Wei, Rong-Jia; Zhou, Hou-Gan; Zhang, Zhi-Yin; Ning, Guo-Hong; Li, Dan published their research in CCS Chemistry in 2021. The article was titled 《Copper (I)- organic frameworks for catalysis: networking metal clusters with dynamic covalent chemistry》.COA of Formula: C5H4IN The article contains the following contents:
Metal clusters exhibit diverse structures, emerging functions, and applications; thus, incorporating clus- ters into metal-organic frameworks (MOFs) brings tremendous merits. Although the construction of cluster-based MOFs is sophisticated, the reticular materials constructed from a combination of the chem. of metal clusters and covalent organic frameworks (COFs) remain unexplored. Herein, we prepared two Cu(l) cluster-based MOFs with cyclic trinuclear units (CTUs), termed JNM-1 and JNM-Z, either by a stepwise synthetic approach or by a one-pot reaction, for networking clusters with dy- namic covalent chem., rarely utilized in MOF syn- thesis. The generated JNMs exhibited excellent stability and could be used as recyclable catalysts for palladium-free Sonogashira coupling reactions with high efficiency and tolerance (>90% yield for nine examples), without loss of performance for at least five cycle runs. In addition, conjugated single molec- ular wires with lengths ranging from 1.6 to 2.7 nm were synthesized feasibly using the JNM-1 catalyst. The experimental part of the paper was very detailed, including the reaction process of 4-Iodopyridine(cas: 15854-87-2COA of Formula: C5H4IN)
4-Iodopyridine(cas: 15854-87-2) belongs to pyridine. Pyridines are often used as catalysts or reagents; particular notice has been paid recently to how pyridine coordinates to metal centers enabling a wide range of valuable reactions. COA of Formula: C5H4IN
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com