On April 12, 2010, Chun, Jiseul; Lee, Han Sol; Jung, Il Gu; Lee, Soon Won; Kim, Hae Jin; Son, Seung Uk published an article.Quality Control of 1H-Imidazolium, 1,3-bis[4-iodo-2,6-bis(1-methylethyl)phenyl]-, chloride (1:1) The title of the article was Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species. And the article contained the following:
A new and direct synthetic route for N-heterocyclic carbene (NHC)-copper complexes was disclosed by heating imidazolium halides with Cu2O. The related synthetic procedure was quite simple and the product easily separable from the reaction mixture by simple filtration. Ultimately, this reaction was successfully applied to decorate three-dimensional(3D)-metal organic framework (MOFs) with coordinatively unsaturated NHC-copper species. The experimental process involved the reaction of 1H-Imidazolium, 1,3-bis[4-iodo-2,6-bis(1-methylethyl)phenyl]-, chloride (1:1)(cas: 934008-48-7).Quality Control of 1H-Imidazolium, 1,3-bis[4-iodo-2,6-bis(1-methylethyl)phenyl]-, chloride (1:1)
The Article related to copper oxide versatile reagent nhc carbene complex, imidazolium halide reaction copper monoxide, crystal mol structure copper cerium imidazolidene carbene complex, Organometallic and Organometalloidal Compounds: Groups Ib, Iib – Cu, Ag, Au, Zn, Cd, Hg and other aspects.Quality Control of 1H-Imidazolium, 1,3-bis[4-iodo-2,6-bis(1-methylethyl)phenyl]-, chloride (1:1)
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com