Direct Arylation of C(sp3)-H Bonds in Aliphatic Amides with Diaryliodonium Salts in the Presence of a Nickel Catalyst was written by Iyanaga, Miki;Aihara, Yoshinori;Chatani, Naoto. And the article was included in Journal of Organic Chemistry in 2014.Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate The following contents are mentioned in the article:
The Ni(II)-catalyzed direct arylation of C(sp3)-H (Me and methylene) bonds in aliphatic amides containing an 8-aminoquinoline moiety as the directing group with diaryliodonium salts as coupling electrophiles is described. A wide variety of functional groups are tolerated in the reaction. The reaction represents the first example of the Ni-catalyzed direct arylation of C(sp3)-H bonds with diaryliodonium salts. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com