Category: 1774-47-6

Tanaka, Yuki; Bai, Shiqiang; Wang, Xizu; Tee, Si Yin; Lim, Siew Lay; Ke, Lin; Dolmanan, Surani B.; Lee, Coryl Jing Jun; Lim, Poh Chong; Yao, Xiang; Wu, Jishan; Han, Ming-Yong published an article in 2021. The article was titled 《Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH3)3SOPbI3》, and you may find the article in Chemical Communications (Cambridge, United Kingdom).Electric Literature of C3H9IOS The information in the text is summarized as follows:

The authors report the synthesis and optical and electronic properties of a one-dimensional sulfoxonium-based hybrid metal halide in an orthorhombic crystal system with a Pnma space group. To provide direct insights, a method is developed to calculate tolerance factors with the ionic radii of non-spherical cations from x-ray crystallog. data.Trimethylsulfoxonium iodide(cas: 1774-47-6Electric Literature of C3H9IOS) was used in this study.

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.Electric Literature of C3H9IOS

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《A new tricrystalline triblock terpolymer by combining polyhomologation and ring-opening polymerization. synthesis and thermal properties》 was written by Ladelta, Viko; Zapsas, George; Gnanou, Yves; Hadjichristidis, Nikos. Synthetic Route of C3H9IOSThis research focused ontricryst triblock terpolymer polyhomologation ring opening polymerization property. The article conveys some information:

New tricryst. triblock terpolymers, polyethylene-block-poly(ε-caprolactone)-block-poly(L-lactide) (PE-b-PCL-b-PLLA), were synthesized by ROP of ε-caprolactone (CL) and L-lactide (LLA) from linear ω-hydroxyl polyethylene (PE-OH) macroinitiators. The linear PE-OH macroinitiators were prepared by C1 polymerization of Me sulfoxonium methylide (polyhomologation). Tin(II) 2-ethylhexanoate was used as the catalyst for the sequential ROP of CL and LLA in one-pot polymerization at 85 °C in toluene (PE-OH macroinitiators are soluble in toluene at 80 °C). 1H NMR spectra confirmed the formation of PE-b-PCL-b-PLLA triblock terpolymers through the appearance of the characteristic proton peaks of each block. GPC traces showed the increase in the number average mol. weight from PE-OH macroinitiator to PE-b-PCL, and PE-b-PCL-b-PLLA corroborating the successful synthesis. The existence of three crystalline blocks was proved by DSC and XRD spectroscopy. The results came from multiple reactions, including the reaction of Trimethylsulfoxonium iodide(cas: 1774-47-6Synthetic Route of C3H9IOS)

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides.Synthetic Route of C3H9IOS

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Iridium-catalyzed B-H insertion of sulfoxonium ylides and borane adducts: a versatile platform to α-boryl carbonyls》 was written by Zhang, Shang-Shi; Xie, Hui; Shu, Bing; Che, Tong; Wang, Xiao-Tong; Peng, Dongming; Yang, Fan; Zhang, Luyong. Category: iodides-buliding-blocks And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020. The article conveys some information:

Ir-catalyzed B-H bond insertion reactions of trimethylamine-borane and sulfoxonium ylides were demonstrated, furnishing α-boryl ketones in moderate to excellent yields in most cases (51 examples; up to 84%). This practical and scalable insertion reaction showed broad substrate scope, high functional-group compatibility and could be applied in late-stage modification of structurally complex drug compounds Further synthetic applications were also demonstrated. In the experimental materials used by the author, we found Trimethylsulfoxonium iodide(cas: 1774-47-6Category: iodides-buliding-blocks)

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Formula: C3H9IOSIn 2019 ,《Controlled synthesis of polymethylene-b-poly(ethylene glycol) as well as its crystallization and self-assembly behavior》 appeared in International Journal of Polymer Analysis and Characterization. The author of the article were Zhang, Yan; Zhou, Qihang; Liu, Yujian. The article conveys some information:

Polymethylene-b-poly(ethylene glycol) (PM-b-PEG) with different block length ratio was synthesized by a combination of polyhomologation and coupling reaction. The effect of hydrophilic and hydrophobic block length on the crystallization process and self-assembly behavior of PM-b-PEG was self-assembled were investigated. The results showed that with the increase of methylene units, the crystallization temperature of PM block raised from 54.59 °C to 70.93 °C gradually, while that of the PEG block reduced from 17.54 °C to 15.23 °C. In addition, the amphiphilic PM-b-PEG was self-assembled into star-like micelles in water, and its diameter extended from 98.2 nm to 151.9 nm as the block length of hydrophobic PM increased from 30 to 70. And the micelles also exhibit super stability when the concentration of copolymer precursor is 0.50 ∼ 0.90 mg/mL and the storage temperature lies in the range of 25 ∼ 60 °C. In the part of experimental materials, we found many familiar compounds, such as Trimethylsulfoxonium iodide(cas: 1774-47-6Formula: C3H9IOS)

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.Formula: C3H9IOS

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Imidazolone-activated donor-acceptor cyclopropanes with a peripheral stereocenter. A study on stereoselectivity of cycloaddition with aldehydes》 was published in Chemistry of Heterocyclic Compounds (New York, NY, United States) in 2020. These research results belong to Mikhaylov, Andrey A.; Solyev, Pavel N.; Kuleshov, Andrei V.; Kublitskii, Vadim S.; Korlyukov, Aleksander A.; Lushpa, Vladislav A.; Baranov, Mikhail S.. Recommanded Product: 1774-47-6 The article mentions the following:

Nucleophilic cyclopropanation of arylideneimidazolones possessed a peripheral chiral center and the subsequent fractional crystallization of diastereomers allowed access to the compounds with an enantiomerically uniform configuration of the spirocyclic donoracceptor cyclopropane fragment. The mechanism of the cycloaddition reaction with aldehydes; it was demonstrated that stereochem. information from the cyclopropane fragment was lost during the reaction. In addition to this study using Trimethylsulfoxonium iodide, there are many other studies that have used Trimethylsulfoxonium iodide(cas: 1774-47-6Recommanded Product: 1774-47-6) was used in this study.

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides.Recommanded Product: 1774-47-6

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The author of 《Synthesis of 2,3-diaryl-2,3,4,4a-tetrahydro-5H-indeno[1,2-c]pyridazin-5-ones》 were Chagarovskiy, Alexey O.; Strel’tsova, Elena D.; Rybakov, Victor B.; Levina, Irina I.; Trushkov, Igor V.. And the article was published in Chemistry of Heterocyclic Compounds (New York, NY, United States) in 2019. Name: Trimethylsulfoxonium iodide The author mentioned the following in the article:

The nucleophilic cleavage of spiro[cyclopropane-1,2′-indane]-1′,3′-diones with phenylhydrazine in the presence of catalytic amounts of scandium triflate led to the formation of indeno[1,2-c]pyridazine derivatives I [R = Ph, 4-MeC6H4, 4-FC6H4, etc.]. The experimental process involved the reaction of Trimethylsulfoxonium iodide(cas: 1774-47-6Name: Trimethylsulfoxonium iodide)

Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.Name: Trimethylsulfoxonium iodide

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com