On August 27, 2003, Vasylyev, Maxym; Popovitz-Biro, Ronit; Shimon, Linda J. W.; Neumann, Ronny published an article.Synthetic Route of 144970-30-9 The title of the article was Inorganic-organic hybrid materials based on Keggin type polyoxometalates and organic polyammonium cations. And the article contained the following:
Co-crystallization of a triammonium cation with short and somewhat flexible ‘arms’, [N,N,N-tris[2-(dimethylamino)ethyl]-1,3,5-benzenetricarboxamide]3+, with a polyoxometalate trianion, PW12O403-, yielded an insoluble channeled or microporous structure (crystal data reported). The polyoxometalate clusters are arranged in a layered and zigzag fashion along the xy plane. Looking along the x-axis, channels of a dimension of ∼3.5×∼6.5 Å are observed C-H···O bonds aided in determining the crystal packing by providing directionality to the anion-cation interaction. However, the co-crystallization of a tetraammonium cation with an extended and rigid tetrahedral configuration, 1,3,5,7-tetrakis{4-[(E)-2(N-methylpyridinium-4-yl)vinyl]phenyl}adamantane tetraiodide, with a polyoxometalate tetracation, SiW12O404-, yielded a lamellar structure with alternating layers with spacing of 16.6 Å of the inorganic-organic hybrid material. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Synthetic Route of 144970-30-9
The Article related to structure control organic cation polyoxometalate salt, crystal structure trisdimethylaminoethylbenzenetricarboxamide phosphotungstate, silicotungstate tetrakismethylpyridiniumylvinylphenyladamantane salt preparation, tungstate phospho silico organic cation preparation structure control, microporous polyoxometalate organic cation structure control and other aspects.Synthetic Route of 144970-30-9
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com