Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Computed Properties of 626-01-7.
Zhou, Wenting;Li, Laiyang;Qin, Ruixuan;Zhu, Jiaxin;Liu, Shengjie;Mo, Shiguang;Shi, Zaifa;Fang, Huihuang;Ruan, Pengpeng;Cheng, Jun;Fu, Gang;Zheng, Nanfeng research published 《 Non-contact biomimetic mechanism for selective hydrogenation of nitroaromatics on heterogeneous metal nanocatalysts》, the research content is summarized as follows. While the enzymic reduction of unsaturated compounds usually has high specificity, highly selective reduction processes are hardly realized by heterogeneous industrial catalysts, which is critical for the green production of many fine chems. Here, we report an unexpected discovery of a biomimetic behavior of dicyandiamide (DICY)-modified Pt nanocatalysts for the green hydrogenation of a wide range of nitroaroms. We demonstrate that the surface modification by DICY not only prevents the direct contact of nitroarom. reactants with Pt surface but also induces an effective non-contact hydrogenation mechanism mediated by protons and electrons. In such a process, the DICY layer serves as a “semi-permeable membrane” to allow the permeation of H2 mols. for being activated into electrons and protons at the Pt-DICY interface. With the generation of separated protons and electrons, the nitro group with strong electrophilic properties can be hydrogenated through the electron transfer followed by the proton transfer, which is facilitated by the hydrogen bonding network formed by protonated DICY. The unique mechanism makes it highly directional toward the hydrogenation of nitro groups without side reactions. Owing to its capability to largely eliminate the waste generation, the developed Pt-DICY catalysts have been successfully applied for the green industrial production of many important aniline intermediates.
626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.
3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Computed Properties of 626-01-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com