Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents was written by He, Chunlin;Hooper, Joseph P.;Shreeve, Jean’ne M.. And the article was included in Inorganic Chemistry in 2016.Category: iodides-buliding-blocks This article mentions the following:
Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3–) or periodate (IO4–) anions were synthesized. The synthesis of analogous I3O8– salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by IR, 1H NMR, and 13C NMR spectroscopy as well as elemental analyses. The mol. structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Addnl., the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7. In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9Category: iodides-buliding-blocks).
4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com