Lu, Xiao-Yu published the artcileTrisubstituted olefin synthesis via Ni-catalyzed hydroalkylation of internal alkynes with non-activated alkyl halides, Formula: C11H12INO2, the main research area is alkene preparation stereoselective regioselective; internal alkyne alkyl halide nickel catalyst hydroalkylation.
Ni-catalyzed regio- and stereo-selective hydroalkylation of internal alkynes R1CCR2 [R1 = Ph, pyridin-3-yl, (CH2)2CH3, etc.; R2 = Me, Ph, (CH2)3CH3, etc.] with non-activated alkyl halides XR3 (R3 = cyclohexyl, butan-2-yl, 1-[(4-methylbenzene)sulfonyl]pyrrolidin-3-yl, etc.; X = I, Br) was reported. This method does not use any sensitive organometallic reagents and shows good functional group compatibility, which enables the efficient synthesis of many tri-substituted olefins R1CH=C(R2)(R3) from readily available coupling partners. It also provides a straightforward method for the modification of bioactive organic mols.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenes Role: SPN (Synthetic Preparation), PREP (Preparation). 939759-26-9 belongs to class iodides-buliding-blocks, name is Benzyl 3-iodoazetidine-1-carboxylate, and the molecular formula is C11H12INO2, Formula: C11H12INO2.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com