, Ze-Lin; Wu, Peng-Yu; Cai, Chun. COA of Formula: C4H4INO2. The article was titled 《Nickel-catalyzed regioselective C-H halogenation of electron-deficient arenes》. The information in the text is summarized as follows:

A straightforward Ni(II)-catalyzed general strategy was developed for the ortho-halogenation of electron-deficient arenes such as benzamide, benzenesulfonamide, Me benzoate, etc. with easily available halogenating reagents N-halosuccinimides (NXS; X = Br, Cl and I). The transformation was highly regioselective and a wide substrate scope and functional group tolerance were observed This discovery could be of great significance for the selective halogenation of amides, benzoic esters and other substances with guiding groups. Mechanistic investigations were also described. The experimental process involved the reaction of 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1COA of Formula: C4H4INO2)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Pal, Debasish’s team published research in Carbohydrate Research in 2021 | CAS: 516-12-1

Application of 516-12-1In 2021 ,《Chemical synthesis of the pentasaccharide repeating unit of the O-specific polysaccharide from Ruminococcus gnavus》 appeared in Carbohydrate Research. The author of the article were Pal, Debasish; Naskar, Mrinal; Bera, Anirban; Mukhopadhyay, Balaram. The article conveys some information:

The Gram-pos. bacterium Ruminococcus gnavus (R. gnavus) has been identified to be responsible for symptoms of Crohn’s disease. R. gnavas produces a glucorhamnan polysaccharide and it is postulated that this polysaccharide induces inflammatory response through toll-like receptor 4 (TLR4). The current manuscript describes the chem. synthesis of the pentasaccharide repeating unit of the O-polysaccharide from R. gnavus. The major challenge associated with this particular synthesis is the presence of two consecutive 1,2-cis glucose units. The target oligosaccharide is achieved through a linear strategy from com. available sugars through rational protecting group manipulation. 1,2-cis glycosylation of glucose through remote participation of acyl group at the 6-O position is used successfully with excellent yield. In both cases, sole 1,2-cis products are obtained at -20°C through the activation of thioglycosides. In the experiment, the researchers used many compounds, for example, 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Application of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Li, Pengsong’s team published research in Science China Materials in 2020 | CAS: 516-12-1

《A multiphase nickel iron sulfide hybrid electrode for highly active oxygen evolution》 was published in Science China Materials in 2020. These research results belong to Li, Pengsong; Zhao, Xiuping; Duan, Xinxuan; Li, Yaping; Kuang, Yun; Sun, Xiaoming. Product Details of 516-12-1 The article mentions the following:

Development of highly active electrocatalysts for oxygen evolution reaction (OER) is one of the critical issues for water splitting, and most reported catalysts operate at overpotentials above 190 mV. Here we present a multiphase nickel iron sulfide (MPS) hybrid electrode with a hierarchical structure of iron doped NiS and Ni3S2, possessing a benchmark OER activity in alk. media with a potential as low as 1.33 V (vs. reversible hydrogen electrode) to drive an OER c.d. of 10 mA cm-2. The Fe doped NiS, combined with highly conductive disulfide phase on porous Ni foam, is believed to be responsible for the ultrahigh activity. Further more, d. functional theory simulation reveals that partially oxidized sulfur sites in Fe doped NiS could dramatically lower the energy barrier for the rate determining elementary reaction, thus contributing to the active oxygen evolution.1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Product Details of 516-12-1) was used in this study.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Song, Yuting’s team published research in Inorganica Chimica Acta in 2021 | CAS: 516-12-1

Song, Yuting; Tao, Jiayu; Wang, Yi; Cai, Zhengchun; Fang, Xianying; Wang, Shifa; Xu, Haijun published an article in 2021. The article was titled 《A novel dual-responsive fluorescent probe for the detection of copper(II) and nickel(II) based on BODIPY derivatives》, and you may find the article in Inorganica Chimica Acta.Related Products of 516-12-1 The information in the text is summarized as follows:

A novel dual-responsive fluorescence probe 6 was constructed by introducing a dipicolyamine moiety on the BODIPY-based skeleton via Sonogashira coupling reaction and confirmed by 1H NMR, 13C NMR, elemental anal. and high-resolution mass spectroscopy (HRMS). The present probe 6 exhibited high selectivity and sensitivity toward Cu2+ and Ni2+ detection over other competitive metal ions by fluorescence quenching phenomena, resp. In addition, the detection limits (DLs) for Cu2+ and Ni2+ were calculated to be as low as both 0.1 μM resp., which were lower than the maximum allowable level of the World Health Organization (WHO) limit for the drinking water. The stoichiometric ratio of the probe 6 toward the Cu2+ or Ni2+ ions was determined to be 1:1 according to the result of the Job′s plot and HRMS anal. These results indicated that probe 6 can be used as a selective ′′turn-off′′ fluorescent sensor for the detection of Cu2+ and Ni2+. In the experiment, the researchers used 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Related Products of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Bera, Madhumita’s team published research in Carbohydrate Research in 2020 | CAS: 516-12-1

《Synthesis of the tetrasaccharide repeating unit of the O-antigen from Pseudomonas putida BIM B-1100 having rare D-Quip3NAc》 was published in Carbohydrate Research in 2020. These research results belong to Bera, Madhumita; Mukhopadhyay, Balaram. HPLC of Formula: 516-12-1 The article mentions the following:

Chem. synthesis of the complex tetrasaccharide repeating unit of the O-antigen from Pseudomonas putida BIM B-1100 is accomplished in the form of its 2-aminoethyl glycoside to leave the scope for further glycoconjugate formation without hampering the anomeric stereochem. A [2 + 2] strategy is followed to complete the total synthesis and a late stage TEMPO mediated oxidation is used to install the required uronic acid. A radical mediated 6-deoxygenation with subsequent protecting group manipulation strategy is used for the preparation of the rare D-FucpNAc and D-Quip3NAc derivatives from suitable D-glucosamine derivatives The results came from multiple reactions, including the reaction of 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1HPLC of Formula: 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Olivas, A.’s team published research in Fuel Processing Technology in 2020 | CAS: 516-12-1

《Transition-metal influence (Fe, Co, Ni, Cu) on the MoWS catalyst for biphenyl hydrogenation》 was written by Olivas, A.; Gaxiola, E.; Cruz-Reyes, J.; Alvarez-Amparan, M. A.; Valdez, R.. Computed Properties of C4H4INO2 And the article was included in Fuel Processing Technology in 2020. The article conveys some information:

The hydrogenation of aromatic hydrocarbon compounds derived of hydrocarbon fuels is crucial to avoid the current environment pollution, harmful to human health. Also, the hydrogenated products can be used as chem. intermediates, additives, and in other chem. processes. The search of efficient and cost-effective catalysts for the hydrogenation of aromatic hydrocarbon compounds is a current challenge in the industrial and scientific community. In this study, trimetallic unsupported MMoW (M = Fe, Co, Ni, and Cu) sulfide catalysts were synthesized and tested in the liquid-phase biphenyl (BP) hydrogenation at 300 °C and 5.5 MPa of H2 pressure. The catalysts were characterized by XRD, SEM-EDX, TEM-SAED and adsorption-desorption of N2. The presence of NiS, CoSx, MoFe2S4, Cu9S5 crystalline sulfide phases together with Mo(W)S2 crystalline sulfide phase, as well as the crystallite size and the surface area, influenced the catalytic performance. Ni-based catalysts were the most active in the BP hydrogenation. A BP conversion value of ∼99% of biphenyl and selectivity of 52% towards cyclohexylbenzene (CHB) and 47% towards bicyclohexyl were reached using NiMoWS catalyst. The presence of NiS crystals, stacked curve-shape Mo(W)S2 crystalline phases and larger surface area values increased the catalytic activity using NiMoWS catalysts. The experimental process involved the reaction of 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Computed Properties of C4H4INO2)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Wu, Caiyun’s team published research in Sustainable Energy & Fuels in 2020 | CAS: 516-12-1

《Mo, Co co-doped NiS bulks supported on Ni foam as an efficient electrocatalyst for overall water splitting in alkaline media》 was written by Wu, Caiyun; Du, Yunmei; Fu, Yunlei; Feng, Di; Li, Hui; Xiao, Zhenyu; Liu, Yanru; Yang, Yu; Wang, Lei. Application In Synthesis of 1-Iodopyrrolidine-2,5-dione And the article was included in Sustainable Energy & Fuels in 2020. The article conveys some information:

In this study, a composite of Mo, Co co-doped NiS bulks grown on an Ni foam (Mo,Co-NiS/NF) was synthesized as a bi-functional electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) using a simple method. The existence of ZIF-67 and Mo ensure the even distribution of Co and Mo elements and the formation of N doped carbon layer in Mo, Co-NiS/NF. Mo, Co co-doping and NF support greatly improved the electrocatalytic performance of NiS bulks, because metal element doping could improve the intrinsic activity and elec. conductivity Moreover, the Ni foam could act as a substrate to avoid aggregation and provide nickel source to form the bimetallic sulfide. The product Mo,Co-NiS/NF-400 showed outstanding electrochem. properties, with ultralow overpotential (92 mV vs. RHE) for HER and ultralow overpotential (117.2 mV vs. RHE) for OER to achieve 10 mA cm-2, as well as the ultralow cell voltage (1.36 V) to achieve 20 mA cm-2 for overall water splitting. This study provides an available method to promote the electrocatalytic activity of the traditional monometallic sulfides for overall water splitting. In the experiment, the researchers used many compounds, for example, 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Application In Synthesis of 1-Iodopyrrolidine-2,5-dione)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com