Category: 15164-44-0

In 2019,Journal of Organic Chemistry included an article by Hu, Weiming; Teng, Fan; Hu, Huaanzi; Luo, Shuang; Zhu, Qiang. Safety of 4-Iodobenzaldehyde. The article was titled 《Pd-Catalyzed C(sp2)-H Imidoylative Annulation: A General Approach To Construct Dibenzoox(di)azepines》. The information in the text is summarized as follows:

In the presence of Pd(OAc)2 and PPh3, aryloxy- and arylaminoaryl isocyanides with ortho-substituents such as I (X = O, NMe) underwent cyclization reactions with aryl iodides such as iodobenzene to yield benzoxazines and benzodiazepines such as II (X = O, NMe) via isocyanide insertion and C-H activation reactions. This is the first example of seven-membered heterocycle formation by C-H imidoylative annulation. In addition to this study using 4-Iodobenzaldehyde, there are many other studies that have used 4-Iodobenzaldehyde(cas: 15164-44-0Safety of 4-Iodobenzaldehyde) was used in this study.

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Safety of 4-Iodobenzaldehyde

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Category: iodides-buliding-blocksIn 2019 ,《A Convenient Synthesis of Sulfones via Light Promoted Coupling of Sodium Sulfinates and Aryl Halides》 was published in Advanced Synthesis & Catalysis. The article was written by Chen, Lei; Liang, Jie; Chen, Zhen-yu; Chen, Jie; Yan, Ming; Zhang, Xue-jing. The article contains the following contents:

A convenient and efficient synthesis of sulfones RS(O)2R1 (R = Me, cyclopropyl, 4-methoxyphenyl, pyridin-3-yl, etc.; R1 = 4-cyanophenyl, pyridin-3-yl, pyrimidin-5-yl, etc.) from sulfinates RS(O)2Na and aryl halides R1X (X = Br, I, Cl) was developed. The reaction occurred under UV irradiation without transition metal catalyst or photocatalyst. A radical pathway via single-electron transfer (SET) of electron donor-acceptor (EDA) complex was proposed based on UV-vis spectroscopy, radical inhibiting and trapping experiments The experimental part of the paper was very detailed, including the reaction process of 4-Iodobenzaldehyde(cas: 15164-44-0Category: iodides-buliding-blocks)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Stimuli-Responsive Polycycles Based on Hetero-Buckybowl Trithiasumanene》 was written by Wang, Wenbo; Feng, Lijun; Hua, Xinqiang; Yuan, Chengshan; Shao, Xiangfeng. Recommanded Product: 15164-44-0This research focused ontrithiasumanene dioxide preparation photophys property sulfide ion detection; oxazolo fused trithiasumanene preparation oxidation photophys property; quinone trithiasumanene three component Dubus Radziszewski reaction aldehyde. The article conveys some information:

Herein, a series of hetero polycycles which show optical response toward chem. stimuli were synthesized from trithiasumanene (I, TTS). TTS is transformed into the ortho-quinone form II, which then undergoes three-component Debus-Radziszewski reaction with aldehydes RCHO (R = H, C6H5, 4-CH3C6H4, 4-IC6H4, Q) and ammonia to give oxazole-fused TTS III. The thiophene rings on III (R = C6H5, 4-CH3C6H4, 4-IC6H4) are selectively oxidized to thiophene-S,S-dioxides, affording IV. It was found that the electronic structures of these compounds III and IV are governed by the substituents on the oxazole moiety and oxidation state of the thiophene ring. Moreover, these hetero-polycycles exhibit optical responses toward different chem. stimuli. Particularly, compounds III (R = Q) and IV (R = C6H5) can serve as fluorescence detectors for harmful chem. sulfide ions (S2-/HS-) and aniline, resp. This work indicates that TTS is a promising precursor for the creation of responsive materials. In the part of experimental materials, we found many familiar compounds, such as 4-Iodobenzaldehyde(cas: 15164-44-0Recommanded Product: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Recommanded Product: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes》 was written by Lozano-Lavilla, Olmo; Gomez-Orellana, Pablo; Lledos, Agusti; Casares, Juan A.. COA of Formula: C7H5IOThis research focused ontransmetalation reaction triggered electron transfer organocopper complex. The article conveys some information:

[Cu(bipy)(C6F5)] reacts with most aryl iodides to form heterobiphenyls by cross-coupling, but when Rf-I is used (Rf = 3,5-dicholoro-2,4,6-trifluorophenyl), homocoupling products are also formed. Kinetic studies suggest that, for the homocoupling reaction, a mechanism based on transmetalation from [Cu(bipy)(C6F5)] to Cu(III) intermediates formed in the oxidative addition step is at work. D. functional theory calculations show that the interaction between these Cu(III) species and the starting Cu(I) complex involves a Cu(I)-Cu(III) electron transfer concerted with the formation of an iodine bridge between the metals and that a fast transmetalation takes place in a dimer in a triplet state between two Cu(II) units. In addition to this study using 4-Iodobenzaldehyde, there are many other studies that have used 4-Iodobenzaldehyde(cas: 15164-44-0COA of Formula: C7H5IO) was used in this study.

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.COA of Formula: C7H5IO

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,ChemistrySelect included an article by Ghasemzadeh, Maryam Sadat; Akhlaghinia, Batool. HPLC of Formula: 15164-44-0. The article was titled 《FMMWCNTs@CPA@SMTU@PdII NPs: As a Versatile Ferromagnetic Nanostructured Catalyst for Sonogashira-Hagihara Cross-Coupling Reaction in Solvent-Free Conditions》. The information in the text is summarized as follows:

This study deals with the designing and preparation of PdII immobilized on ferromagnetic multi-walled carbon nanotubes functionalized by aminated 2-chloroethylphosphonic acid with S-methylisothiourea (FMMWCNTs@CPA@SMTU@PdII NPs) as a versatile ferromagnetic nanostructured catalyst. The results show that FMMWCNTs@CPA@SMTU@PdII NPs with decorated MWCNTs by Fe3O4 NPs exhibited ferromagnetic properties with a uniform rod-like morphol. and particle sizes of about 20-30 nm. The catalytic performance of FMMWCNTs@CPA@SMTU@PdII NPs was evaluated in Sonogashira-Hagihara cross-coupling reaction at room temperature and in solvent-free conditions. Under appropriate condition, all reactions proceeded at a faster initial rate while exhibiting excellent activity and selectivity and the desired products were obtained in relatively excellent yields. In the experimental materials used by the author, we found 4-Iodobenzaldehyde(cas: 15164-44-0HPLC of Formula: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.HPLC of Formula: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Yang, Liming; Xie, Henan; An, Guanghui; Li, Guangming published their research in Journal of Organic Chemistry in 2021. The article was titled 《Acid-Enabled Palladium-Catalyzed β-C(sp3)-H Functionalization of Weinreb Amides》.Recommanded Product: 15164-44-0 The article contains the following contents:

Herein, Pd(II)-catalyzed C(sp3)-H arylation and alkenylation of Weinreb amides was reported. A com. available, inexpensive sulfonic acid was employed to enhance the coordination of the catalyst with weak-coordinating substrates by increasing the electrophilicity of in situ formed palladium catalysts. The results came from multiple reactions, including the reaction of 4-Iodobenzaldehyde(cas: 15164-44-0Recommanded Product: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Recommanded Product: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Electric Literature of C7H5IOIn 2020 ,《Indium-mediated difunctionalization of iodoalkyl-tethered unactivated alkenes via an intramolecular cyclization and an ensuing palladium-catalyzed cross-coupling reaction with aryl halides》 was published in Organic Chemistry Frontiers. The article was written by Song, Xuan-Di; Li, Xiang-Rui; Wang, Ya-Wen; Chu, Xue-Qiang; Rao, Weidong; Xu, Haiyan; Han, Guo-Zhi; Shen, Zhi-Liang. The article contains the following contents:

An efficient cobalt-catalyzed, indium-mediated difunctionalization of iodoalkyl-tethered unactivated alkenes via a cyclization/cross-coupling sequence was developed. The reactions proceeded effectively with wide functional group tolerance, leading to a wide variety of cyclic compounds, including cyclopentane, furan, pyrrolidine, octahydro-1H-indene, octahydro-benzofuran, hexahydro-4H-furo[2,3-b]pyran, and hexahydro-furo[2,3-b]furan, which are pivotal cores widely found in pharmaceutical and bioactive compounds4-Iodobenzaldehyde(cas: 15164-44-0Electric Literature of C7H5IO) was used in this study.

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Electric Literature of C7H5IO

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Journal of Organic Chemistry included an article by Zhi, Man-Ling; Chen, Bing-Zhi; Deng, Wei; Chu, Xue-Qiang; Loh, Teck-Peng; Shen, Zhi-Liang. Reference of 4-Iodobenzaldehyde. The article was titled 《Preparation of Alkyl Indium Reagents by Iodine-Catalyzed Direct Indium Insertion and Their Applications in Cross-Coupling Reactions》. The information in the text is summarized as follows:

Alkylindium reagents were generated in situ by direct metalation of primary alkyl iodides and bromides and cyclohexyl iodide with indium metal in the presence of iodine in THF (for alkyl iodides) or N,N-dimethylacetamide (for alkyl bromides). Palladium-catalyzed coupling of the alkylindium reagents with aryl iodides and selected aryl bromides and chlorides yielded arenes. In the experiment, the researchers used 4-Iodobenzaldehyde(cas: 15164-44-0Reference of 4-Iodobenzaldehyde)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Reference of 4-Iodobenzaldehyde

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2019,Materials Research Express included an article by Behrouzi, Leila; Bagheri, Robabeh; Song, Zhenlun; Kazemi, Foad; Kaboudin, Babak; Najafpour, Mohammad Mahdi. COA of Formula: C7H5IO. The article was titled 《Oxidation of alkylarenes by modified graphite》. The information in the text is summarized as follows:

Herein, an electrochem. method had introduced and developed for the selective benzylic oxidation of alkylarenes. This work utilized a simple redox mediator system, N-hydroxyphthalimide (NHPI), with an inexpensive and innovatory modified graphite and nickel-based electrode using undivided cell setups to the selective oxidation of alkylarenes toward the aldehyde and ketone production Since, the selective oxidation of alkylarenes toward aldehyde formation (in the aerobic conditions) was a prominent challenge, our method for alkylarenes oxidation with high yield and selectivity in the presence of oxygen under mild and metal free conditions was promising. In the experiment, the researchers used many compounds, for example, 4-Iodobenzaldehyde(cas: 15164-44-0COA of Formula: C7H5IO)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.COA of Formula: C7H5IO

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The author of 《Metallic salt-catalyzed direct indium insertion into alkyl iodides and their applications in cross-coupling reactions》 were Chen, Bing-Zhi; Wang, Chuang-Xin; Jing, Zhen-Hua; Chu, Xue-Qiang; Loh, Teck-Peng; Shen, Zhi-Liang. And the article was published in Organic Chemistry Frontiers in 2019. Name: 4-Iodobenzaldehyde The author mentioned the following in the article:

An efficient method for the synthesis of alkyl indium reagents by an indium(III) or lead(II) halide-catalyzed direct insertion of indium into alkyl iodides and their applications in palladium-catalyzed cross-coupling reactions with aryl halides is developed. NMR and ESI-MS analyses indicated that rather than the formation of the commonly recognized alkyl indium sesquihalide with the formulation of R3In2X3, the formed alkyl indium reagent in the present protocol should be a mixture of an alkyl indium dihalide (RInX2) and a dialkyl indium halide (R2InX) (both of them presumably exist as dimers). The results came from multiple reactions, including the reaction of 4-Iodobenzaldehyde(cas: 15164-44-0Name: 4-Iodobenzaldehyde)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Name: 4-Iodobenzaldehyde

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com