Palladium-Catalyzed C-H ortho Arylation of Benzoic Acids with Diaryliodonium Salts in Water was written by Wu, Zhiqing;Chen, Si;Hu, Chenxu;Li, Zhengkai;Xiang, Haifeng;Zhou, Xiangge. And the article was included in ChemCatChem in 2013.Application of 1204518-02-4 The following contents are mentioned in the article:
We disclose an efficient and practical protocol for the C-H ortho arylation of benzoic acids by using water as an environmentally benign, nontoxic reaction medium. Remarkably, the diaryliodonium salts were first utilized as arylating reagents for C -H arylation of benzoic acids. The choice of water as the solvent is crucial for this reaction, which sets the stage for the broad application of aqueous conditions in C-H functionalization reactions. Overall, this simple catalytic system represents an important complement to previous reports for the preparation of biaryls. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Application of 1204518-02-4).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Application of 1204518-02-4
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com