Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation was written by Roberts, Bryan;Liptrot, David;Alcaraz, Lilian;Luker, Tim;Stocks, Michael J.. And the article was included in Organic Letters in 2010.SDS of cas: 77350-52-8 This article mentions the following:
A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation A range of reactions illustrating the wide scope of this chem. were carried out and proceeded in good to excellent yields. In the experiment, the researchers used many compounds, for example, N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8SDS of cas: 77350-52-8).
N,N-Diethyl-4-iodobenzamide (cas: 77350-52-8) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.SDS of cas: 77350-52-8
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com