Deng, Weili’s team published research in Synthesis in 50 | CAS: 31253-08-4

Synthesis published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Deng, Weili published the artcileIron-Catalyzed Carboiodination of Alkynes, HPLC of Formula: 31253-08-4, the publication is Synthesis (2018), 50(15), 2974-2980, database is CAplus.

An iron-catalyzed carboiodination of alkynes/aliphatic alkenes with alkyl iodides at room temperature was developed to afford vinyl iodides I [R1 = Ac, CO2Et, Ph, etc.; R2 = CH2CN, CF2CO2Et, cyclohexyl, etc.] and secondary alkyl iodides II [R3 = n-hexyl, Bn, 4-FC6H4CH2, CH2CH2Ph; R4 = CF2CF3, CF2CO2Et, FCH(CF3)2] resp. This method could provided synthetically useful vinyl iodides with general alkyl chains, fluoroalkyl group, ester and cyano group. Conjugated alkynes or unconjugated alkynes were both suitable for this transformation. A radical pathway was proposed for the mechanism and acetyl tert-Bu peroxide was selected as the radical initiator. Alkenes could also be applied to this chem. and produce more complex alkyl iodides.

Synthesis published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com