Category: 144970-30-9

On June 13, 2006, Vasylyev, Maxym; Neumann, Ronny published an article.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Preparation, characterization, and catalytic aerobic oxidation by a vanadium phosphonate mesoporous material constructed from a dendritic tetraphosphonate. And the article contained the following:

Reaction of neat V(O)(OiPr)3 with 1,3,5,7-tetrakis(4-phosphonatophenyl)adamantane (TPPhA) afforded a vanadium phosphonate mesoporous material, with V:P ratio of 1:1 and formula C34H28O16P4V4/10H2O. The N2 sorption isotherm is consistent with a mesoporous material, with pore size maximum of 38-39 脜 in the distribution curve. The compound was further characterized by powder XRD, TEM, EPR and SEM. The product is effective as catalyst for aerobic oxidation of benzylic alcs. to benzaldehydes. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to vanadium phosphonatophenyladamantane mesoporous material preparation, oxidation catalyst benzyl alc mesoporous vanadium dendritic tetraphosphonate, Inorganic Chemicals and Reactions: Metal-Containing Salts and Related Metal-Containing Compounds and other aspects.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On April 24, 2006, Vasylyev, Maxym V.; Wachtel, Ellen J.; Popovitz-Biro, Ronit; Neumann, Ronny published an article.Product Details of 144970-30-9 The title of the article was Titanium phosphonate porous materials constructed from dendritic tetraphosphonates. And the article contained the following:

An organic-inorganic hybrid material, TPPhA-Ti, was constructed by nonhydrolytic condensation of a dendritic tetrakis-1,3,5,7-(4-phosphonatophenyl)adamantane precursor and Ti(IV) isopropoxide. One preparative pathway yielded insoluble materials with a Ti/P ratio of 鈭? which was confirmed by a combination of FTIR, TGA, and EDS measurements. N2 sorption experiments showed that TPPhA-Ti is a porous solid (micropores 鈭?3 脜; mesopores 鈭?8 脜) with a high surface area, 鈭?50 m2g-1. The structure and morphol. of the TPPhA-Ti as studied by transmission and SEM showed a layered-type material. Addnl. x-ray diffraction data suggest a paracryst. material; an optimization of possible mol. arrangements of TPPhA-Ti was simulated that was in agreement with the exptl. data. A second preparative pathway yielded a Ti oxide-phosphonate with a Ti/P ratio of 鈭?.4. Both TEM and SEM revealed that hollow nanospheres were formed with diameters of 鈭?80-300 nm. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Product Details of 144970-30-9

The Article related to titanium phosphonatophenyladamantane porous material nanosphere preparation, Inorganic Chemicals and Reactions: Metal-Containing Salts and Related Metal-Containing Compounds and other aspects.Product Details of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On June 13, 2003, Li, Quan; Rukavishnikov, Aleksey V.; Petukhov, Pavel A.; Zaikova, Tatiana O.; Jin, Changshu; Keana, John F. W. published an article.SDS of cas: 144970-30-9 The title of the article was Nanoscale Tripodal 1,3,5,7-Tetrasubstituted Adamantanes for AFM Applications. And the article contained the following:

The synthesis of four novel nanoscale 1,3,5,7-tetrasubstituted adamantanes, e.g. I [R = MeCOSCH2, 1,2,5-dithiazepan-5-yl, 4-(MeCOSCH2)C6H4C顚咰], designed for at. force microscopy (AFM) applications is described. Each tetrahedrally shaped mol. incorporates a broad tripodal base made up of three identical legs that terminate with a sulfur-containing moiety, which is either a 4-acetylsulfanylmethylphenyl unit or a (1,2,5-dithiazepan-1-yl)phenyl unit. The sulfur atoms are intended for eventual binding of the mol. multivalently to the apex of a gold-coated com. AFM tip through formation of multiple S-Au bonds. In each mol., the fourth terminus is a para-substituted benzoic acid Me ester that is designed to scan the sample. It was found that I [R = 4-(MeCOSCH2)C6H4C顚咰] is sufficiently large and rigid to be imaged by a conventional AFM tip. These adamantanes may also find application as chem. well-defined nanoscale objects for calibration of AFM tips. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).SDS of cas: 144970-30-9

The Article related to adamantane phenylethynyl tetrasubstituted preparation atomic force microscopy application, Alicyclic Compounds: Tricyclic Compounds and Higher Analogs, Including Adamantanes, Fullerenes and other aspects.SDS of cas: 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On April 30, 2012, Zhang, Kai; Wang, Ling; Liang, Yanliang; Yang, Siqi; Liang, Jing; Cheng, Fangyi; Chen, Jun published an article.Product Details of 144970-30-9 The title of the article was A thermally and electrochemically stable organic hole-transporting material with an adamantane central core and triarylamine moieties. And the article contained the following:

Hole transporting materials (HTMs) play an important role in constructing optoelectronic devices. Herein, we report the design and synthesis of a novel HTM ad-OMeTPA, I, containing a central unit of adamantine and peripheral groups of triarylamine moieties. Its mol. structure was identified by 1H NMR, FT-IR, and Raman spectroscopy. The glass-transition temperature (Tg) of ad-OMeTPA was measured by differential scanning calorimetry (DSC), indicating its thermal stability. The optical and electrochem. properties of I were investigated by UV-vis absorption spectroscopy, fluorenscence spectroscopy, and cyclic voltammetry (CV). In addition, the harmonic vibrational wavenumbers and frontier MOs were calculated using d. functional theory (DFT) method. The results reveal that I has favorable optical adsorption/emission properties, suitable energy levels and high electrochem. stability, indicating its potential application in organic optoelectronic devices. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Product Details of 144970-30-9

The Article related to adamantane triarylamine derivative preparation organic hole transporting material, optoelectronic device glass transition temperature optical electrochem property, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Product Details of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On July 3, 2012, Stopin, Antoine; Garcia-Garibay, Miguel A. published an article.HPLC of Formula: 144970-30-9 The title of the article was Crystals and Aggregates of a Molecular Tetrarotor with Multiple Trityl Embraces Derived from Tetraphenyladamantane. And the article contained the following:

Samples of tetrakis-1,3,5,7-(4′-(3”,3”,3”-triphenylpropynyl)-phenylene)adamantane and its trityl-deuterated isotopologue were synthesized and their crystallization and packing properties were analyzed within the context of formation of 4- or 6-fold Ph embraces. The tetrahedral shape of these mols. with four propeller-like triphenylmethyl moieties generates several edge-to-face intermol. interactions in the solid state that result in the formation of infinite chains of mols. that are tightly interlocked. The formation of analogous edge-to-face intermol. interactions leading to aggregation in solution was also suggested by NMR experiments carried out in different solvents as a function of concentration The formation of interdigitated chains was also manifested in fibrils and thin needles, which were documented by SEM (SEM). Single crystal X-ray diffraction studies revealed the presence of multiple 4-fold Ph embraces and edge-to-face interactions as the leading motifs behind the formation of tightly interlocked mol. chains. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).HPLC of Formula: 144970-30-9

The Article related to mol rotor trityl alkynyl adamantane crystal structure aggregation chain, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.HPLC of Formula: 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On March 31, 2022, Jin, Xiao-Yang; Wu, Chuan-Shuo; Liu, An-Di; Liu, Li; Cheng, Liang published an article.SDS of cas: 144970-30-9 The title of the article was Synthesis of Rigid Rod, Trigonal, and Tetrahedral Nucleobase-Terminated Molecules. And the article contained the following:

An efficient fragment splicing method for the construction of multiple nucleobase-terminated monomers has been developed. Conformationally fixed rod, trigonal planar and tetrahedral thymine and adenine structures were generated in moderate to good yields, which will serve as inspiring examples for exploration of nucleobases as natural hydrogen-bond components in supramol. chem. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).SDS of cas: 144970-30-9

The Article related to nucleobase terminated mol rigid preparation, Biomolecules and Their Synthetic Analogs: Others, Including Purines, Pyrimidine Nucleic Acid Bases, Flavins, Lignans and other aspects.SDS of cas: 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On September 30, 2015, Pop, Lidia; Golban, Mirabela Ligia; Hadade, Niculina D.; Socaci, Crina; Grosu, Ion published an article.Related Products of 144970-30-9 The title of the article was CuAAC Synthesis of Tetragonal Building Blocks Decorated with Nucleobases. And the article contained the following:

The CuAAC synthesis and the characterization of new rigid nucleobase-decorated tetrapodands exhibiting 1,3,5,7-tetraphenyladamantane and 9,9′-spirobifluorene central units are reported. 1,3,5,7-Tetraphenyladamantane and 3,3′,6,6′-tetrasubstituted 9,9′-spirobifluorene derivatives are tetrahedral building blocks (I and II, R = nucleobase), while the derivatives of 2,2′,7,7′-tetrasubstituted 9,9′-spirobifluorene (III) can lead to 2D architectures. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Related Products of 144970-30-9

The Article related to click synthesis tetragonal adamantane spirobifluorene podand nucleobase derivative, Biomolecules and Their Synthetic Analogs: Others, Including Purines, Pyrimidine Nucleic Acid Bases, Flavins, Lignans and other aspects.Related Products of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On August 21, 2010, Takamatsu, Daiko; Fukui, Ken-ichi; Aroua, Safwan; Yamakoshi, Yoko published an article.Related Products of 144970-30-9 The title of the article was Photoswitching tripodal single molecular tip for noncontact AFM measurements: synthesis, immobilization, and reversible configurational change on gold surface. And the article contained the following:

Tripodal mols. consisting of a tetrasubstituted adamantane with three phenylacetylene legs and a reversibly photoswitching apex were designed as “single mol. tips” for both chem. and topog. characterization of the substrate surface. By covalent attachment onto gold-coated AFM tips through three S-Au bonds, these rigid tripodal mols. are expected to act as sharp, robust, and stationary mol. tips whose configuration can be reversibly changed upon irradiation with UV or visible light. In this report, the full account of the syntheses of two photoswitching tripodal mol. tips, their immobilization onto Au(111) surfaces, and the detection of photoinduced configurational change on Au(111) surface by SPM measurements are documented. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Related Products of 144970-30-9

The Article related to photoswitching tripodal single mol tip noncontact afm, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Related Products of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On July 19, 2005, Lamberto, Massimiliano; Pagba, Cynthia; Piotrowiak, Piotr; Galoppini, Elena published an article.Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Synthesis of novel rigid-rod and tripodal azulene chromophores. And the article contained the following:

Two novel azulene chromophores and were synthesized to study dynamics of ultrafast electron injection at the interface of TiO2 semiconductor nanoparticles. Fluorescence quenching was observed upon binding. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to rigid rod tripodal azulene chromophore photoinduced electron injection titania, photoinduced electron transfer titania bound azulene chromophore, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On August 31, 2004, Cannon, Amy S.; Jian, Tianying; Wang, Jun; Warner, John C. published an article.Related Products of 144970-30-9 The title of the article was Synthesis of tetrahedral carboxamide hydrogen bond acceptors. And the article contained the following:

Tetracarboxamides were prepared from tetraphenylnmethane and 1,3,5,7-tetraphenyladamantane via the halides, nitriles, and carboxylic acids. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Related Products of 144970-30-9

The Article related to tetraphenylmethane tetracarbamoyl preparation, tetraphenyladamantane tetracarbamoyl preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Related Products of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com