Category: 144970-30-9

Wang, Xu; Lu, Sheng-mei; Li, Jun; Liu, Yan; Li, Can published an article in 2015, the title of the article was Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation.Category: iodides-buliding-blocks And the article contains the following content:

A series of chiral conjugated microporous polymers (CMPs) based on the chiral (R)-BINAP ligand (BINAP-CMPs) were synthesized with tunable BET surface areas. These solid catalysts show high activities and enantioselectivities for the asym. hydrogenation of 尾-keto esters after coordination with ruthenium species. Moreover, CMPs can realize spatial isolation. Through preventing the formation of dimers and trimers, BINAP-CMPs show much higher activity than BINAP for the Ir-catalyzed asym. hydrogenation of quinaldine. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Category: iodides-buliding-blocks

The Article related to cmp ruthenium binap catalyst asym hydrogenation ketoester sem tga, Physical Organic Chemistry: Stereochemistry and Stereochemical Relationships, Including Conformational Inversions and Rotational Isomerization and other aspects.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On November 30, 2006, Dohi, Toshifumi; Morimoto, Koji; Takenaga, Naoko; Maruyama, Akinobu; Kita, Yasuyuki published an article.Application of 144970-30-9 The title of the article was A facile and clean direct cyanation of heteroaromatic compounds using a recyclable hypervalent iodine(III) reagent. And the article contained the following:

The facile and clean direct cyanating reaction of pyrroles and thiophenes was achieved using a recyclable hypervalent iodine(III) reagent by a simple solid-liquid separation of the products and the reagent. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application of 144970-30-9

The Article related to pyrrole cyanation silyl cyanide recyclable hypervalent iodine reagent, thiophene cyanation silyl cyanide recyclable hypervalent iodine reagent, cyano heteroaromatic compound pyrrole thiophene preparation and other aspects.Application of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On November 21, 2009, Plietzsch, Oliver; Schilling, Christine Inge; Tolev, Mariyan; Nieger, Martin; Richert, Clemens; Muller, Thierry; Brase, Stefan published an article.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Four-fold click reactions: Generation of tetrahedral methane- and adamantane-based building blocks for higher-order molecular assemblies. And the article contained the following:

A modular concept for the generation of achiral and chiral non-racemic tetrahedral tectons from common precursors was developed. The tectons presented here are based on tetraphenylmethane or 1,3,5,7-tetraphenyladamantane core structures. They are obtained through high-yielding four-fold click reactions, using either the tetraazido or the tetraalkyne precursors. In most cases, the tetratriazoles are obtained as pure products after simple washing with water and methanol. The side chains of the tectons prepared include a self-complementary DNA dimer, obtained from a 3′-azidonucleoside and a phosphoramidite. The concept allows for a variation of the “sticky ends”, leading to tecton or ligand libraries. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to tetrahedral methane adamantane tecton triazole preparation, amine azidation azide alkyne click chem, dipolar cycloaddition copper catalyst, dna dimer dinucleotide preparation azidonucleoside phosphoramidite and other aspects.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Boldog, Ishtvan; Domasevitch, Konstantin V.; Baburin, Igor A.; Ott, Holger; Gil-Hernandez, Beatriz; Sanchiz, Joaquin; Janiak, Christoph published an article in 2013, the title of the article was A rare alb-4,8-Cmce metal-coordination network based on tetrazolate and phosphonate functionalized 1,3,5,7-tetraphenyladamantane.Recommanded Product: 144970-30-9 And the article contains the following content:

Sym. tetrahedral ligands are prominent, but somewhat under-studied building blocks for the generation of coordination polymeric networks. Coordination networks [Mn5Cl2(L1)2(H2O)4(DMF)4]·3H2O·7DMF, 1 and the [La2(H5L2)2(H2O)6], 2 were synthesized under mild solvothermal methods in DMF from the adamantane-based tetrahedral ligands, 1,3,5,7-tetrakis(4-phenyltetrazol-5-yl)adamantane (H4L1), reported for the first time, and 1,3,5,7-tetrakis(4-phenylphosphonic acid)adamantane (H8L2), resp. Compounds 1 and 2 are based on completely different pentanuclear and binuclear secondary metal building units, resp., and have different symmetries, but demonstrate an interesting coincidence of underlying topologies, which could be interpreted as a directing or imprinting’ effect of the symmetry of the rigid tetrahedral ligands. Both structures represent examples of a rarely observed (4,8)-coordinated net. The χMT product for 1 at room temperature is slightly lower than the expected for five Mn(II) ions with S = 5/2 and g ≈ 1.98 and on lowering the temperature χMT approaches the expected value for a single Mn(II) as a result of the antiferromagnetic coupling through the tetrazolate bridges. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Recommanded Product: 144970-30-9

The Article related to manganese lanthanum tetrazolate phosphonate tetraphenyladamantane complex preparation crystal structure, magnetic property manganese lanthanum tetrazolate phosphonate functionalized tetraphenyladamantane complex and other aspects.Recommanded Product: 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On October 17, 2002, Li, Quan; Rukavishnikov, Aleksey V.; Petukhov, Pavel A.; Zaikova, Tatiana O.; Keana, John F. W. published an article.Category: iodides-buliding-blocks The title of the article was Nanoscale 1,3,5,7-Tetrasubstituted Adamantanes and p-Substituted Tetraphenyl-methanes for AFM Applications. And the article contained the following:

Tetrahedrally shaped mols.such as I based on tetrasubstituted methane or tetrasubstituted adamantane cores are prepared as potential precursors for single-mol. AFM tips. 1,3,5,7-Tetra(4-iodophenyl)adamantane is prepared in two steps from 1-bromoadamantane and benzene by heating with tert-Bu bromide and aluminum chloride followed by electrophilic iodination; the corresponding tetra(4-iodophenyl)methane is prepared from 4-tritylaniline by diazotization and substitution with iodide followed by electrophilic iodination. N-alkynylaryldithiazepane building blocks are prepared from 4-iodoaniline by addition of ethylene oxide, chlorination of the 2-hydroxyethylamino substituents, conversion via the bisthiocyanate to the dithiazepane, Sonogashira coupling reaction of the aryl iodide moiety with trimethylsilylacetylene and desilylation, coupling with 4-iodophenylethynyltrimethylsilane, and desilylation to provide the arms of I in seven steps. Sonogashira coupling of tetra(4-iodophenyl)methane with the arm unit yields I. AFM images of I indicate that I can be imaged with a conventional AFM tip. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Category: iodides-buliding-blocks

The Article related to tetrahedral arylalkyne preparation single mol afm probe tip, iodophenylmethane iodophenyladamantane preparation, sonogashira coupling reaction alkynylarylazadithiepine, afm imaging azathiepinylethynylphenylethynylphenylmethane and other aspects.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On September 13, 2004, Wei, Qian; Galoppini, Elena published an article.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Tripodal Ru(II) complexes with conjugated and non-conjugated rigid-rod bridges for semiconductor nanoparticles sensitization. And the article contained the following:

Three tripodal Ru(II)-polypyridyl complexes were synthesized as models to study long-range electron transfer in TiO2 semiconductor nanoparticle thin films, in particular to study the effect of the conjugation of the bridge containing the Ru complex and for distance-dependence studies. The tripodal sensitizers, which are 1,3,5,7-tetraphenyladamantane derivatives having three COOMe anchoring groups and one rigid-rod bridge substituted with a Ru(II) complex, are the longest prepared to date (Ru-to-footprint distance ∼24 Å). Two have a rigid-rod bridge made of two p-ethynylphenylene units (Ph-E)2 capped with a 4-(2,2′-bipyridyl) (bpy) ligand or a 5-(1,10-phenanthrolinyl) (phen) ligand for the Ru complex. The third tripod, which contains a bpy ligand for the Ru complex, has one bicyclo[2.2.2]octylene (Bco) unit in place of a p-phenylene (Ph) unit and is the first example of a tripodal sensitizer with a nonconjugated bridge. Solution absorption and fluorescence data of the three complexes are reported. Photophys. studies of the non-conjugated Bco-bridged complex on TiO2 are not reported. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to ruthenium tripodal sensitizer conjugated nonconjugated bridge preparation fluorescence, conjugation effect ruthenium tripodal sensitizer rigid rod bridge, photophys ruthenium tripodal sensitizer conjugated nonconjugated bridge and other aspects.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On September 30, 2019, Chhanda, Sadia Afrin; Itsuno, Shinichi published an article.Computed Properties of 144970-30-9 The title of the article was Design and synthesis of chiral hyperbranched polymers containing cinchona squaramide moieties and their catalytic activity in the asymmetric Michael addition reaction. And the article contained the following:

Chiral hyperbranched polymers (HBP) containing cinchona alkaloids were synthesized using a Mizoroki-Heck (MH) coupling polymerization reaction between a cinchona squaramide dimer and tri- or tetra-substituted aromatic iodides. This was a new type of polymeric chiral organocatalyst. We found that the as-obtained chiral HBPs show excellent catalytic activity in the asym. Michael reaction. Almost perfect enantioselectivity (>99% ee) was achieved in the reaction of β-ketoester and trans-β-nitrostyrene. The three-dimensional network structure of the chiral HBPs is structurally robust and can be reused for further reaction without any loss in their catalytic activity. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Computed Properties of 144970-30-9

The Article related to cinchona squaramide iodoarene copolymer preparation recyclability, keto ester nitro vinylarene chiral polymer organocatalyst michael addition, alkyl aryl nitroalkyl oxo cyclopentanecarboxylate diastereoselective enantioselective preparation and other aspects.Computed Properties of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Boldog, Ishtvan; Domasevitch, Konstantin; MacLaren, Jana K.; Heering, Christian; Makhloufi, Gamall; Janiak, Christoph published an article in 2014, the title of the article was A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane And the article contains the following content:

Three porous coordination polymers with a simplified formula of [M4(μ4-Cl)L2]·nGuest (M = Cu, Cd) based on two adamantane-derived tetrahedral tetrazolate ligands, 1,3,5,7-tetrakis(tetrazol-5-yl)adamantane and 1,3,5,7-tetrakis(tetrazol-5-ylphenyl)adamantane, were synthesized. Along with one known representative (with tetrakis(tetrazol-5-ylphenyl)methane), the compounds establish a new isoreticular series with fluorite as the underlying net. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to isoreticular adamantane based tetrahedral tetrazolate copper cadmium mof preparation, crystal structure isoreticular adamantane based tetrazolate copper cadmium mof, gas adsorption adamantane based tetrahedral tetrazolate copper cadmium mof and other aspects.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On November 21, 2009, Plietzsch, Oliver; Schilling, Christine Inge; Tolev, Mariyan; Nieger, Martin; Richert, Clemens; Muller, Thierry; Brase, Stefan published an article.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Four-fold click reactions: Generation of tetrahedral methane- and adamantane-based building blocks for higher-order molecular assemblies. And the article contained the following:

A modular concept for the generation of achiral and chiral non-racemic tetrahedral tectons from common precursors was developed. The tectons presented here are based on tetraphenylmethane or 1,3,5,7-tetraphenyladamantane core structures. They are obtained through high-yielding four-fold click reactions, using either the tetraazido or the tetraalkyne precursors. In most cases, the tetratriazoles are obtained as pure products after simple washing with water and methanol. The side chains of the tectons prepared include a self-complementary DNA dimer, obtained from a 3′-azidonucleoside and a phosphoramidite. The concept allows for a variation of the “sticky ends”, leading to tecton or ligand libraries. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to tetrahedral methane adamantane tecton triazole preparation, amine azidation azide alkyne click chem, dipolar cycloaddition copper catalyst, dna dimer dinucleotide preparation azidonucleoside phosphoramidite and other aspects.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Boldog, Ishtvan; Domasevitch, Konstantin; MacLaren, Jana K.; Heering, Christian; Makhloufi, Gamall; Janiak, Christoph published an article in 2014, the title of the article was A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane And the article contains the following content:

Three porous coordination polymers with a simplified formula of [M4(μ4-Cl)L2]·nGuest (M = Cu, Cd) based on two adamantane-derived tetrahedral tetrazolate ligands, 1,3,5,7-tetrakis(tetrazol-5-yl)adamantane and 1,3,5,7-tetrakis(tetrazol-5-ylphenyl)adamantane, were synthesized. Along with one known representative (with tetrakis(tetrazol-5-ylphenyl)methane), the compounds establish a new isoreticular series with fluorite as the underlying net. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to isoreticular adamantane based tetrahedral tetrazolate copper cadmium mof preparation, crystal structure isoreticular adamantane based tetrazolate copper cadmium mof, gas adsorption adamantane based tetrahedral tetrazolate copper cadmium mof and other aspects.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com