Miller, Eric M.; Walczak, Maciej A. published the artcile< Light-Mediated Cross-Coupling of Anomeric Trifluoroborates>, Product Details of C6H3F2I, the main research area is BMIDA ester deoxy sugar disaccharide fluoroborate glycosylation; light mediated cross coupling anomeric fluoroborate stereoselective arylation etherification.
Stereoselective reactions at the anomeric carbon constitute the cornerstone of preparative carbohydrate chem. Here, we report stereoselective C-arylation and etherification reactions of anomeric trifluoroborates derived from BMIDA esters. These reactions are characterized by high anomeric selectivities for 2-deoxysugars and broad substrate scope (24 examples), including disaccharides and trifluoroborates with free hydroxyl groups. Taken together, this new class of carbohydrate reagents adds the palette of anomeric nucleophile reagents suitable for efficient installation of C-C bonds.
Organic Letters published new progress about Arylation catalysts, stereoselective. 2265-92-1 belongs to class iodides-buliding-blocks, and the molecular formula is C6H3F2I, Product Details of C6H3F2I.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com