In 2022,Peng, Dao; Zhang, Yu; Liu, Xiao-Qing; Shang, Hang; Lin, Gang; Jin, Hong-Ying; Liu, Xue-Fen; He, Ran; Shang, Ye-Han; Xu, Yin-Hua; Luo, Shu-Ping published an article in Molecular Catalysis. The title of the article was 《Highly active and reusable copper phthalocyanine derivatives catalyzed the hydroxylation of (hetero)aryl halides》.Product Details of 626-02-8 The author mentioned the following in the article:
Authors have researched and developed a series of copper phthalocyanine derivatives as new highly active and reusable catalysts for the hydroxylation of (hetero)aryl halides. The perfluorinated copper phthalocyanine (CuPcF16) showed the highest activity for the hydroxylation of aryl iodide with an excellent yield (up to 98%) under low catalytic loading (0.5 mol% CuPcF16). Similarly, the hydroxylation of aryl bromides and aryl chlorides catalyzed by CuPcF16 also had high activity with 42-98% yield. Moreover, the recyclability of this catalyst can up to 6 times without significant loss in catalytic activity. In addition to this study using 3-Iodophenol, there are many other studies that have used 3-Iodophenol(cas: 626-02-8Product Details of 626-02-8) was used in this study.
3-Iodophenol(cas: 626-02-8) belongs to organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Product Details of 626-02-8 Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com