Dense Iodine-Rich Compounds with Low Detonation Pressures as Biocidal Agents was written by He, Chunlin;Zhang, Jiaheng;Shreeve, Jean’ne M.. And the article was included in Chemistry – A European Journal in 2013.Product Details of 15813-09-9 This article mentions the following:
Fifteen iodo compounds and six iodyl compounds with an iodine content between 45.3-89.0 % were prepared The mono, di, and triiodyl compounds were obtained from the corresponding iodo compound by employing Oxone. All the compounds were characterized by IR, 1H and 13C NMR, elemental anal., and differential scanning calorimetry (DSC). The impact sensitivity was measured by using BAM (Bundesamt fuer Materialforschung) methodol. Based on the calculated heats of formation and exptl. densities, the detonation properties and detonation products were predicted by employing Cheetah 6.0. A total percentage of iodine-containing species in weight % (I2, HI, and I in gas phase) ranged from 46.7 (21)-88.94 % (11) was found in the detonation products. The high concentration and easy accessibility of iodine and/or iodine-containing species is very important in developing materials suitable as Agent Defeat Weapons (ADWs). In the experiment, the researchers used many compounds, for example, 4,5-Diiodo-1H-imidazole (cas: 15813-09-9Product Details of 15813-09-9).
4,5-Diiodo-1H-imidazole (cas: 15813-09-9) belongs to iodide derivatives. Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Product Details of 15813-09-9
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com