N,N’-Disulfonylhydrazines: A novel source of sulfonyl moieties for synthesis of diaryl sulfones was written by Wang, Xuesong;Luo, Dongping;Wang, Xingyong;Zeng, Xiaobao;Wang, Xinyan;Hu, Yuefei. And the article was included in Tetrahedron Letters in 2021.Category: iodides-buliding-blocks The following contents are mentioned in the article:
A new synthesis of diaryl sulfones is achieved from N,N’-disulfonylhydrazines and diaryliodonium salts. Its key advantage is that N,N’-disulfonylhydrazines carry out an efficient base-promoted evolution of nitrogen to generate in situ ammonium sulfinates with good solubility and high reactivity. N,N’-Disulfonylhydrazines prove to be an excellent synthetic equivalent of sulfinic acids and their salts with none of their drawbacks. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Category: iodides-buliding-blocks).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com