Nozawa, Takeshi’s team published research in Chemistry Letters in 2015 | CAS: 624-73-7

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Formula: C2H4I2

Formula: C2H4I2In 2015 ,《1,3,5-[(tBu2MeSi)2Si]3C6H3: isolable Si-centered triradical with a high-spin quartet ground state》 was published in Chemistry Letters. The article was written by Nozawa, Takeshi; Ichinohe, Masaaki; Sekiguchi, Akira. The article contains the following contents:

Reductive deiodination of 1,3,5-tris[2,2-di-tert-butyl-1-(di-tert-butylmethylsilyl)-1-iodo-2-methyldisilanyl]benzene (1) with KC8 results in the formation of isolable Si-centered triradical 1,3,5-[(t-Bu2MeSi)2Si]3C6H3 (2), which was characterized by x-ray crystallog. and ESR (EPR) spectroscopy. The quartet ground state for triradical 2 was established using EPR spectroscopy by Curie plots (5-60 K) for the characteristic Δm = 2 and Δm = 3 transitions. The experimental process involved the reaction of 1,2-Diiodoethane(cas: 624-73-7Formula: C2H4I2)

1,2-Diiodoethane(cas: 624-73-7) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Formula: C2H4I2

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com