《Intermolecular Alkene Difunctionalization via Gold-Catalyzed Oxyarylation》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Zhang, Shuyao; Wang, Chenhuan; Ye, Xiaohan; Shi, Xiaodong. Quality Control of 1-Iodo-4-methylbenzene The article mentions the following:
The gold-catalyzed intermol. oxyarylation of alkenes is reported. This work employed the oxidative addition of aryl iodides to Me-DalphosAu+ for the formation of a AuIII-Ar intermediate. The better binding ability of alkenes over O nucleophiles ensured the success of intermol. oxyarylation, giving desired products with a broad substrate scope and high efficiency (>50 examples with up to 95% yield). One-pot converting of methoxy groups into other nucleophiles allowed achieving alkene difunctionalization with the construction of C-N, C-S, and C-C bonds under mild conditions. In the experimental materials used by the author, we found 1-Iodo-4-methylbenzene(cas: 624-31-7Quality Control of 1-Iodo-4-methylbenzene)
1-Iodo-4-methylbenzene(cas: 624-31-7) undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium.Quality Control of 1-Iodo-4-methylbenzene
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com