Obeid, Naim M. published the artcile(Oligo)aromatic species with one or two conjugated Si:Si bonds: near-IR emission of anthracenyl-bridged tetrasiladiene, Product Details of C10H13I, the main research area is disilene preparation crystal structure DFT calculation fluorescence; tetrasiladiene paraarylene bridged preparation crystal structure DFT calculation fluorescence; crystal structure disilene paraarylene bridged tetrasiladiene; mol structure disilene paraarylene bridged tetrasiladiene.
Aryl disilenes Tip2Si:Si(Tip)Ar (2a-d) and para-arylene bridged tetrasiladienes, Tip2Si:Si(Tip)-LU-Si(Tip):SiTip2 (3a-d) were synthesized by the transfer of the Tip2Si:SiTip unit to aryl halides and dihalides by nucleophilic disilenides Tip2Si:SiTipLi (Tip = 2,4,6-iPr3C6H2, Ar = aryl substituent, LU = para-arylene linking unit). The scope of the nucleophilic Si:Si transfer reaction is demonstrated to also include substrates of considerable steric bulk such as mesityl or duryl halides Ar-X (Ar = Mes = 2,4,6-Me3C6H2; Ar = Dur = 2,3,5,6-Me4C6H, X = Br or I). Bridged tetrasiladienes Tip2Si:Si(Tip)-LU-Si(Tip):SiTip2 with more extended linking units surprisingly exhibit fluorescence at room temperature, albeit weak. DFT calculations suggest that partial charge transfer character of the excited state is a possible explanation.
Dalton Transactions published new progress about Aryl halides Role: RCT (Reactant), RACT (Reactant or Reagent). 2100-25-6 belongs to class iodides-buliding-blocks, name is 3-Iodo-1,2,4,5-tetramethylbenzene, and the molecular formula is C10H13I, Product Details of C10H13I.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com