In 2019,Journal of Organic Chemistry included an article by Niu, Yi-Jie; Sui, Guo-Hui; Zheng, Hong-Xing; Shan, Xiang-Huan; Tie, Lin; Fu, Jia-Le; Qu, Jian-Ping; Kang, Yan-Biao. Related Products of 90-14-2. The article was titled 《Competing Dehalogenation versus Borylation of Aryl Iodides and Bromides under Transition-Metal-Free Basic Conditions》. The information in the text is summarized as follows:
Selectivity-controllable base-promoted transition-metal-free borylation and dehalogenation of aryl halides are described. Under the conditions of borylation, the dehalogenation which emerges as a competitive side reaction was well-controlled by carefully controlling the borylation conditions. However, the dehalogenation using benzaldehyde as a H source also was accomplished. The applications of direct radical borylation and dehalogenation of aryl halides demonstrate their synthetic practicability in pharmaceutical-oriented organic synthesis. Based on the exptl. evidences, the tBuOK/1,10-Phen-triggered radical nature of both competitive reactions was revealed. In the experiment, the researchers used 1-Iodonaphthalene(cas: 90-14-2Related Products of 90-14-2)
1-Iodonaphthalene(cas: 90-14-2) is one of organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Oceanic alkyl iodides are believed to be the principal source of atmospheric iodine.Related Products of 90-14-2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com