Base-Promoted Coupling of Carbon Dioxide, Amines and Diaryliodonium Salts: A Phosgene- and Metal-Free Route to O-Aryl Carbamates was written by Xiong, Wenfang;Qi, Chaorong;Peng, Youbin;Guo, Tianzuo;Zhang, Min;Jiang, Huanfeng. And the article was included in Chemistry – A European Journal in 2015.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:
A phosgene- and metal-free synthesis of O-aryl carbamates is realized through a three-component coupling of carbon dioxide, amines, and diaryliodonium salts. The reaction only requires a base as the promoter, providing access to a diverse array of O-aryl carbamates in moderate to high yields with excellent chemoselectivity. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Name: Bis(2,4,6-trimethylphenyl)iodonium triflate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com