Total synthesis of (±)-lythrancepine II and (±)-lythrancepine III was written by Hart, David J.;Hong, Won Pyo;Hsu, Leh Yeh. And the article was included in Journal of Organic Chemistry in 1987.Recommanded Product: 2314-37-6 This article mentions the following:
Total syntheses of the Lythraceae alkaloids (±)-lythrancepine II (I, R = H) and (±)-lythrancepine III (I, R = Ac) are described. The syntheses feature a stereoselective N-acyliminium ion cyclization of II, a mechanistically interesting Eschenmoser sulfide contraction of III (X = S) to III (X = CHCO2Et) and construction of a 13-membered ring by using the Semmelhack-Ullmann procedure. In the experiment, the researchers used many compounds, for example, 3-Iodo-4-methoxybenzaldehyde (cas: 2314-37-6Recommanded Product: 2314-37-6).
3-Iodo-4-methoxybenzaldehyde (cas: 2314-37-6) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Recommanded Product: 2314-37-6
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com