Sapountzis, Ioannis published the artcileSynthesis of Functionalized Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange, SDS of cas: 101420-79-5, the publication is Journal of Organic Chemistry (2005), 70(7), 2445-2454, database is CAplus and MEDLINE.
Various nitro-substituted aryl and heteroaryl iodides undergo an iodine-magnesium exchange reaction when treated with PhMgCl leading to nitro-containing magnesium organometallics. These Grignard reagents display an excellent stability at temperatures below -40 °C and do not undergo electron-transfer reactions. They react as expected with various electrophiles. E.g., reaction of 2-IC6H4NO2 with PhMgCl resulted in iodine-magnesium exchange to give a nitro-substituted Grignard reagent, which reacted with PhCHO to give 2-O2NC6H4CHPhOH. In addition, transmetalation of the nitro-substituted Grignard reagents by CuCN.2LiBr, followed by reaction with electrophiles, was successful. Transmetalation of the nitro-substituted Grignard reagents by ZnBr2 gave organozinc intermediates, which underwent Pd-catalyzed Negeshi cross-coupling reaction with aryl iodides.
Journal of Organic Chemistry published new progress about 101420-79-5. 101420-79-5 belongs to iodides-buliding-blocks, auxiliary class Nitrile,Nitro Compound,Iodide,Benzene,Benzene Compounds, name is 4-Iodo-3-nitrobenzonitrile, and the molecular formula is C7H3IN2O2, SDS of cas: 101420-79-5.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com