In 2019,Journal of the American Chemical Society included an article by Yang, Qi-Liang; Xing, Yi-Kang; Wang, Xiang-Yang; Ma, Hong-Xing; Weng, Xin-Jun; Yang, Xiang; Guo, Hai-Ming; Mei, Tian-Sheng. Application of 625-99-0. The article was titled 《Electrochemistry-Enabled Ir-Catalyzed Vinylic C-H Functionalization》. The information in the text is summarized as follows:
Herein, the development of electrochem. vinylic C-H functionalization of acrylic acids with alkynes is reported. In this reaction an iridium catalyst enables C-H/O-H functionalization for alkyne annulation, affording α-pyrones with good to excellent yields in an undivided cell. Preliminary mechanistic studies show that anodic oxidation is crucial for releasing the product and regeneration of a Ir(III) intermediate from a diene-Ir(I) complex, which is a coordinatively saturated, 18-electron complex. Importantly, common chem. oxidants such as Ag(I) or Cu(II) did not give significant amounts of the desired product in the absence of elec. current under other-wise identical conditions.1-Chloro-3-iodobenzene(cas: 625-99-0Application of 625-99-0) was used in this study.
1-Chloro-3-iodobenzene(cas: 625-99-0) belongs to organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine.Application of 625-99-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com