Transition-metal-free 伪-arylation of nitroketones with diaryliodonium salts for the synthesis of tertiary 伪-aryl, 伪-nitro ketones was written by An, Yang;Zhang, Xiao-Ming;Li, Ze-Yu;Xiong, Wen-Hui;Yu, Run-Dong;Zhang, Fu-Min. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Application of 139139-80-3 The following contents are mentioned in the article:
Transition-metal-free 伪-arylation of 伪-nitroketones with diaryliodonium salts was realized for the first time. As an application of this methodol., a concise synthesis of the clin. drug tiletamine was also achieved via a three-step procedure from 2-nitrocyclohexanone without the isolation of intermediates. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Application of 139139-80-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com