Category: 364-12-5

On August 9, 1994, Tsucha, Kazuhiko; Sugiura, Atsushi; Suzuki, Kenji; Fujii, Tsunenori published a patent.Recommanded Product: 364-12-5 The title of the patent was Trifluoromethyl benzene derivative and liquid crystal composition containing same. And the patent contained the following:

The title trifluoromethyl-benzene derivative, 1-CF3-2-(AmR1)-5-(BnR2)-C6H3 [ R1, R2 = C1-14 alkyl, alkoxy, alkoxy-alkyl; A, B = phenylene, biphenylene, p-cyclohexyl phenylene, bicyclohexylene; m, n = 0, 1 ] is claimed. The title composition showed improved characteristics suitable for ferroelec. and nematic liquid crystal displays. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Recommanded Product: 364-12-5

The Article related to liquid crystal composition trifluoromethyl benzene, lcd ferroelec nematic trifluoromethyl benzene, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Other and other aspects.Recommanded Product: 364-12-5

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On February 21, 2013, Dineen, Thomas; Marx, Isaac E.; Nguyen, Hanh Nho; Weiss, Matthew published a patent.Recommanded Product: 5-Bromo-2-iodobenzotrifluoride The title of the patent was Preparation of indolesulfoamide derivatives as sodium channel inhibitors useful in the treatment of pain disorders. And the patent contained the following:

The invention relates to indolesulfoamide derivatives of formula I and II; pharmaceutical composition containing them; and their preparation and use as sodium channel inhibitors for the treatment of pain disorders. Indolesulfoamide derivatives of formula I and II, wherein X1, X2 and X3 are independently CH, Chalo, CC1-6 alkyl, COC1-6 alkyl, CCN and N; R1 is (un)substituted 5- and 6-membered (hetero)aryl and (hetero)cycloalkyl; R2 is (un)substituted 5- to 10-membered (hetero)cycloalkyl and (hetero)aryl; R3 is H, C1-6 alkyl, COC1-6 alkyl, CO2C1-6 alkyl and SO2C1-6 alkyl; R4 is H and C1-6 alkyl; and their pharmaceutically acceptable salt, are claimed. Example compound III was prepared by cross coupling of 3-bromo-N-(2,4-dimethoxybenzyl)-N-(1,2,4-thiadiazol-5-yl)-1H-indole-6-sulfonamide with (4-chloro-2-(1-methyl-1H-pyrazol-5-yl)phenyl)boronic acid to afford 3-(4-chloro-2-(1-methyl-1H-pyrazol-5-yl)phenyl)-N-(2,4-dimethoxybenzyl)-N-(1,2,4-thiadiazol-5-yl)-1H-indole-6-sulfonamide, which underwent debenzylation to give compound III. All the example compounds were evaluated for their sodium channel inhibitory activity. From the assay, it was determined that example compound III exhibited IC50 value of 0.445 渭M and > 10.0 渭M against Nav 1.7 and Nav 1.5 resp. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Recommanded Product: 5-Bromo-2-iodobenzotrifluoride

The Article related to indolesulfoamide preparation sodium channel inhibitor treatment pain, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Recommanded Product: 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On December 10, 2015, Grammenos, Wassilios; Boudet, Nadege; Mueller, Bernd; Escribano Cuesta, Ana; Lohmann, Jan Klaas; Grote, Thomas; Craig, Ian Robert; Fehr, Marcus; Quintero Palomar, Maria Angelica; Lauterwasser, Erica May Wilson; Kretschmer, Manuel published a patent.Product Details of 364-12-5 The title of the patent was Preparation of substituted [1,2,4]triazole compounds as agrochemical fungicides. And the patent contained the following:

The present invention relates to compounds of the formula I [R1 = each (un)substituted C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, or C3-6 cycloalkyl; R2 = H or each (un)substituted C1-4 alkyl, C2-4 alkenyl, or C2-4 alkynyl; R3 = H, halogen, cyano, or each (un)substituted C1-4 alkyl, C1-4 alkoxy, C2-4 alkenyl, C2-4 alkynyl, C3-6 cycloalkyl, or S(O)p(C1-4 alkyl), wherein p = 0-2; R4, R5, R6 = independently H, halogen, or each (un)substituted C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C1-4 alkoxy, C3-6 cycloalkyl, C3-6 cycloalkenyl, C3-6 cycloalkyl-C1-4 alkyl, -N(Ra)2, C3-6 halogencycloalkyl, aryl, or aryloxy; R4 and R5 together are =O, and R6 is as defined above; R4 and R5 together are :C(Ra)2, and R6 is as defined above and Ra is as defined below; or R4 and R5 together form a carbocycle or heterocycle, and R6 is as defined above; Ra = independently halogen, OH, cyano, C1-4 alkyl, C1-4 halogenalkyl, C3-6 cycloalkyl, C3-6 halogencycloalkyl, C1-4 alkoxy, C1-4 halogenalkoxy, or and Si(C1-4 alkyl)3; X = O, S(O)n, wherein n = 0-2, or (un)substituted NH] and the N-oxides and the agriculturally acceptable salts thereof. These compounds have an improved activity and/or a broader activity spectrum against phytopathogenic harmful fungi and are useful for combating phytopathogenic fungi in plants or seeds. Thus, a mixture of 3-chloro-4-[1-cyclopropyl-1-hydroxy-2-(1,2,4-triazol-1-yl)ethyl]phenol 500, Cs2CO3 870, and dibromotetrafluoroethane 930 mg in 5 mL DMSO was heated to 50掳 for 3 days to give, after workup, 1-[4-(2-bromo-1,1,2,2-tetrafluoroethoxy)-2-chlorophenyl]-1-cyclopropyl-2-(1H-1,2,4-triazol-1-yl)ethanol (II) as a yellow oil. One invention compound (III) completely controlled the growth of gray mold Botrytis cinerea at 31 ppm, rice blast Pyricuiaria oryzae at 31 ppm, and leaf blotch on wheat caused by Septoria tritici at 8 ppm. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Product Details of 364-12-5

The Article related to triazole preparation agrochem fungicide, phenylcyclopropyltriazolylethanol preparation agrochem fungicide, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Product Details of 364-12-5

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On March 26, 2015, Tokito, Shizuo; Kumaki, Daisuke; Mamada, Masashi; Fukuda, Kenjiro; Tanaka, Yasuhiro; Shima, Hidetaka; Yoneda, Yasuhiro; Fujita, Harunori; Kakita, Kazuaki; Omata, Youji; Yamada, Natsuko; Honma, Takashi; Machida, Toshikazu published a patent.Quality Control of 5-Bromo-2-iodobenzotrifluoride The title of the patent was Preparation of benzobis(thiadiazole) derivatives, ink containing them, and organic electronic device using them. And the patent contained the following:

The present invention pertains to a benzobis(thiadiazole) derivative represented by general formula [I; R1 = straight-chain or branched alkyl group or any of group A; group A = , NO2, F, Br, CF3, SCF3, C(R)F2, cyano, CO2R, Cl, iodo, OCF3, SF6, OC(R)F2, or OC(O)R, SC(R)F2; R2 = H; R3 = H, straight-chain or branched alkyl group, or any of group A; at least one R1 and R3 = one of the group A; the two R1s, two R2s, and two R3s may be identical to or different from one another; R = straight-chain or branched alkyl group]. These compounds are thermally stable, soluble in organic solvents, capable of fabricating thin films by coating method, stable in the air, and are excellent in hole and/or electron field effect mobility (渭FE) and are useful for organic electronic devices such as organic thin film transistor, organic electroluminescent device, display devices, displays, and solar cells. The use of these compounds in the semiconductor layer of organic thin film transistor (TFT), high field effect mobility characteristic is realized. When they are used in the hole or electron transport layer of organic electroluminescent device, high luminescent efficiency is realized. When using in the charge-separation layer, hole transport layer, or electron transport layer of solar cells, high incident photon to current conversion efficiency (IPCE) is realized. Thus, 4,7-dibromobenzo[1,2-c:4,5-c’]bis[1,2,5]thiadiazole was coupled with 2-(tributylstannyl)-5-[3-(trifluoromethoxy)phenyl]thiophene in the presence of dichlorobis(triphenylphosphine)palladium in anhydrous toluene at 100掳 (inner temperature) for 6 h, followed by filtration of the crude product (2.1 g) and sublimation for purification to give 0.25 g compound (II) as green solid. The solubility of II was 0.1 weight% in toluene at 100掳, 0.1 weight% in mesitylene at 80掳, and 0.3 weight% in mesitylene at 130掳. A semiconductor ink containing 0.2 weight% II in Me salicylate was added dropwise into a barrier rib pattern on a polyvinylphenol-melamine thin film (formed on a glass substrate with an aluminum gate electrode), dried at 80掳 to form an organic semiconductor layer on which gold film was vacuum-deposited as source and drain electrode. The fabricated organic TFT had field effect mobility of 6.3 X 10-1 cm2/Vs. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Quality Control of 5-Bromo-2-iodobenzotrifluoride

The Article related to organic thin film transistor benzobisthiadiazole semiconductor layer, benzobisthiadiazole preparation solar cell organic electroluminescent device, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Quality Control of 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On July 7, 2022, Jin, Jinghai; Shen, Chunli; Wu, Chengde; Chen, Shuhui published a patent.Recommanded Product: 364-12-5 The title of the patent was Preparation of selinexor analogs as XOP1 inhibitors. And the patent contained the following:

The invention relates to selinexor analogs (e.g., I) pharmaceutically acceptable salts thereof; pharmaceutical preparation comprising them; and their use as XOP1 inhibitors. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Recommanded Product: 364-12-5

The Article related to selinexor analog antitumor xop1 inhibitor preparation, Heterocyclic Compounds (More Than One Hetero Atom): Pyrazines and Quinoxalines (Including Piperazines) and other aspects.Recommanded Product: 364-12-5

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On May 1, 2007, Suga, Takeo; Pu, Yong-Jin; Kasatori, Shinji; Nishide, Hiroyuki published an article.Safety of 5-Bromo-2-iodobenzotrifluoride The title of the article was Cathode- and Anode-Active Poly(nitroxylstyrene)s for Rechargeable Batteries: p- and n-Type Redox Switching via Substituent Effects. And the article contained the following:

Three polystyrenes bearing redox-active nitroxide radical(s) in each repeating unit, poly[4-(N-tert-butyl-N-oxylamino)styrene] (1), poly[3,5-di(N-tert-butyl-N-oxylamino)styrene] (2), and poly[4-(N-tert-butyl-N-oxylamino)-3-trifluoromethylstyrene] (3), were synthesized via free radical polymerization of protected precursor styrenic derivatives and subsequent chem. oxidation The radicals in these polymers were robust at ambient conditions, and the polymers possessed radical densities of 2.97 脳 1021, 4.27 脳 1021, and 1.82 脳 1021 unpaired electrons/g for 1-3, resp., resulting in an electrode-active material with a high charge/discharge capacity. Particularly, the dinitroxide functional polymer 2 possessed the highest radical d. Cyclic voltammetry of the poly(nitroxylstyrene) 1 revealed a reversible redox at 0.74 V vs. Ag/AgCl, which was assigned to the oxidation of the nitroxide radical to form the oxoammonium cation (p-type doped state). However, the poly(nitroxylstyrene) ortho-substituted with the electron-withdrawing trifluoromethyl Group 3 showed a reversible redox at -0.76 V, ascribed to the n-type redox pair between the nitroxide radical and the aminoxy anion. Thus, the nitroxide radical polymer could be switched from p-type material suitable for a cathode to n-type material (anode-active) via altering the electron-withdrawing character of the substituents on the poly(nitroxylstyrene). This is the 1st report of an n-type radical polymer and the 1st report of using substituent effects to switch the redox behavior of the polymer. This versatile switching ability enables these polymers to function as components of metal-free electrodes in rechargeable batteries. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Safety of 5-Bromo-2-iodobenzotrifluoride

The Article related to cathode anode poly nitroxylstyrene rechargeable battery switching redox, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.Safety of 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Galan, Elena; Perrin, Mickael L.; Lutz, Martin; van der Zant, Herre S. J.; Grozema, Ferdinand C.; Eelkema, Rienk published an article in 2016, the title of the article was Synthesis of 1,2-biphenylethane based single-molecule diodes.Application In Synthesis of 5-Bromo-2-iodobenzotrifluoride And the article contains the following content:

We have described the synthesis of novel biphenylethane-based wires for mol. electronics. Exceptional single-mol. diode behavior was predicted for unsym. substituted biphenylethane derivatives, synthesized here using the so far unexplored unsym. substituted 1,2-bis(4-bromophenyl)ethanes as key intermediates, which were obtained from the corresponding tolane precursor by selective hydrogenation. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Application In Synthesis of 5-Bromo-2-iodobenzotrifluoride

The Article related to ethynyl ethylnylphenethyldifluorobenzene preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Application In Synthesis of 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On December 5, 2019, Pitts, Cody Ross; Santschi, Nico; Togni, Antonio published a patent.Product Details of 364-12-5 The title of the patent was Method for preparing polyfluorinated compound. And the patent contained the following:

The present invention relates to a process for preparing a polyfluorinated compound of formula Ar-Ri , wherein Ar-Ri(I) is an aromatic ring system wherein R1 is selected from the group consisting of SF4CI, SF3, SF2CF3, TeFS, TeF4CF3, SeF3, IF2, SeF2CF3, and IF4, X2 is N or CR2, X3 is N or CR3, X4 is N or CR4 , X5 is N or CR5, X 6 is N or CR6, and the total number of nitrogen atoms in the aromatic ring system is between 0 and 3, and if X5 is CR5 and X6 is CR6 R5 and R6 may form together a saturated or unsaturated five or six membered ring system comprising one or more nitrogen, wherein said five or six membered ring system may be substituted with one or more residues R 7 said process involving the following reaction step reacting a starting material selected from the group consisting of Ar2S2, Ar2Te2, Ar2Se2, ArSCF3, Arl, ArTeCF3, ArSeCF3, ArSCF3, and ArSCl, wherein Ar has the same definition as above, with trichloroisocyanuric acid (TCICA) in the presence of the alkali metal fluoride (MF). The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Product Details of 364-12-5

The Article related to trichloroisocyanuric acid alkali metal fluoride fluorination reagent, polyfluorinated compound preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Product Details of 364-12-5

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On May 17, 2022, Kusakabe, Yu; Wada, Yoshimasa; Misono, Tomoya; Suzuki, Katsuaki; Shizu, Katsuyuki; Kaji, Hironori published an article.Recommanded Product: 5-Bromo-2-iodobenzotrifluoride The title of the article was Imidazole Acceptor for Both Vacuum-Processable and Solution-Processable Efficient Blue Thermally Activated Delayed Fluorescence. And the article contained the following:

The members of the imidazole family have been widely used for electron transporting, host, conventional fluorescent, and phosphorescent materials. Although the imidazole core also has great potential as an acceptor segment of deep-blue thermally activated delayed fluorescence (TADF) owing to its high triplet energy, the emission color of imidazole-based TADF organic light-emitting diodes (OLEDs) has so far been limited to blue to green. In this work, four acridan-imidazole systems are theor. designed aiming for deep- or pure-blue emitters. All four emitters exhibit deep-blue to blue emission owing to the high energy levels of the lowest excited singlet states, exhibiting y coordinates of Commission Internationale de l’Eclairage coordinates between 0.06 and 0.26. The mol. composed of a trifluoromethyl-substituted benzimidazole acceptor in combination with a tetramethyl-9,10-dihydroacridine donor (named MAc-FBI) achieves a high maximum external quantum efficiency (EQEMAX) of 13.7% in its application to vacuum-processed OLEDs. The emitter has high solubility even in ecofriendly nonhalogenated solvents, which motivates us to fabricate solution-processed MAc-FBI-based OLEDs, resulting in an even higher EQEMAX of 16.1%. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Recommanded Product: 5-Bromo-2-iodobenzotrifluoride

The Article related to imidazole acceptor vacuum processable solution blue thermally activated fluorescence, Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers: Structure Correlation With Physical Properties and other aspects.Recommanded Product: 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On May 6, 2016, Welz, Claudia; Koehler, Adeline; Boerngen, Kirsten; Kulke, Daniel; Goergens, Ulrich; Schwarz, Hans-Georg; Ilg, Kerstin published a patent.Computed Properties of 364-12-5 The title of the patent was Preparation of arylamide compounds for use in anthelmintic treatment. And the patent contained the following:

Disclosed are compounds of formula I which possess anthelmintic properties wherein the structural elements have the meaning as indicated in the description. Further disclosed are such compounds for the control, treatment and/or prevention of infections with helminths in animals and humans. Compounds of formula I wherein n is 1, 2 and 3; m is 0, 1, 2, 3 and 4; R1 is H, CHO, OH, C1-4 alkyl,e tc.; each X is independently halo, NO2, CN, amino, etc.; each Y is independently H, halo, NO2, CN, OH, SH, etc.; A is (un)substituted Ph, (un)substituted pyridinyl and (un)substituted pyrazinyl; and salts, solvates, solvates of salts, N-oxides, metal complexes and metalloid complexes thereof, are claimed. Example compound II was prepared by amidation of 2-trifluoromethylbenzoyl chloride with 2-(4-bromo-2- chloro-phenyl)-2,2-difluoro-ethanamine; the resulting N-[2-(4-bromo-2-chloro-phenyl)-2,2-difluoro-ethyl]-2-(trifluoromethyl)benzamide underwent cross-coupling with 4-fluorophenylboronic acid to give compound II. The invention compounds were evaluated for their anthelmintic activity (some data given). The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Computed Properties of 364-12-5

The Article related to arylamide preparation anthelmintic, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Computed Properties of 364-12-5

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com