Maier, Martin S. published the artcileOxidative Approach Enables Efficient Access to Cyclic Azobenzenes, Computed Properties of 101420-79-5, the publication is Journal of the American Chemical Society (2019), 141(43), 17295-17304, database is CAplus and MEDLINE.
Azobenzenes are versatile photoswitches that found widespread use in a variety of fields, ranging from photopharmacol. to the material sciences. In addition to regular azobenzenes, the cyclic diazocines have recently emerged. Although diazocines have fascinating conformational and photophys. properties, their use was limited by their synthetic accessibility. Herein, the authors present a general, high-yielding protocol that relies on the oxidative cyclization of dianilines. In combination with a modular substrate synthesis, it allows for rapid access to diversely functionalized diazocines on gram scales. The authors’ work systematically explores substituent effects on the photoisomerization and thermal relaxation of diazocines. It will enable their incorporation into a wide variety of functional mols., unlocking the full potential of these emerging photoswitches. The method can be applied to the synthesis of a new cyclic azobenzene with a nine-membered central ring and distinct properties.
Journal of the American Chemical Society published new progress about 101420-79-5. 101420-79-5 belongs to iodides-buliding-blocks, auxiliary class Nitrile,Nitro Compound,Iodide,Benzene,Benzene Compounds, name is 4-Iodo-3-nitrobenzonitrile, and the molecular formula is C7H3IN2O2, Computed Properties of 101420-79-5.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com