Category: 105752-04-3

Patil, Arvind M. published the artcile2-methoxyethanol, a remarkably efficient and alternative reaction medium for iodination of reactive aromatics using iodine and iodic acid, SDS of cas: 105752-04-3, the main research area is aromatic iodination iodine iodic acid methoxyethanol; aryl iodide preparation solvent effect green chem.

Remarkably effective iodination of reactive aromatics carried out using iodine and iodic acid in 2-methoxyethanol as an efficient and alternative reaction medium. The comparison was made by carrying out iodination reaction in acetic acid and ethanol. The 2-methoxyethanol is excellent reaction solvent in terms of clean reaction conditions, short reaction time giving quant. yields of product and no need of further purification

Orbital: The Electronic Journal of Chemistry published new progress about Aromatic hydrocarbons Role: RCT (Reactant), RACT (Reactant or Reagent). 105752-04-3 belongs to class iodides-buliding-blocks, name is 4-Iodo-3-nitroaniline, and the molecular formula is C6H5IN2O2, SDS of cas: 105752-04-3.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Shinde, Avinash T. published the artcileA practical iodination of aromatic compounds by using iodine and iodic acid, Recommanded Product: 4-Iodo-3-nitroaniline, the main research area is aromatic iodination iodine iodic acid; aryl iodide preparation.

This article described simple and efficient method for the iodination of different aromatic amines, hydroxy aromatic aldehydes, hydroxy acetophenones and phenols using iodine and iodic acid in ethanol as a solvent. Notable advantages include mild reaction condition, no need of catalyst, short reaction time, simple practical procedure, giving excellent yield of the product.

Synthetic Communications published new progress about Aromatic compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 105752-04-3 belongs to class iodides-buliding-blocks, name is 4-Iodo-3-nitroaniline, and the molecular formula is C6H5IN2O2, Recommanded Product: 4-Iodo-3-nitroaniline.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Knipe, Peter C. published the artcileA Lewis acid-mediated conformational switch, Quality Control of 105752-04-3, the main research area is pyridine alkyne ethyne benzoate preparation mol switch.

Mols. that change conformation in response to a stimulus have numerous uses, such as artificial chemoreceptors, novel drug delivery strategies and liquid crystal technol. Here the authors describe the design, synthesis and conformational behavior of an isonicotinamide-substituted diphenylacetylene upon recognition of Lewis acids, including metalloporphyrins. Binding of these at a remote site (i.e., pyridine nitrogen) increases hydrogen-bond donor ability of the proximal amide NH, causing an increased preference for the alkyne rotamer in which this hydrogen bond is maintained. The synthesis of the target compound was achieved by a reaction of 2-[2-[2-amino-6-(benzoylamino)phenyl]ethynyl]benzoic acid Me ester with 4-pyridinecarbonyl chloride. The title compound thus formed was a bis[amide] compound [[[[(pyridinyl)carbonyl]amino][(benzoyl)amino]phenyl]ethynyl]benzoic acid ester. The alkyne link permits a rapid interchange between conformers and the preferred conformation is determined by the hydrogen-donor properties of the amide bonds. Conformational changes were induced by various Lewis acids, such as [5,10,15,20-tetrakis[3,5-bis(1,1-dimethylethyl)phenyl]-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]zinc (metalloporphyrin), trifluoroacetic acid, trifluoro[1,1′-oxybis[ethane]]boron (boron trifluoride etherate).

Organic & Biomolecular Chemistry published new progress about Chemoreceptors Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), PROC (Process), PREP (Preparation). 105752-04-3 belongs to class iodides-buliding-blocks, name is 4-Iodo-3-nitroaniline, and the molecular formula is C6H5IN2O2, Quality Control of 105752-04-3.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Knipe, Peter C. published the artcileA Lewis acid-mediated conformational switch, Quality Control of 105752-04-3, the main research area is pyridine alkyne ethyne benzoate preparation mol switch.

Mols. that change conformation in response to a stimulus have numerous uses, such as artificial chemoreceptors, novel drug delivery strategies and liquid crystal technol. Here the authors describe the design, synthesis and conformational behavior of an isonicotinamide-substituted diphenylacetylene upon recognition of Lewis acids, including metalloporphyrins. Binding of these at a remote site (i.e., pyridine nitrogen) increases hydrogen-bond donor ability of the proximal amide NH, causing an increased preference for the alkyne rotamer in which this hydrogen bond is maintained. The synthesis of the target compound was achieved by a reaction of 2-[2-[2-amino-6-(benzoylamino)phenyl]ethynyl]benzoic acid Me ester with 4-pyridinecarbonyl chloride. The title compound thus formed was a bis[amide] compound [[[[(pyridinyl)carbonyl]amino][(benzoyl)amino]phenyl]ethynyl]benzoic acid ester. The alkyne link permits a rapid interchange between conformers and the preferred conformation is determined by the hydrogen-donor properties of the amide bonds. Conformational changes were induced by various Lewis acids, such as [5,10,15,20-tetrakis[3,5-bis(1,1-dimethylethyl)phenyl]-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]zinc (metalloporphyrin), trifluoroacetic acid, trifluoro[1,1′-oxybis[ethane]]boron (boron trifluoride etherate).

Organic & Biomolecular Chemistry published new progress about Chemoreceptors Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), PROC (Process), PREP (Preparation). 105752-04-3 belongs to class iodides-buliding-blocks, name is 4-Iodo-3-nitroaniline, and the molecular formula is C6H5IN2O2, Quality Control of 105752-04-3.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com