516-12-1 Archives - Page 10 of 10 - Iodides-buliding-blocks

Zou, Long’s team published research in Chemical Communications (Cambridge, United Kingdom) in 2020 | CAS: 516-12-1

1-Iodopyrrolidine-2,5-dione(cas: 516-12-1) is used in the preparation of vinyl sulfones from olefins and benzenesulfinic acid. It acts as a source for I+ and involved in Hunsdiecker reactions for the conversion of cinnamic acids, and propiolic acids to the corresponding alfa-halostyrenes and 1-halo-1-alkynes respectively. SDS of cas: 516-12-1

《Photo-driven haloazidation cyclization of 1,5-enynes having cyano groups with TMSN3 and NIS/NCS/NBS under metal-free conditions》 was published in Chemical Communications (Cambridge, United Kingdom) in 2020. These research results belong to Zou, Long; Wang, Lei; Sun, Li; Xie, Xiaofei; Li, Pinhua. SDS of cas: 516-12-1 The article mentions the following:

A visible-light-driven three-component haloazidation cyclization of 1,5-enynes I (R1 = H, 3-F, 4-Me, 5-MeO, etc.; R2 = cyclopropyl, Ph, 4-BrC6H4, 3-pyridyl, etc.) having cyano groups with TMSN3, and N-halosuccinimides (halo = X = I, Cl, Br) under metal-free and oxidant-free conditions to afford the corresponding (halovinyl)indans II has been developed. The reaction proceeds via radical addition/5-exo-dig cyclization/radical coupling process with the successive formation of C-N, C-C, and C-halogen (Cl, Br, and I) bonds, which is initiated by the addition of an azidyl radical to the carbon-carbon double bond of the 1,5-enyne. In the experiment, the researchers used 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1SDS of cas: 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Mao, Min’s team published research in Journal of Materials Science: Materials in Electronics in 2020 | CAS: 516-12-1

《Enhancement of catalytic hydrogen evolution by NiS modification of ZnCo2O4 with cubic morphology》 was written by Mao, Min; Xu, Jing; Li, Jingjiao; Zhao, Sheng; Li, Xuanhao. Related Products of 516-12-1 And the article was included in Journal of Materials Science: Materials in Electronics in 2020. The article conveys some information:

A review. Abstract: It was the constant pursuit of researchers to explore catalysts with higher catalytic activity, and the use of co-catalysts to modify the performance of photocatalytic materials had a significant effect on charge separation In this paper, the non-precious metal NiS-modified ZnCo2O4 composite catalytic material prepared by hydrothermal method had high-efficiency catalytic performance. When the weight ratio of NiS to ZnCo2O4 was 12%, the optimal catalytic activity is 3.57 mmol g-1 h-1, which was more than twice that of ZnCo2O4. The presence of NiS not only improved the sp. surface area of the catalyst and its ability to respond to light, but the close interface formed by the combination of the two monomer phases accelerated the transfer and the utilization of the photocharge on ZnCo2O4 to NiS, thereby promoting the separation of electron holes and improving the photocatalytic activity of the catalyst. According to the research results, the mechanism of hydrogen production in the photocatalytic system was revealed. In this paper, NiS was used to modify the bimetallic oxide with cubic appearance, which provided a new strategy for the development of new photocatalysts. The experimental process involved the reaction of 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Related Products of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Bosch, Eric’s team published research in Acta Crystallographica, Section C: Structural Chemistry in 2022 | CAS: 516-12-1

In 2022,Bosch, Eric; Bowling, Nathan P. published an article in Acta Crystallographica, Section C: Structural Chemistry. The title of the article was 《Co-operative halogen bonds and nonconventional sp-C-H·O hydrogen bonds in 1:1 cocrystals formed between diethynylpyridines and N-halosuccinimides》.Product Details of 516-12-1 The author mentioned the following in the article:

The rapid evaporation of 1:1 solutions of diethynylpyridines and N-halosuccinimides, that react together to form haloalkynes, led to the isolation of unreacted 1:1 cocrystals of the two components. The 1:1 cocrystal formed between 2,6-diethynylpyridine and N-iodosuccinimide (C4H4INO2·C9H5N) contains an N-iodosuccinimide-pyridine I·N halogen bond and two terminal alkyne-succinimide carbonyl C-HO hydrogen bonds. The three-dimensional extended structure features interwoven double-stranded supramol. polymers that are interconnected through halogen bonds. The cocrystal formed between 3,5-diethynylpyridine and N-iodosuccinimide (C4H4INO2.C9H5N) also features an I·N halogen bond and two C-H·O hydrogen bonds. However, the components form essentially planar double-stranded one-dimensional zigzag supramol. polymers. The cocrystal formed between 3,5-diethynylpyridine and N-bromosuccinimide (C4H4BrNO2.C9H5N) is isomorphous to the cocrystal formed between 3,5-diethynylpyridine and N-iodosuccinimide, with a Br·N halogen bond instead of an I·N halogen bond. In the experiment, the researchers used many compounds, for example, 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Product Details of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Suzuki, Takanobu’s team published research in Chemical Communications (Cambridge, United Kingdom) in 2019 | CAS: 516-12-1

The author of 《Photooxygenation inhibits tau amyloid formation》 were Suzuki, Takanobu; Hori, Yukiko; Sawazaki, Taka; Shimizu, Yusuke; Nemoto, Yu; Taniguchi, Atsuhiko; Ozawa, Shuta; Sohma, Youhei; Kanai, Motomu; Tomita, Taisuke. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2019. Safety of 1-Iodopyrrolidine-2,5-dione The author mentioned the following in the article:

Tau amyloid formation and deposition are responsible for the onset of Alzheimer’s disease. In particular, the seeding activity of the tau protein plays an important role in the spreading of tau pathol. via its propagation in the human brain. Here we demonstrate that catalytic photo-oxygenation markedly suppresses tau seeding activity, resulting in the inhibition of amyloid formation, both in vitro and in cultured cells. In the part of experimental materials, we found many familiar compounds, such as 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Safety of 1-Iodopyrrolidine-2,5-dione)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Okubo, Masayoshi’s team published research in Journal of Polymer Science, Part A: Polymer Chemistry in 2019 | CAS: 516-12-1

The author of 《Partitioning effect of nitrogen catalyst into polymerizing particles on dispersion reversible chain transfer catalyzed polymerization (dispersion RTCP) of methyl methacrylate in supercritical carbon dioxide and organic solvents》 were Okubo, Masayoshi; Kitayama, Yukiya; Taniyama, Tomoya; Liu, Xiang; Zhang, Jianzheng; Shi, Hao. And the article was published in Journal of Polymer Science, Part A: Polymer Chemistry in 2019. COA of Formula: C4H4INO2 The author mentioned the following in the article:

Reversible chain transfer catalyzed polymerization (RTCP) in dispersion polymerization system (dispersion RTCP) of Me methacrylate (MMA) was performed with N-iodosuccimide (NIS) as a nitrogen catalyst in supercritical carbon dioxide (scCO2). The solubility of NIS in scCO2 can be controlled by tuning the pressure, and this led to promote NIS partitioning into polymerizing particles. As a result, the mol. weight distribution control was successfully improved by decreasing the NIS solubility in the medium by tuning the scCO2 at a low pressure of 20 MPa. On the other hand, at the same NIS concentration, a solution RTCP of MMA in toluene as a homogeneous polymerization system did not proceed with a controlled/living manner. The importance of NIS partitioning into the polymerizing particles was also confirmed in hexane as well as scCO2 medium. From these results, it was clarified that the NIS catalyst partitioning into the polymerizing particles as main polymerization loci is a key factor to control the mol. weight distribution in the dispersion RTCP of MMA in scCO2. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018. In the experimental materials used by the author, we found 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1COA of Formula: C4H4INO2)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Golebiewska, Justyna’s team published research in Phosphorus, Sulfur and Silicon and the Related Elements in 2022 | CAS: 516-12-1

In 2022,Golebiewska, Justyna; Bartoszewicz, Agnieszka; Kalek, Marcin; Stawinski, Jacek published an article in Phosphorus, Sulfur and Silicon and the Related Elements. The title of the article was 《Second generation of nucleotide analogs》.Computed Properties of C4H4INO2 The author mentioned the following in the article:

The most common type of modification of a phosphorus center is the replacement of one or two non-bridging atoms of the phosphate group with different heteroatoms (e.g., sulfur, selenium) or groups of atoms (e.g., Me, borane). Such compounds are referred to as the first generation of nucleotide analogs, e.g. I. We were interested in exploring the possibility of further functionalizing of the heteroatoms present in nucleoside phosphorothioates, phosphoroselenoate or boranephosphonates to create a second generation of nucleotide analogs with hopefully new biol. properties. Here we report a preliminary account of our work on introducing addnl. modifications on the sulfur or selenium heteroatom of nucleotide analogs.1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Computed Properties of C4H4INO2) was used in this study.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Lin, Xiongjie’s team published research in Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy in 2019 | CAS: 516-12-1

In 2019,Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy included an article by Lin, Xiongjie; Tang, Danting; He, Tian; Xu, Zheng; Qiu, Huayu; Zhang, Qian; Yin, Shouchun. Application of 516-12-1. The article was titled 《A series of novel BODIPY-fluorene copolymers: Synthesis, characterization, optical-electronic and nonlinear optical properties》. The information in the text is summarized as follows:

A series of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with different connection sites and conjugation length and fluorene alternating conjugated polymers have been synthesized via palladium-catalyzed Suzuki coupling reaction. The polymers were fully characterized by 1H NMR spectroscopy and gel permeation chromatog. (GPC), and their properties were measured by thermogravimetric anal. (TGA), UV-vis absorption spectroscopy, cyclic voltammetry (CV), photoluminescence (PL) spectroscopy, the Z-scan technique, and theor. calculation using d.-functional theory (DFT) method. The results indicate that the connection sites and conjugation length of BODIPY have great effect on the optical-electronic and nonlinear optical properties of the conjugated BODIPY- fluorene copolymers although they don’t affect the polymerization process. The absorption and emission peaks of P1 exhibit red shifts compared to those of P2 and P3. The polymers show good nonlinear optical properties that are closely related to the connection sites of the BODIPY pendants. P1 exhibits relatively richer nonlinear optical (NLO) properties than P2 and P3. The third order nonlinear optical coefficient (χ(3)) of P1 is 3.57 × 10-11 esu, which is ∼4 times larger than those of P2 and P3. In the experiment, the researchers used many compounds, for example, 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Application of 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Tian, Zhenhao’s team published research in Journal of Materials Chemistry B: Materials for Biology and Medicine in 2019 | CAS: 516-12-1

The author of 《A highly sensitive and selective two-photon fluorescent probe for glutathione S-transferase detection and imaging in living cells and tissues》 were Tian, Zhenhao; Tian, Xiangge; Feng, Lei; Tian, Yan; Huo, Xiaokui; Zhang, Baojing; Deng, Sa; Ma, Xiaochi; Cui, Jingnan. And the article was published in Journal of Materials Chemistry B: Materials for Biology and Medicine in 2019. Recommanded Product: 516-12-1 The author mentioned the following in the article:

Glutathione transferase (GST) is a very important metabolic enzyme that mediates the wide metabolism of endogenous and xenobiotic compounds; it usually has a significant over expression in cancer cells, which is a key reason resulting in drug resistance, and will show an obvious down regulation during liver injury, thus it was also regarded as a vital biomarker in clin. diagnosis. Herein, based on boron-dipyrromethene (BODIPY) dye, a two-photon probe BNPA was designed for the real-time detection of GST activities and fluorescence imaging in both cancer cells and liver tissues. Importantly, BNPA exhibited a high selectivity, ultrahigh imaging resolution and showed a classic Michaelis-Menten kinetics toward GSTs. Furthermore, it was successfully used for monitoring the GST activities in living cells and deep tissues by two-photon imaging, as well as detecting the down regulation of GST activities during α-naphthylisothiocyanate (ANIT) induced liver injury. Our results fully demonstrated that BNPA could serve as a promising tool for evaluating the GST function and the process of cellular GSTs in living systems, and also provided a new approach for studying GST-associated liver diseases, which would be greatly useful for rational drug use and disease diagnosis in clinics.1-Iodopyrrolidine-2,5-dione(cas: 516-12-1Recommanded Product: 516-12-1) was used in this study.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Sharipov, Bulat T.’s team published research in Chemistry of Heterocyclic Compounds (New York, NY, United States) in 2022 | CAS: 516-12-1

Sharipov, Bulat T.; Davidova, Anna N.; Valeev, Farid A. published an article in 2022. The article was titled 《cis-Annulation of an oxazoline fragment to levoglucosenone and the synthesis of 4-substituted 3-amino-1,6-anhydro-3-deoxy-β-D-mannopyranose》, and you may find the article in Chemistry of Heterocyclic Compounds (New York, NY, United States).COA of Formula: C4H4INO2 The information in the text is summarized as follows:

Chiral 2-trichloromethyl-oxazolines 4,5-cis-annulated to a carbohydrate fragment were synthesized on the basis of levoglucosenone. The synthesized compounds were converted by acid hydrolysis into 4-substituted 3-amino-1,6-anhydro-3-deoxy-β-D-mannopyranoses. Intramol. amination of allyl trichloroacetimidates by electrophilic reagents was used to construct the oxazoline ring. It was established that trichloroacetimidates containing an epoxide ring in α,β-positions spontaneously undergo re-cyclization with the formation of an oxazoline ring. In addition to this study using 1-Iodopyrrolidine-2,5-dione, there are many other studies that have used 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1COA of Formula: C4H4INO2) was used in this study.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Mikhailov, Yu. M.’s team published research in International Journal of Self-Propagating High-Temperature Synthesis in 2021 | CAS: 516-12-1

Mikhailov, Yu. M.; Aleshin, V. V.; Zhemchugova, L. V.; Bakeshko, A. V.; Kovalev, D. Yu. published an article in 2021. The article was titled 《Synthesis of Nanosized FeS, CoS and NiS Crystals in a Wave of Flameless RDX Combustion》, and you may find the article in International Journal of Self-Propagating High-Temperature Synthesis.SDS of cas: 516-12-1 The information in the text is summarized as follows:

Thermochem. interactions of Fe, Co and Ni precursors with thiourea, ammonium thiocyanate, and sulfur in the wave of flameless combustion of RDX in ballasted systems were explored. In case of thiourea or ammonium thiocyanate as a source of sulfur, combustion-synthesized sulfides CoS, NiS and oxides Fe2O3, Fe3O4 turn encapsulated in a viscous material formed upon thermal decomposition of organic binder and sulfur-containing compounds The replacement of thiourea or ammonium thiocyanate by elemental sulfur afforded for the combustion synthesis of FeS, CoS, and NiS powders with a sp. surface of 37-72 m2/g. In the part of experimental materials, we found many familiar compounds, such as 1-Iodopyrrolidine-2,5-dione(cas: 516-12-1SDS of cas: 516-12-1)

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com