Metal-Free Synthesis of Unsymmetrical Organoselenides and Selenoglycosides was written by Guan, Yong;Townsend, Steven D.. And the article was included in Organic Letters in 2017.Application In Synthesis of Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:
Arylselenocyanates were prepared chemoselectively without added metal reagents by reaction of aryliodonium salts with potassium selenocyanate in EtOAc; reduction of the selenocyanates with NaBH4 in EtOH and alkylation with alkyl bromides, arylation with aryliodonium salts, alkynylation with an alkynyliodoxolone, or glycosylation with peracetylated 伪-glycosyl bromides yielded unsym. aryl alkyl and diarylselenides and 尾-(arylseleno)glycosides. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application In Synthesis of Bis(2,4,6-trimethylphenyl)iodonium triflate).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Application In Synthesis of Bis(2,4,6-trimethylphenyl)iodonium triflate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com