Baciocchi, Enrico’s team published research in Tetrahedron Letters in 35 | CAS: 31253-08-4

Tetrahedron Letters published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Baciocchi, Enrico published the artcileSynthesis of γ-haloesters and γ-ketoesters by homolytic addition of carbon radicals generated by α-haloesters and triethylborane to alkenes and silyl enol ethers, HPLC of Formula: 31253-08-4, the publication is Tetrahedron Letters (1994), 35(17), 2763-6, database is CAplus.

γ-Haloesters are efficiently prepared under very mild conditions by addition of electrophilic carbon radicals ·CH(R)CO2Et (R=H, Me, CO2Et) generated by XCH(R)CO2Et (X=Br, iodo)/BEt3/air in DMSO to alkenes and cycloalkenes. Thus, stirring ICH2CO2Et with 1-decene in DMSO in air gave 90% Me(CH2)7CHICH2CH2CO2Et. γ-Ketoesters are obtained when silyl enol ethers are used as the substrates.

Tetrahedron Letters published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com