In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Application In Synthesis of 626-01-7.
Zhang, Jun;Li, Yue;Wang, Bei;Jia, Ai-Quan;Zhang, Qian-Feng research published 《 Synthesis of Dichlorobenzamide Derivatives: Crystal Structures of 3,5-Dichloro-N-(2-chlorophenyl)benzamide and 3,5-Dichloro-N-(4-chlorophenyl)benzamide》, the research content is summarized as follows. Reactions of 3,5-dichlorobenzoyl chloride and arylamines in N,N’-dimethylformamide solution at 60°C afforded a series of dichlorobenzamide derivatives 3,5-di-ClC6H3C(O)NHR1 [R1 = Bn, 2,6-di-MeC6H3, 4-ClC6H4, etc.] in good yields. The dichlorobenzamides 3,5-di-ClC6H3C(O)NHR1 [R1 = 2-ClC6H4, 4-ClC6H4] were characterized by X-ray crystallog. The compound 3,5-di-ClC6H3C(O)NHR1 [R1 = 4-ClC6H4] crystallizes in triclinic space group P̅, with a = 5.047 (18), b = 10.28 (4), c = 13.36 (5) Å, α = 107.59 (5)°, β = 93.55 (5)°, γ = 98.34 (5)°, and Z = 2. The unit cell of compound 3,5-di-ClC6H3C(O)NHR1 [R1 = 2-ClC6H4] had a monoclinic Pn symmetry with cell parameters a = 9.581 (3), b = 12.217 (4), c = 11.072 (3) Å, β = 92.584 (4)°, and Z = 4.
Application In Synthesis of 626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.
3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com