Category: 15164-44-0

In 2019,Chem included an article by Liu, Wei; Zhao, Liang-Liang; Melaimi, Mohand; Cao, Lei; Xu, Xingyu; Bouffard, Jean; Bertrand, Guy; Yan, Xiaoyu. Related Products of 15164-44-0. The article was titled 《Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups》. The information in the text is summarized as follows:

Investigation of the reaction of aldehydes with 1,2,3-triazolylidenes has revealed the reversible formation of Breslow intermediates and the inhibition of the condensation steps in methanol solvent. 1,2,3-Triazolylidenes catalyzed the H/D exchange of aryl, alkenyl and alkyl aldehydes in high yields and deuterium incorporation levels using deuterated methanol as an affordable D source. The unique properties of these mesoionic carbenes (MICs) enabled a streamlined preparation of deuterated synthetic intermediates and pharmacophores that are highly valuable as mechanistic and metabolic probes. In addition to this study using 4-Iodobenzaldehyde, there are many other studies that have used 4-Iodobenzaldehyde(cas: 15164-44-0Related Products of 15164-44-0) was used in this study.

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Related Products of 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In 2022,Wang, Wei; Yao, Ken; Wu, Fan published an article in Synlett. The title of the article was 《Nickel-Catalyzed Reductive Cross-Coupling of Benzylic Sulfonium Salts with Aryl Iodides》.Related Products of 15164-44-0 The author mentioned the following in the article:

A nickel-catalyzed cross-electrophile coupling of benzylic sulfonium salts R1CH(S+(CH3)2)R2·O-S(O)CF3 [R1 = Ph, naphthalen-2-yl, benzo[d][1,3]dioxol-5-yl, etc.; R2 = H, Me, Et] with aryl iodides R3I [R3 = 4-carboxymethylphenyl, 9H-fluoren-2-yl, 4-formylphenyl, etc.] has been developed, providing direct access to diarylalkanes R1CH(R2)R3 from readily available and stable coupling partners. Preliminary mechanistic studies suggest that the C-S bond cleavage proceeds through a single-electron transfer process to generate a benzylic radical. After reading the article, we found that the author used 4-Iodobenzaldehyde(cas: 15164-44-0Related Products of 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Related Products of 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《3-(4-Iodophenyl)-2,3-dihydro-1H-benzo[f]chromen-1-one》 was written by Dean, Raven; Miller, Chelsea N.; Zingales, Sarah K.; Padgett, Clifford W.. Formula: C7H5IO And the article was included in IUCrData in 2020. The article conveys some information:

In the title compound, C19H13IO2, the dihedral angle between the naphthyl ring system and the pendant iodophenyl ring is 72.48 (11)°. In the crystal, C-H···π interactions and I···O [3.293 (2) Å] halogen bonds are observed, which combine to generate a herringbone packing motif. In the experiment, the researchers used many compounds, for example, 4-Iodobenzaldehyde(cas: 15164-44-0Formula: C7H5IO)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Formula: C7H5IO

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Shan, Zi-Wei; Chen, Xiao-Yan; Zhang, Hao; Liu, Hai-Yang; Yuan, Gao-Qing published an article in 2022. The article was titled 《Copper Porphyrin Catalyzed C(sp3)-H Activation via Cross-Dehydrogenative Coupling: Facile Transformation of Aldehydes to Esters》, and you may find the article in Synlett.Recommanded Product: 15164-44-0 The information in the text is summarized as follows:

Copper porphyrin catalyzed alkane C-H bond functionalization with aldehydes via cross-dehydrogenative coupling (CDC) using DTBP oxidant has been firstly described in nonsolvents or nonadditives system. Different aryl/heteroaryl carboxylic esters were obtained in good to excellent yields depending on the aldehyde derivatives This CDC reaction catalyzed by copper porphyrin has the advantages of shorter reaction time, lower reaction temperature, and catalyst loading as well as the aerobic reaction atm. In the part of experimental materials, we found many familiar compounds, such as 4-Iodobenzaldehyde(cas: 15164-44-0Recommanded Product: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Recommanded Product: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The author of 《3-(4-Iodophenyl)pentanedinitrile》 were Nanpo, Yuuki; Okuno, Tsunehisa. And the article was published in IUCrData in 2019. Application In Synthesis of 4-Iodobenzaldehyde The author mentioned the following in the article:

In the title pentanedinitrile derivative, C11H9IN2, the iodophenyl group is connected at the 3-position. The central propylene chain of the pentanedinitrile moiety contains one gauche conformation as a result of steric repulsion with the Ph ring. Intermol. close contacts in the crystal comprise a weak Csp3-H···N hydrogen bond and a C-I···N halogen bond. The experimental part of the paper was very detailed, including the reaction process of 4-Iodobenzaldehyde(cas: 15164-44-0Application In Synthesis of 4-Iodobenzaldehyde)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Application In Synthesis of 4-Iodobenzaldehyde

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Li, Jun; Yang, Yi; Liu, Yunxia; Liu, Qing; Zhang, Lizhi; Li, Xinjin; Dong, Yunhui; Liu, Hui published an article in 2021. The article was titled 《Palladium/Norbornene Catalyzed ortho Amination/Cyclization of Aryl Iodide: Process to 3-Methyl-indole Derivates and Controllable Reductive Elimination against the Second Amination》, and you may find the article in Organic Letters.Category: iodides-buliding-blocks The information in the text is summarized as follows:

A palladium/norbornene cooperative catalyzed selective C-H bond amination of aryl iodides was explored, providing an efficient tool for constructing benzocyclic mols. When ortho-substituted iodobenzene was involved, the C-H bond amination and following Heck cyclization efficiently delivered a 3-methyl-indole scaffold. On the other hand, we realized the controllable synthesis of monoaminated benzo-cyclobutanyl scaffold. The possible coordination of an installed terminal alkenyl group with palladium and steric hindrance were proposed to be responsible for the monoamination selectivity. In the experiment, the researchers used 4-Iodobenzaldehyde(cas: 15164-44-0Category: iodides-buliding-blocks)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Wang, Jian; Li, Lianjie; Chai, Minxue; Ding, Shumin; Li, Jing; Shang, Yongjia; Zhao, Haixia; Li, Dan; Zhu, Qiang published an article in 2021. The article was titled 《Enantioselective Construction of 1H-Isoindoles Containing Tri- and Difluoromethylated Quaternary Stereogenic Centers via Palladium-Catalyzed C-H Bond Imidoylation》, and you may find the article in ACS Catalysis.Reference of 4-Iodobenzaldehyde The information in the text is summarized as follows:

An intermol. enantioselective synthesis of 1H-isoindoles containing tri- and difluoromethylated quaternary stereogenic centers through a palladium-catalyzed desym. C-H bond imidoylation has been developed. α,α-Diaryl tri- and difluoroethylated isocyanides acted as powerful precursors of chiral 1H-isoindoles, in which the fluoroalkyl group was proven to play a crucial role in both the stereochem. and reaction efficiency. In addition, an allene insertion cascade was realized, offering rapid access to diverse C1-tethered bis-heterocyclic scaffolds with good yields and high enantioselectivities. The reactions proceeded smoothly under mild conditions with low catalyst loadings. The results came from multiple reactions, including the reaction of 4-Iodobenzaldehyde(cas: 15164-44-0Reference of 4-Iodobenzaldehyde)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Reference of 4-Iodobenzaldehyde

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

《Regioselective Three-Component Synthesis of Vicinal Diamines via 1,2-Diamination of Styrenes》 was written by Cao, Jie; Lv, Daqi; Yu, Fei; Chiou, Mong-Feng; Li, Yajun; Bao, Hongli. HPLC of Formula: 15164-44-0This research focused onvicinal diamine preparation regioselective; styrene diamination azodicarboxylate. The article conveys some information:

Herein, a regioselective intermol. three-component vicinal diamination of styrenes with acetonitrile and azodicarboxylates is reported. The diamination products can be produced in moderate to excellent yields via the Ritter reaction. Synthetic applications and theor. studies of this reaction have been conducted. After reading the article, we found that the author used 4-Iodobenzaldehyde(cas: 15164-44-0HPLC of Formula: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.HPLC of Formula: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Cheng, Sidi; Luo, Yu; Yu, Ting; Li, Jing; Gan, Chunfang; Luo, Shuang; Zhu, Qiang published an article in 2022. The article was titled 《Palladium-Catalyzed Four-Component Cascade Imidoyl-Carbamoylation of Unactivated Alkenes》, and you may find the article in ACS Catalysis.HPLC of Formula: 15164-44-0 The information in the text is summarized as follows:

A 1,2-difunctionalization of an unactivated alkene, imidoyl-carbamoylation were developed through a palladium-catalyzed four-component cascade reaction involving aryl iodide, alkenyl isocyanide, CO and amine. Continuous migratory insertion of three different functionalities to the Pd(II) intermediate generated from the previous step took place in a well-defined sequence. Four chem. bonds, including three C-C bonds and one C-N bond, were formed in this cascade process, leading to a convenient and convergent access to acetamides substituted with five- to seven-membered cyclic ketoimines. In addition, an extra C-N bond was formed through in-situ or postreaction cyclization of the amido NH to the ketoimine moiety, providing a facile one-pot access to pyrrolo-fused heterocycles. The experimental part of the paper was very detailed, including the reaction process of 4-Iodobenzaldehyde(cas: 15164-44-0HPLC of Formula: 15164-44-0)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.HPLC of Formula: 15164-44-0

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Luo, Xin-Long; Ge, Danhua; Yu, Zi-Lun; Chu, Xue-Qiang; Xu, Pei published an article in 2021. The article was titled 《Vitamin B1-catalyzed aerobic oxidative esterification of aromatic aldehydes with alcohols》, and you may find the article in RSC Advances.Category: iodides-buliding-blocks The information in the text is summarized as follows:

A straightforward aerobic oxidative esterification of aryl aldehydes RCHO (R = 3-nitrophenyl, 3-fluoro-4-nitrophenyl, 4-iodophenyl, etc.) with alcs. R1OH (R1 = Me, benzyl, pyridin-2-ylmethyl, etc.) has been developed for the synthesis of substituted esters RC(O)OR1 by employing vitamin B1 as a cost-effective, metal-free, and eco-friendly NHC catalyst. Air is used as a green terminal oxidant. The reaction is a useful addition to the existing NHC-catalytic oxidative esterification. After reading the article, we found that the author used 4-Iodobenzaldehyde(cas: 15164-44-0Category: iodides-buliding-blocks)

4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com