On July 20, 2009, Chun, Jiseul; Jung, Il Gu; Kim, Hae Jin; Park, Mira; Lah, Myoung Soo; Son, Seung Uk published an article.Formula: C27H35ClI2N2 The title of the article was Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions. And the article contained the following:
A new building block containing an imidazolium salt was synthesized and used for the construction of supramol. networks with cadmium and copper ions. The authors discovered the concomitant formation of an N-heterocyclic carbene-Cu complex (CN = 2) in the self-assembly of imidazolium dicarboxylates and Cu nitrates in DMF under heating. The proton in the 2 position of the imidazolium salt was abstracted, and CuII was reduced to CuI during the self-assembly process. The experimental process involved the reaction of 1H-Imidazolium, 1,3-bis[4-iodo-2,6-bis(1-methylethyl)phenyl]-, chloride (1:1)(cas: 934008-48-7).Formula: C27H35ClI2N2
The Article related to copper heterocyclic carbene complex preparation self assembly supramol structure, crystal structure copper heterocyclic carbene complex, mol structure copper heterocyclic carbene complex, imidazolium dicarboxylate self assembly copper nitrate and other aspects.Formula: C27H35ClI2N2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com