Maya, Francisco published the artcileSynthesis of Fluorinated Oligomers toward Physical Vapor Deposition Molecular Electronics Candidates, Safety of 4-Iodo-3-nitroaniline, the main research area is fluorinated oligomer thiol nitrile pyridine chemisorption gold platinum; safety deprotection thioacetate.
New electron-deficient fluorinated oligo(phenylene ethynylenes) (OPEs) with varied functional groups were synthesized as free thiols, nitriles, and pyridines, ready to be used for surface adhesion. Calculated dipole moments suggest better matching between energy levels of bulk interfaces and mol. frontier orbitals when compared to nonfluorinated OPEs. Differential scanning calorimetry confirmed a higher thermal stability than the nonfluorinated counterparts. Surface anal. by ellipsometry, contact angle goniometry, cyclic voltammetry, and surface IR and XPS verified that the OPEs chemisorb on Au and Pt surfaces. On the basis of the phys. properties of the fluorinated OPEs, they might be useful in future phys. vapor deposition techniques, methods that are typically used in standard semiconductor fabrication processes. Safety: deprotection of a thioacetate derivative led to a violent explosion.
Chemistry of Materials published new progress about Differential scanning calorimetry (of fluorinated oligo(phenylene ethynylenes)). 105752-04-3 belongs to class iodides-buliding-blocks, name is 4-Iodo-3-nitroaniline, and the molecular formula is C6H5IN2O2, Safety of 4-Iodo-3-nitroaniline.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com