《Binuclear Palladium Complex Immobilized on Mesoporous SBA-16: Efficient Heterogeneous Catalyst for the Carbonylative Suzuki Coupling Reaction of Aryl Iodides and Arylboronic Acids Using Cr(CO)6 as Carbonyl Source》 was published in Catalysis Letters in 2020. These research results belong to Niakan, Mahsa; Asadi, Zahra; Emami, Mohammad. Application of 624-31-7 The article mentions the following:
A binuclear palladium complex immobilized on organo-functionalized SBA-16 was prepared and structurally characterized by routine techniques. Characterizations indicated that the mesostructure of SBA-16 was maintained after the immobilization of palladium complex. Then, the prepared nanomaterial was applied as a heterogeneous catalyst in the carbonylative Suzuki coupling reaction of aryl iodides RI with arylboronic acids R1B(OH)2 using Cr(CO)6 as carbonyl source to afford diaryl ketones RC(O)R1 [R = Ph, 4-MeC6H4, 4-ClC6H4, 2-H2NC6H4, etc.; R1 = Ph, 4-EtC6H4, 4-F3CC6H4] in excellent yields. Moreover, the catalyst was readily recovered by filtration and could be reused for seven cycles without losing its structural integrity and catalytic activity. The results came from multiple reactions, including the reaction of 1-Iodo-4-methylbenzene(cas: 624-31-7Application of 624-31-7)
1-Iodo-4-methylbenzene(cas: 624-31-7) undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium.Application of 624-31-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com